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DIR Return to: Analytical Chemistry
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#Post#: 821--------------------------------------------------
Potentiometry
DIR By: Finwe
Date: October 5, 2012, 6:09 pm
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I'm currently studying how electrochemical cells used for
potentiometric measurements work (just like the pH meters), and
though I understand how the pH meter can measure the potential
developed across the glass membrane, I don't understand why the
gradient of activity across the membrane is given by the
following equation:
ΔG=-R*T*ln(activity of H+ in sample/activity of H+ in
solution).
Can someone explain it to me?
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