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       #Post#: 77--------------------------------------------------
       Traces of Cat.
       By: Admin Date: January 29, 2017, 4:46 am
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       Contents
       Chapter 1: LANDSCAPES WITH CRATERS: METEORITE IMPACTS,
       EARTH, AND THE SOLAR SYSTEM..... 1
       1.1. The New Geology: Meteorite Impacts on the Earth ..... 1
       1.2. The Planetary Perspective..... 4
       1.3. A Peculiar Process: Why Impacts are Different ..... 6
       1.3.1. Rarity ..... 7
       1.3.2. Immense Energy ..... 7
       1.3.3. Instant Effects ..... 7
       1.3.4. Concentrated Energy Release ..... 8
       1.3.5. Extreme Physical Conditions ..... 9
       1.3.6. Unique Deformation Effects ..... 10
       Chapter 2: TARGET EARTH: PRESENT, PAST, AND FUTURE .....11
       2.1. Comets and Asteroids: The Killer Neighbors? ..... 11
       2.1.1. Asteroids ..... 11
       2.1.2. Comets ..... 11
       2.1.3. Close Encounters ..... 12
       2.2. In Our Time: Small Catastrophes ..... 12
       2.3. The Problems of Prediction: How Big, How Often? ..... 12
       2.3.1. Ingredients of Catastrophe ..... 12
       2.3.2. Uncertain Estimates ..... 13
       2.3.3. An Uncertain Future? ..... 16
       Chapter 3: FORMATION OF IMPACT CRATERS .....17
       3.1. Shock Waves and Crater Formation ..... 17
       3.1.1. Contact/Compression Stage ..... 18
       3.1.2. Excavation Stage: The Transient Crater ..... 20
       3.1.3. Modification Stage ..... 23
       3.2. Simple and Complex Impact Structures ..... 23
       3.2.1. Simple Craters ..... 23
       3.2.2. Complex Craters ..... 24
       3.2.3. Multiring Basins ..... 27
       3.3. Subsequent Development of Impact Structures ..... 28
       Chapter 4: SHOCK-METAMORPHIC EFFECTS IN ROCKS AND MINERALS
       .....31
       4.1. Formation Conditions and General Characteristics ..... 31
       4.2. Stages of Shock Metamorphism ..... 36
       4.3. Megascopic Shock-Deformation Features: Shatter Cones .....
       36
       4.4 High-Pressure Mineral Polymorphs ..... 40
       4.5. Planar Microstructures in Quartz ..... 42
       4.5.1. Planar Fractures ..... 42
       4.5.2. Planar Deformation Features (PDFs) ..... 42
       4.5.3. PDF Orientations ..... 49
       4.5.4. PDFs in Sedimentary Rocks ..... 52
       4.6. Planar Microstructures in Feldspar and Other Minerals .....
       53
       4.7. Shock Isotropization and Diaplectic Glasses ..... 55
       4.8. Selective Mineral Melting ..... 57
       vi
       Chapter 5: SHOCK-METAMORPHOSED ROCKS (IMPACTITES) IN
       IMPACT STRUCTURES .....61
       5.1. Rock Types in the Final Impact Structure ..... 61
       5.2. Classification of Impactites ..... 62
       5.3. Subcrater Rocks ..... 62
       5.3.1. Formation Conditions ..... 62
       5.3.2. In-Place Shock-Metamorphosed Rocks ..... 63
       5.3.3. Lithic Breccias (Parautochthonous) ..... 64
       5.3.4. Cross-Cutting (Allogenic) Breccias ..... 64
       5.3.5. Pseudotachylite ..... 65
       5.4. Crater Interior: Crater-Fill Deposits (Breccias and Melt
       Rocks) ..... 69
       5.4.1. Formation Conditions ..... 69
       5.4.2. Lithic Breccias (Allogenic) ..... 71
       5.4.3. Melt-Fragment Breccias (Allogenic) (Suevites) ..... 71
       5.4.4. Melt-Matrix Breccias (Impact-Melt Breccias) ..... 74
       5.5. Crater Rim Zone and Proximal Ejecta Deposits ..... 74
       5.6. Distal Ejecta ..... 78
       Chapter 6: IMPACT MELTS .....79
       6.1. Formation Conditions ..... 79
       6.2. Impact Melt Volumes and Crater Size ..... 81
       6.3. Impact Melt Varieties in the Near-Crater Environment.....
