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       LITHIFICATION
       By: Admin Date: February 2, 2017, 11:16 pm
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       Lithification
  HTML https://www.britannica.com/science/lithification
       Lithification, complex process whereby freshly deposited loose
       grains of sediment are converted into rock. Lithification may
       occur at the time a sediment is deposited or later. Cementation
       is one of the main processes involved, particularly for
       sandstones and conglomerates. In addition, reactions take place
       within a sediment between various minerals and between minerals
       and the fluids trapped in the pores; these reactions,
       collectively termed authigenesis, may form new minerals or add
       to others already present in the sediment. Minerals may be
       dissolved and redistributed into nodules and other concretions,
       and minerals in solution entering the sediment from another area
       may be deposited or may react with minerals already present. The
       sediment may be compacted by rearrangement of grains under
       pressure, reducing pore space and driving out interstitial
       liquid.
       Lithification
  HTML https://www.reference.com/science/process-lithification-260ed465d44a46db#full-answer
       Lithification is the process by which sediment turns into
       hardened rock. There are three ways in which lithification can
       occur. These processes are called compaction, recrystallization
       and cementation.
       Compaction is a process of lithification that works for finer
       particles only. Compaction occurs when particles such as clay
       minerals are compressed. Coarser particles are not able to be
       hardened with this process because compression does not make
       them stick together.
       Minerals such as limestone and aragonite can harden through the
       process of recrystallization. These minerals are easily
       dissolved in water, and the crystals that form from those
       dissolved minerals are much harder than the original substances.
       Cementation is the process where coarser grain sediments become
       hardened rock. Water fills into the empty space between the
       particles, and the ions in the water create new crystalline
       formations among the sediments. When the water evaporates, the
       sediment eventually seals and hardens, leaving behind a solid
       piece of rock.
       The creation of new minerals during the cementation process is
       an example of authigenesis. Authigenesis is a term that
       describes a process in which new minerals are created inside a
       rock, or that the deposited minerals react and combine with the
       minerals already present in the rock or sediment.
       Cementation
       sedimentary rock
  HTML https://www.britannica.com/science/cementation-sedimentary-rock
       Cementation, in geology, hardening and welding of clastic
       sediments (those formed from preexisting rock fragments) by the
       precipitation of mineral matter in the pore spaces. It is the
       last stage in the formation of a sedimentary rock. The cement
       forms an integral and important part of the rock, and its
       precipitation affects the porosity and permeability of the rock.
       Many minerals may become cements; the most common is silica
       (generally quartz), but calcite and other carbonates also
       undergo the process, as well as iron oxides, barite, anhydrite,
       zeolites, and clay minerals.
       It is unclear just how and when the cement is deposited. Part
       seems to originate within the formation, and part seems to be
       brought in from outside by circulating waters.
       The reverse process is called dissolution. There is evidence
       that dissolution has occurred in calcareous sandstones, in which
       case the calcareous cement or grains are broken down in the same
       manner as the solution of limestones. The frosted and etched
       surfaces of quartz grains in some friable and loosely cemented
       sandstones seem to indicate the former presence of a carbonate
       cement that has been leached.
       DIAGENESIS
  HTML http://www.earth.northwestern.edu/public/seth/107/Rocks/lithification.htm
       (William Deering Professor
       and Institute for Policy Research Associate
       Department of Earth and Planetary Sciences
       Room F498, 2145 Sheridan Road
       Northwestern University,  Evanston, IL 60208-3130
       Telephone: (847) 491-5265   FAX:(847) 491-8060
       email: seth AT earth.northwestern.edu
       (substitute "@" for AT) GEOLOGY 107 Our Dynamic Planet Fall
       2005)
       DIAGENESIS: MINERAL CHANGES OCCUR DUE TO INCREASING TEMPERATURE
       AND PRESSURE
       FOR EXAMPLE, FLINT IS CHEMICALLY PRECIPITATED SiO2 CHANGED TO
       CRYSTALLINE ROCK
       STRUCTURAL AND TEXTURAL EVIDENCE OF EARLY LITHIFICATION IN
       FINE-GRAINED CARBONATE ROCKS
  HTML http://onlinelibrary.wiley.com/doi/10.1111/j.1365-3091.1969.tb00877.x/abstract
       Abstract
       SUMMARY
       Absence of compaction, intraformational breccias, resedimention,
       internal sediments and synsedimentary hardgrounds indicate early
       lithification of finegrained carbonate rocks. One of the factors
       controlling early lithification is the purity of lime mud. Less
       than 2% of insoluble residue (especially clay minerals) favours
       cementation and recrystallisation before further sediment
       accumulation causes compaction. Thus, early lithification is
       terminated in or near the environment of sedimentation.
