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#Post#: 1189--------------------------------------------------
Graphene 💫✨👍👍👍🌞
addressing the challenge of oil-water separation
DIR By: AGelbert
Date: July 18, 2023, 12:29 pm
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Posted: Jul 18,2023 by Roni Peleg
[center]Researchers develop rGO-based
[glow=green,2,300]approach[/glow] to address oil-water
separation challenges[/center]
[move][glow=green,2,300]rGO-PU sponge [/glow]absorbed and
collected oil from an oil-water mixture, achieving a remarkable
recovery rate of approximately 97%
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/>
HTML https://soberthinking.createaforum.com/gallery/soberthinking/1-070422160139.gif[/move]
Researchers from Qatar University (QU), Maimoona Mohamed and
Nada Yahya Deyab, along with their supervisor Dr. Shabi Abbas
Zaidi, have made progress in addressing the challenge of
oil-water separation.
Their research focuses on developing a novel material for
efficient oil recovery from oil-water mixtures. By modifying
polyurethane (PU) sponges and cotton with reduced graphene oxide
(rGO), they have achieved promising results in terms of
hydrophobicity, oil-absorption efficacy, reusability, and
cost-effectiveness, offering a promising solution to address the
issue of water and soil pollution caused by oil spills.
The 3D porous structure of polyurethane sponges has shown
promise in oil-water separation applications; however, its poor
hydrophobicity limits its oil-absorption efficiency. To overcome
this limitation, the team focused on enhancing the
hydrophobicity of the sponge by modifying it with
[glow=green,2,300]graphene oxide (GO) [/glow]and subsequently
reducing it to reduced graphene oxide (rGO) using a readily
available [glow=green,2,300]green [/glow]reducing agent,
L-ascorbic acid (L-AA).
The process of synthesizing GO involved mixing 1g of graphite
flakes with 23 ml of 98% H2SO4, followed by stirring for 24
hours at room temperature. Subsequently, 100mg of NaNO3 was
added, and the mixture was stirred for 30 minutes. Afterward, 3g
of KMnO4 was gradually introduced, and the resulting mixture was
heated and stirred for about 30 minutes.
Further additions of water, followed by the introduction of 10
ml of 30% H2O2, completed the synthesis process. The obtained GO
was then centrifuged to remove any un-oxidized graphite and
dried to obtain a powder-like substance. Individual sheets of
synthesized GO were dispersed in distilled water for reduction
and modification studies.
To fabricate rGO-PU sponges, the team employed a green method
that utilized L-ascorbic acid as a reducing agent. The PU
sponges were initially cut into small pieces and thoroughly
rinsed with distilled water and acetone before being dried. An
aqueous dispersion of GO was prepared through sonication, and
L-AA was dissolved in it. The dry PU sponges were immersed in
this mixture and left for 48 hours with mild stirring.
Then, the sponges were washed and dried to obtain rGO-PU
sponges. The same protocol was applied to obtain rGO-cotton. The
modified surfaces of both [glow=green,2,300]rGO-PU[/glow] and
[glow=green,2,300]rGO-cotton exhibited[/glow] superior
absorption behavior and water contact angles compared to their
bare counterparts.
The capabilities of the rGO-PU sponge were put to the test by
absorbing and collecting oil from an oil-water mixture,
reportedly achieving a remarkable recovery rate of approximately
97%. Moreover, the rGO-PU sponge demonstrated excellent
reusability and compressibility without any signs of cracking or
leaking. In a comparative study, the team found that the highly
compressible and porous nature of the rGO-PU sponge outperformed
the rGO-cotton surfaces in various samples.
Source: thepeninsulaqatar
Tags: Graphene applications Graphene water treatment Graphene
Oxide reduced graphene oxide
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