       82
       6.3.1. Small Glassy Bodies ..... 82
       6.3.2. Impact Melt Breccias ..... 82
       6.3.3. Large Crystalline Bodies (Dikes and Sills) ..... 86
       6.4. Impact Melt in Distal Ejecta ..... 87
       6.4.1. Spherules ..... 88
       6.4.2. Tektites and Microtektites ..... 89
       6.4.3. Miscellaneous Impact Glasses ..... 90
       6.5. Recognition of Impact Melt Rocks ..... 90
       Chapter 7: HOW TO FIND IMPACT STRUCTURES .....97
       7.1. Reasons for the Search ..... 97
       7.2. Detection of Candidate Impact Sites ..... 97
       7.2.1. Geological Features ..... 98
       7.2.2. Geophysical Features ..... 98
       7.3. Verification of Impact Structures ..... 99
       Chapter 8: WHAT NEXT? CURRENT PROBLEMS AND
       FUTURE INVESTIGATIONS ..... 101
       8.1. Identification of New Impact Structures ..... 101
       8.2. Impact Events and Extinctions ..... 101
       8.3. Distal Impact Ejecta ..... 102
       8.4. Carbon Chemistry in the Impact Environment ..... 102
       8.5. Postimpact Processes and Effects ..... 103
       8.6. Petrogenesis of Igneous Rocks: Impact Melts ..... 103
       8.7. Impacts and the Early Earth ..... 104
       Appendix ..... 107
       References ..... 111
       1.3. A PECULIAR PROCESS: WHY IMPACTS
       ARE DIFFERENT
       Large impact events differ in many ways from more familiar
       geological processes like volcanic explosions, earthquakes,
       and the slow movements of plate tectonics. Much of
       the past confusion and controversy about meteorite impact
       on Earth has arisen from the fact that the chief features
       of large impact events are unfamiliar to geologists and the
       public alike.
       1.3.1. Rarity
       Unlike other geological processes, large meteorite impacts
       are rare, even over geological timescales, and there have been
       (fortunately) no historical examples of such events. For most
       people, the impact process involves only the occasional falls
       of small meteorites, which produce excitement and public
       interest, but only occasional minor damage. This lack of direct
       human experience with large impact events sets them
       apart from more familiar recurrent geological “catastrophes”
       such as floods, earthquakes, and volcanic eruptions and makes
       them harder to appreciate.
       1.3.2. Immense Energy
       Large impact events release energies that are almost
       incomprehensibly
       large by the more familiar standards of earthquakes
       and volcanic explosions. The energy of an impact
       event is derived from the kinetic energy of the impacting
       projectile and is equal to 1/2 mv2, where m is the projectile
       mass and v its velocity. Because velocities of impacting objects
       are high, typically tens of kilometers per second, kinetic
       energies are also large, even for small objects (for details,
       see below and Table 2.1). An object only a few meters across
       carries the kinetic energy of an atomic bomb, and its impact
       could devastate a large city. Furthermore, unlike earthquakes
       and volcanic explosions, where the properties of Earth itself
       provide some upper bounds to the energy release, the impact
       energy is limited only by the mass and velocity of the
       projectile. The impact of an object only a few kilometers
       across (still smaller than many known asteroids and comets)
       can release more energy in seconds than the whole Earth
       releases (through volcanism, earthquakes, tectonic processes,
       and heat flow) in hundreds or thousands of years.