       “Electrodiagenesis” is considered to be a possible mechanism for
       cementation.
       Electrodiagenesis
       Possible role of electrical currents and potentials during
       diagenesis
  HTML http://jsedres.geoscienceworld.org/content/37/2/695
       Abstract
       Experimental work by the writers suggests that electrical
       currents and potentials affect some diagenetic processes; this
       may be termed "electrodiagenesis." It was discovered that
       currents (produced chiefly by ionic exchange processes) flowing
       through sediments may stimulate cementation and the formation of
       authigenic minerals such as gibbsite, limonite, calcite,
       hydrohematite, hydrogoethite (lepidocrocite), hisingerite,
       allophane, allophanoid, gypsum, hematite, magnetite, nontronite,
       trona, and natron (Na 2 CO 3 .10H 2 0). Currents may also cause
       selective ion drive and explain zonation of some trace elements,
       various minerals, etc.
       Dr. George V. Chilingarian
       Engineer and Scientist
       Petroleum Engineering and Geology
  HTML http://scip-lab.usc.edu/assets/009/53728.pdf
       - 1951–1952.  Proposed utilization of electrophoretic phenomen
       on for separation of very fine grained sediments into grades.
       Proved plating theory of chemicals which reduce viscosity of
       muds.
       - Possible Role of Electrical Currents and Potentials during
       Diagenesis
       (“Electrodiagenesis”). J. Sediment. Petrology, June 1967, pp.
       695–698.
       - 1956–1968. Worked on electrochemical stabilization of weak
       grounds, and
       electrical dewatering. Discovered that clays are destroyed on
       application of
       electrical current. Showed formation of new minerals in the
       process. Coined a new
       term “Electrodiagenesis” which explains some previously
       unexplained phenomena.
       - 1956–1968. Pioneered high-pressure compaction studies of
       sediments in USA.
       His pressure verse porosity curves are used extensively in
       petroleum industryelectrical logging, subsidence, etc.. Showed
       that chemistry of solutions squeezed out of clays changes with
       pressure. Established pressures at which oriented water begins
       to be squeezed out, and proposed a new theory of migration of
       oil. Showed possibility of estimating overburden pressure from
       X-ray analysis.
       - 1956–1968. Worked on electrochemical stabilization of weak
       grounds, and
       electrical dewatering. Discovered that clays are destroyed on
       application of
       electrical current. Showed formation of new minerals in the
       process. Coined a new
       term “Electrodiagenesis” which explains some previously
       unexplained phenomena.
       - Established definite correlation between porosity and
       permeability of carbonate rocks (microfractured) by introducing
       two additional variables-specific surface area and irreducible
       fluid saturation.
       - His work on carbonate reservoir rocks was pioneering as
       evidenced by the
       publication of the first books on the subject. For example, he
       proved that in many
       cases dolomitization gives rise to porosity. Also, he showed
       that many carbonates
       are oil-wet, at a time when most petroleum engineers and
       geologists believed that
       all rocks are water-wet.
       - Through extensive laboratory experiments he proposed the use
       of electric current in well stimulation and in secondary and
       tertiary oil recovery.
       - He showed that sands are just as compactable as clays.
       - It is well established that in many cases there is very poor
       correlation between
       porosity and permeability. Yet; if one uses Professor
       Chilingarian's definition of
       “effective porosity,” namely, porosity excluding pores and
       cracks occupied by the
       irreducible fluid, then there is indeed a very good correlation
       between “effective
       porosity” and permeability.
       -----
       Minerals in Sediments
  HTML http://homepage.usask.ca/~mjr347/prog/geoe118/geoe118.021.html
       (c) Department of Civil and Geological Engineering, University
       of Saskatchewan, 57 Campus Drive, Saskatoon, SK, Canada, S7N 5A9
       Three sedimentary rocks are important volumetrically. They are:
       MUDSTONE(shale), SANDSTONE, and LIMESTONE. These very common
       rocks contain a very limited set of 5 or 6 minerals:
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