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#Post#: 747--------------------------------------------------
Petroleum fractions
DIR By: Michel
Date: September 27, 2012, 9:05 am
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Hydrocarbons can exist in all three phases (gas, liquid and
solid). Petroleum generally contains 83-87% Carbon,
10-14%Hydrogen, with trace amounts of other elements like
Oxygen, Sulfur,Nitrogen, etc. For petroleum to be useful as a
source of energy and raw materials for chemical industries, it
has to be separated into its component fractions. This is done
by fractional distillation ofcrude oil in an oil refinery.
Crude oil typically contains fourdifferent types of
hydrocarbon molecules. The relative percentageof each fraction
varies from oil to oil. The four typical hydrocarbon molecules
found in crude oil include; Paraffins (15-60%), Naphthalenes
(30-60%), aromatics (3-30%), Asphaltics/Asphaltenes (~6%)
Alkanes: They are compounds with single carbon to carbon bonds
with the general formula CnH2n+2. Apart from ethane, all alkanes
have isomers. Natural gas is mainly ethane and methane. Higher
molecular weight alkanes may exist as vapor or liquid depending
on reservoir conditions.
Cycloalkanes: Just as the name suggests, they are alkanes with
one or more ring structures. Examples include cyclobutane,
cyclopentane, etc. cycloalkanes have properties similar to
alkanes but they have higher boiling points.
Aromatics: The aromatic hydrocarbons are unsaturated
hydrocarbons with one or more benzene rings. The benzene ring
has six carbon atoms bonded in ahexagonal geometry. X-ray
diffraction studies show that the electrons for the C-C bonds in
benzene are equally distributed and that the bond lengths of the
C-C bonds are all equal and intermediate in length. The high
degree of unsaturation in aromatics make them burn with asooty
flame. Aromatics such as benzene, toluene, xylene etc are useful
industrial chemicals.
Asphaltics: Asphaltics are a sub class of aromatics. They are
otherwise called resins. Asphaltene precipitation is more common
in large to medium oils. Asphaltene precipitation may occur as a
result of hydrocarbon injection.
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