       1.3.3. Instant Effects
       Another critical difference between impacts and other
       geological processes is that the energy release in an impact
       event — and the formation of the resulting crater — is vir-
       tually instantaneous. At the instant of impact, the object’s
       kinetic energy is converted into intense high-pressure shock
       waves, which radiate rapidly outward from the impact point
       through the target rocks at velocities of a few kilometers per
       second (see e.g., Melosh, 1989, Chapters 3–5). Large volumes
       of target rock are shattered, deformed, melted, and even
       vaporized in a few seconds, and even large impact structures
       form in only minutes. A 1-km-diameter crater [about the
       size of Barringer Meteor Crater (Arizona)] forms in a few
       seconds. A 200-km-diameter structure [like Sudbury
       (Canada) or Vredefort (South Africa)] forms in less than
       10 minutes, although subsequent geological adjustments,
       largely driven by gravity, will continue for many years.
       1.3.4. Concentrated Energy Release
       Most forms of internal terrestrial energy (heat flow, seismic
       waves) are released over large areas that are subcontinental
       to global in extent. By contrast, the energy of an impact
       event is released instantly, at virtually a single point on
       Earth’s
       surface. Most of the energy passes, directly and rapidly, into
       the near-surface target rocks, the atmosphere, and the
       biosphere,
       where it can produce immediate and catastrophic
       changes.
       A small impact, releasing the energy of only a few million
       tons of TNT (approximately the amount released by a
       hydrogen bomb), is similar in total energy to a severe
       earthquake
       or volcanic explosion, and its effects will be largely
       local (e.g., Kring, 1997). But a large impact transmits so much
       energy into the target that an impact structure tens or hundreds
       of kilometers in diameter is formed, accompanied by
       catastrophic environmental effects on a continental or global
       scale.
       The near-surface release of impact energy, and the transfer
       of much of the energy directly into the biosphere, makes
       large impact events especially effective in causing devastating
       and widespread biological extinctions. Current impactrelated
       models for the major Cretaceous-Tertiary (K/T)
       extinction (e.g., Silver and Schultz, 1982; Sharpton and Ward,
       1990; Kring, 1993; Ryder et al., 1996) indicate that, during
       the impact that formed the Chicxulub crater at 65 Ma, as
       much as 25–50% of the projectile’s original kinetic energy
       was converted into heat. This heat not only vaporized the
       projectile itself, but also melted and vaporized large volumes
       of the near-surface sedimentary target rocks, releasing large
       amounts of CO2 (from carbonates) and SO2 (from evaporites).
       Introduced into Earth’s atmosphere, together with large
       quantities of impact-produced dust, these gases and their
       reaction products could produce major environmental effects:
       immediate darkening and cooling, subsequent global warming,
       and deluges of acid rain. Any of these consequences, or
       a combination of them, could have produced the resulting
       widespread extinction.
       1.3.5. Extreme Physical Conditions
       The mechanism by which impacts do their work — generation
       and transmission of intense shock waves through the
       target rocks — is also unfamiliar to many geologists. Under
       normal conditions, rocks in Earth’s crust and upper mantle
       are subjected to static load pressures produced by the weight
       of overlying rocks. These pressures are less than a few
       gigapascals (GPa) (1 GPa, a standard unit of pressure, equals
       104 bar or about 104 atm). Normal geological stresses within
       Earth generate relatively low strain rates (typically10–3/s
       to 10–6/s), and rocks either deform slowly at lower pressures
       or fracture at higher pressures when their yield strengths (a
       few GPa) are exceeded. The general tendency of terrestrial
       rocks to fracture when the pressure gets too high, thus
       releasing
       the pressure, limits the pressure buildup in ordinary
       geological processes (e.g., earthquakes) to a few GPa.
       These “normal” conditions do not exist in impact events.
       The rapid release of large amounts of energy in such events
       puts too much sudden stress on the target rocks for them to
       respond in the normal way. Typical impact velocities of tens
       of kilometers per second far exceed the velocities of sound in
       the target rocks (typically 5–8 km/s). The resulting
       impactproduced
       shock waves travel through the target rocks at supersonic
       velocities, and they impose intense stresses on the
       rocks without giving them time to give way by normal
       deformation.
       In the shock-wave environment, transient pres-
       sures may exceed 500 GPa at the impact point and may be
       as high as 10–50 GPa throughout large volumes of the
       surrounding target rock. Transient strain rates may reach
       104/s –106/s, orders of magnitude higher than those in ordinary
       geological processes. At the higher shock pressures
       (>60 GPa), shock-produced temperatures can exceed
       2000°C, and rapid, large-scale melting occurs immediately
       after the shock wave has passed.
       1.3.6. Unique Deformation Effects
       The extreme physical conditions of pressure, temperature,
       and strain imposed by transient shock waves produce
       unique effects (e.g., mineral deformation, melting) in the
       rocks and mineral grains through which they pass. These
       shock-metamorphic effects are distinct from features produced
       by normal geological deformation, and they are now
       generally accepted as unique products of impact events (for
       reviews and references, see French and Short, 1968; Stöffler,
       1972, 1974; Stöffler and Langenhorst, 1994; Grieve et al.,
       1996).
       Shock-metamorphic effects (or “shock effects”) have been
       crucial in establishing the importance of extraterrestrial
       impact
       events. Preserved meteorites around an impact crater
       can provide definite evidence of an impact origin, but only a
       small fraction of terrestrial impact structures (about a dozen)
       have actual preserved meteorites associated with them. These
       structures are all relatively small and geologically young. The
       Barringer Meteor Crater (Arizona), 1.2 km in diameter and
       about 50,000 years old (Fig. 1.1), is the largest member of
       this group.
       The absence of meteorite fragments around older impact
       craters results from two causes: (1) the projectile itself is
       also
       subjected to the intense shock waves generated by the impact,
       and it is almost completely melted and vaporized;
       and (2) all meteorites are partly to completely composed of
       nickel-iron metal, and even surviving fragments of the
       projectile
       tend to be rapidly destroyed by surface weathering,
       except in the driest desert regions or on polar icecaps.
       The rapid destruction of meteorites means that other lines
       of evidence must be used to identify older or deeply eroded
       terrestrial impact structures. Shock-metamorphic effects can
       be preserved in rocks for periods of 106–109 years, and they
       provide a unique means of identifying impact structures,
       especially
       ones that are old, deeply eroded, or both (French
       and Short, 1968). The great majority of currently known
       impact structures (currently over 150) have no preserved
       meteorites,
       but have been identified by the discovery of shockmetamorphic
       effects in their rocks (Grieve, 1991; Grieve et
       al., 1995; Grieve and Pesonen, 1992, 1996).
       #Post#: 78--------------------------------------------------
       Re: Traces of Cat.
       By: Admin Date: January 29, 2017, 4:48 am
       ---------------------------------------------------------
       Formation of Impact Craters 17
       17
       The processes by which large impact craters form, and
       the sudden releases of huge quantities of energy involved,
       cannot be duplicated in the laboratory, and, fortunately, no
       such structure has formed during recorded human history.
       All our knowledge about large impact structures is therefore
       indirect, and it has come from combining several areas of
       once-separate research: theoretical and experimental studies
       of shock waves (for reviews and literature, see Melosh,
       1989), experimental production of small craters (e.g., Gault
       et al., 1968; Gault, 1973; Holsapple and Schmidt, 1982, 1987;
       papers in Roddy et al., 1977), and geological studies of larger
       terrestrial impact structures (Shoemaker, 1963; Dence, 1968;
       Dence et al., 1977; Grieve and Cintala, 1981; Grieve et al.,
       1981; Schultz and Merrill, 1981; Stöffler et al., 1988). The
       cratering process is complex, many details are still uncertain,
       and neither calculations nor predictions can be made with
       firm confidence. But these studies provide the essential basis
       for understanding how impact craters form and for deciphering
       the geological features they display.
       3.1. SHOCK WAVES AND
       CRATER FORMATION
       The general term “impact crater” is used here to designate
       a hypervelocity impact crater, the structure formed by
       a cosmic projectile that is large enough and coherent enough
       to penetrate Earth’s atmosphere with little or no deceleration
       and to strike the ground at virtually its original cosmic
       velocity (>11 km/s). Such projectiles tend to be relatively
       large, perhaps >50 m in diameter for a stony object and >20 m
       for a more coherent iron one.
       Smaller projectiles, typically a few meters or less in size,
       behave differently in passing through the atmosphere. They
       lose most or all of their original velocity and kinetic energy
       in the atmosphere through disintegration and ablation, and
       they strike the ground at speeds of no more than a few hundred
       meters per second. In such a low-velocity impact, the
       projectile penetrates only a short distance into the target
       (depending
       on its velocity and the nature of the target material),
       and the projectile’s momentum excavates a pit that is
       slightly larger than the projectile itself. The projectile
       survives,
       more or less intact, and much of it is found in the
       bottom of the pit. Such pits, sometimes called penetration
       craters or penetration funnels, are typically less than a few
       tens of meters in diameter.
       Examples of these features include Brenham (Kansas),
       the many small pits made by the Sikhote-Alin (Russia) meteorite
       shower in 1947, and the pit dug by the largest piece
       of the Kirin (China) meteorite fall in 1976. The process of
       excavation is strictly a mechanical one, and high-pressure
       shock waves are not produced.
       In sharp contrast, a hypervelocity impact crater starts to
       form at the instant that an extraterrestrial object strikes the
       ground surface at its original cosmic velocity. These impact
       velocities are much greater than the speed of sound in the
       target rocks, and the crater is produced by intense shock
       waves that are generated at the point of impact and radiate
       outward through the target rocks. Shock waves are intense,
       transient, high-pressure stress waves that are not produced
       by ordinary geological processes (for details, see Melosh, 1989,
       Chapter 3 and references therein). Peak shock pressures produced
       at typical cosmic encounter velocities may reach several
       hundred GPa. These pressure are far above the stress
       levels (~1 GPa) at which terrestrial rocks undergo normal
       elastic and plastic deformation, and the shock waves produce
       unique and permanent deformation effects in the rocks
       through which they pass.
       The shock waves radiate from the impact point at high
       velocities that may exceed 10 km/s, much greater than the
       speed of sound in the target rocks. As they expand, they
       interact
       with the original ground surface to set a large volume
       of the target rock into motion, thus excavating the impact
       crater. The formation of an impact crater by shock waves,
       Formation of Impact Craters
       18 Traces of Catastrophe
       and the immediate modification of the newly formed crater
       by gravity and rock mechanics, is a complex and continuous
       process. However, it is convenient to divide this process,
       somewhat arbitrarily, into three distinct stages, each dominated
       by different forces and mechanisms: contact and compression,
       excavation, and modification (Gault et al., 1968;
       see also Melosh, 1989, Chapters 4, 5, and 8).
       3.1.1. Contact/Compression Stage
       This stage begins at the instant that the leading edge of
       the moving projectile makes contact with the ground surface.
       If the target is solid rock, the projectile is stopped in a
       fraction of a second and penetrates no more than 1–2× its
       own diameter (Fig. 3.1) before its immense kinetic energy is
       transferred to the target rocks by shock waves generated at
       the interface between projectile and target (Kieffer and
       Simonds, 1980; O’Keefe and Ahrens, 1982, 1993; Melosh, 1989,
       Chapter 4).
       The general features of this conversion of kinetic energy
       into shock waves have been determined from experiments
       and theoretical studies (e.g., O’Keefe and Ahrens, 1975, 1977,
       1993; Ahrens and O’Keefe, 1977; papers in Roddy et al., 1977;
       Melosh, 1989, Chapter 4), although many details are still not
       well understood. One clear result is that, as one set of shock
       waves is transmitted outward from the interface into the target
       rocks, a complementary shock wave is reflected back into
       the projectile (Fig. 3.1) (Melosh, 1989, Chapter 4; O’Keefe
       and Ahrens, 1993).
       The shock waves transmitted into the target rocks lose
       energy rapidly as they travel away from the impact point.
       Two factors are involved in this energy loss: (1) the expanding
       shock front covers an increasingly larger hemispherical
       area with increasing radial distance, thus reducing the overall
       energy density; (2) additional energy is lost to the target
       rocks through heating, deformation, and acceleration. The
       peak pressures of the shock waves therefore also drop rapidly
       with distance from the impact point. Theoretical models
       (Melosh, 1989, pp. 60–66) and geological studies of
       shock-metamorphosed rocks in individual structures (Dence,
       1968; Robertson, 1975; Grieve and Robertson, 1976; Dence et
       al., 1977; Robertson and Grieve, 1977; Dressler et al., 1998)
       indicate that the peak shock-wave pressure (Ps) drops
       exponentially
       with the distance R from the impact point according
       to an equation of the form Ps a R–n. Various field and
       laboratory studies indicate a dependence of R–2 to R–4.5; the
       exact value of the exponent depends on projectile size and
       impact velocity (Ahrens and O’Keefe, 1977).
       On the basis of these studies, it is possible to regard the
       impact point as surrounded by a series of concentric, roughly
       hemispherical shock zones, each zone distinguished by a
       certain range of peak shock pressure (Fig. 3.2) and
       characterized
       by a unique suite of shock-metamorphic effects produced
       in the rocks. At the impact point, peak shock-wave
       pressures may exceed 100 GPa (= 1000 kbar or 1 Mbar) for
       typical cosmic encounter velocities, producing total melting,
       if not vaporization, of the projectile and a large volume of
       surrounding target rock. Further outward, pressures of 10–
       50 GPa may exist over distances of many kilometers from
       the impact point, producing distinctive shock-deformation
       effects in large volumes of unmelted target rock.
       At even greater distances from the impact point, the peak
       shock-wave pressures eventually drop to about 1–2 GPa
       (Kieffer and Simonds, 1980). At this point, near the eventual
       crater rim, the shock waves become regular elastic waves or
       seismic waves, and their velocity drops to that of the velocity
       of sound in the target rocks (typically 5–8 km/s). These seismic
       waves can be transmitted throughout the entire Earth,
       like similar waves generated by earthquakes and volcanic
       eruptions. Because of their low pressures, they do not produce
       any permanent deformation of the rocks through which
       they pass. However, seismic waves may produce fracturing,
       brecciation, faulting, and (near the surface) landslides, and
       the results may be difficult to distinguish from those of normal
       geological processes.
       The duration of the contact/compression stage is determined
       by the behavior of the shock wave that was reflected
       back into the projectile from the projectile/target interface
       (Fig. 3.1) (Melosh, 1989, pp. 57–59). When this shock wave
       reaches the back end of the projectile, it is reflected forward
       into the projectile as a rarefaction or tensional wave (also
       Fig. 3.1. Contact/compression stage: shock-wave generation
       and projectile deformation. Theoretical cross-section showing
       calculated conditions immediately after the impact of a large,
       originally spherical, projectile (stippled) onto a uniform
       target. The
       projectile has penetrated about half its diameter into the
       target,
       and intense shock waves (pressures in GPa) are radiating outward
       into the target from the interface. The projectile itself has
       become
       intensely compressed, and similar shock waves from the interface
       are spreading toward the rear of the projectile. When this shock
       wave reaches the rear of the projectile, it will be reflected
       forward
       as a tensional wave or rarefaction, unloading the projectile and
       allowing it to transform, virtually instantaneously, into melt
       and
       vapor. The original model, developed for large lunar impact
       events
       (O’Keefe and Ahrens, 1975), represents conditions about 1 s
       after
       the impact of a 46-km-diameter anorthosite projectile at 15 km/s
       onto a gabbroic anorthosite target, but similar conditions will
       be
       produced by smaller impacts and other material compositions.
       (Modified from Melosh, 1989, Fig. 4.1a, p. 47.)
       Formation of Impact Craters 19
       called a release wave). As the release wave passes through
       the projectile from back to front, it unloads the projectile
       from the high shock pressures it had experienced. Because
       the shock pressures, and the associated temperatures, have
       been so high, this release results in the virtually complete
       melting and vaporization of the projectile. At the instant at
       which the release wave reaches the front end of the projectile,
       the whole projectile is unloaded, and the release wave
       continues forward into the target and begins to decompress
       it as well. This point, at which the release wave reaches the
       front of the projectile and begins to enter the adjacent
       compressed
       target, is taken as the end of the complete contact/
       compression stage.
       The contact/compression stage lasts no more than a few
       seconds, even for impacts of very large objects. The time
       required for the shock wave to travel from the projectile/
       target interface to the rear edge of the projectile is
       approximately
       equal to the time it takes the projectile to travel the
       distance of one diameter at its original velocity. Even for
       large projectiles, this time is short: 2 s for a 50-km-diameter
       projectile traveling at 25 km/s, and less than 0.01 s for a
       100-m-diameter object traveling at the same speed. The
       additional time required for the release wave to travel from
       the rear to the front edge will be no more than a few times
       this value, depending on the properties of projectile and target
       rock (Melosh, 1989, pp. 48 and 58). For most impact
       events, the entire contact/compression stage is over in less
       than a second.
       After the release wave has reached the front end of the
       projectile and unloaded it completely, the projectile itself
       plays
       no further role in the formation of the impact crater, and the
       actual excavation of the crater is carried out by the shock
       waves expanding through the target rocks. The vaporized
       portion of the projectile may expand out of the crater as part
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       􀀀􀀀􀀀
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       􀀀
       Fig. 3.2. Contact/compression stage: initial shock-wave
       pressures and excavation flow lines around impact point.
       Schematic crosssection
       showing peak shock pressure isobars (pressures in GPa) developed
       in the target around the impact point near the end of the
       contact/compression stage. The originally spherical projectile,
       after penetrating about two diameters into the target, has been
       almost
       completely destroyed and converted to melt and vapor. Shock
       waves radiating from the projectile-target interface decline
       rapidly outward
       in peak pressure (isobars in GPa on left side of cavity),
       creating concentric, approximately hemispherical zones of
       distinctive shock effects
       (right side of cavity). From the original interface outward,
       these zones involve: (1) melting (>50 GPa) and formation of a
       large melt unit;
       (2) shock-deformation effects (5–50 GPa); (3) fracturing and
       brecciation (1–5 GPa). The subsequent excavation stage involves
       two
       processes: (1) upward ejection (spalling) of large near-surface
       fragments and smaller ejecta (ejecta curtain) (upward-pointing
       arrows
       above ground surface); (2) subsurface flow of target material to
       form the transient crater (arrow paths crossing isobars at left
       side).
       (Modified from Melosh, 1989, Fig. 5.4, p. 64.)
       20 Traces of Catastrophe
       of a vapor plume (Melosh, 1989, pp. 68–71), and the remainder,
       virtually all melted, may be violently mixed into the
       melted and brecciated target rocks.
       3.1.2. Excavation Stage: The Transient Crater
       The brief contact/compression stage grades immediately
       into a longer excavation stage, during which the actual impact
       crater is opened up by complex interactions between
       the expanding shock waves and the original ground surface
       (Fig. 3.3) (Melosh, 1989, Chapter 5; Grieve, 1991). As the
       contact/compression stage ends, the projectile is surrounded
       by a roughly hemispherical envelope of shock waves that
       expand rapidly through the target rock. Because the projectile
       has penetrated a finite distance into the target, the center
       of this hemisphere actually lies within the original target
       rock at a point below the original ground surface.
       Within this hemispherical envelope, the shock waves that
       travel upward and intersect the original ground surface are
       reflected downward as rarefactions (release waves). In a
       nearsurface
       region where the stresses in the tensional release
       wave exceed the mechanical strength of the target rocks,
       the release wave is accompanied by fracturing and shattering
       of the target rock (Fig. 3.2). This reflection process also
       converts some of the initial shock-wave energy to kinetic
       energy, and the rock involved is accelerated outward, much
       of it as individual fragments traveling at high velocities
       (Fig. 3.4).
       These complex processes drive the target rock outward
       from the impact point, producing a symmetric excavation
       flow around the center of the developing structure. Exact
       flow directions vary with location within the target rocks
       (Fig. 3.4). In the upper levels, target material moves
       dominantly
       upward and outward. At lower levels, target material
       moves dominantly downward and outward. These movements
       quickly produce a bowl-shaped depression (the transient
       cavity or transient crater) in the target rocks (Maxwell,
       1977; Grieve at al., 1977; Grieve and Cintala, 1981; Melosh,
       1989, pp. 74–78).
       The transient crater is divided into approximately equal
       upper and lower zones (Figs. 3.4 and 3.5). Within the upper
       ejection zone, velocities imparted to the target rocks may be
       as high as several kilometers per second, high enough to
       excavate
       the fragmented material and to eject it beyond the
       rim of the final crater (Grieve et al., 1977; Dence et al.,
       1977;
       Fig. 3.3. Development of a simple impact structure. Series of
       cross-section diagrams showing progressive development of a
       small,
       bowl-shaped simple impact structure in a horizontally layered
       target: (a) contact/compression stage: initial penetration of
       projectile,
       outward radiation of shock waves; (b) start of excavation stage:
       continued expansion of shock wave into target; development of
       tensional
       wave (rarefaction or release wave) behind shock wave as the
       near-surface part of original shock wave is reflected downward
       from ground
       surface; interaction of rarefaction wave with ground surface to
       accelerate near-surface material upward and outward; (c) middle
       of
       excavation stage: continued expansion of shock wave and
       rarefaction wave; development of melt lining in expanding
       transient cavity;
       well-developed outward ejecta flow (ejecta curtain) from the
       opening crater; (d) end of excavation stage: transient cavity
       reaches maximum
       extent to form melt-lined transient crater; near-surface ejecta
       curtain reaches maximum extent, and uplifted crater rim
       develops; (e) start
       of modification stage: oversteepened walls of transient crater
       collapse back into cavity, accompanied by near-crater ejecta, to
       form
       deposit of mixed breccia (breccia lens) within crater; (f )
       final simple crater: a bowl-shaped depression, partially filled
       with complex
       breccias and bodies of impact melt. Times involved are a few
       seconds to form the transient crater (a)–(d), and minutes to
       hours for the
       final crater (e)–(f ). Subsequent changes reflect the normal
       geological processes of erosion and infilling.
       Kieffer and Simonds, 1980; Melosh, 1989, pp. 74–76). Even
       at significant distances from the impact point, shock pressures
       and the resulting ejection velocities remain high enough
       (>100 m/s) to eject material. For this reason, the diameter of
       the final crater is many times larger (typically 20–30×) than
       the diameter of the projectile itself.
       At deeper levels, tensional stresses in the release waves
       are lower. As a result, fracturing is less pronounced,
       excavation
       flow velocities are lower, and the excavation flow lines
       themselves are not oriented to eject material beyond the crater
       rim (Fig. 3.4). This region forms a displaced zone in
       which material is driven downward and outward more or
       less coherently.
       Both zones in the transient crater continue to expand,
       accompanied by the uplift of near-surface rocks to form the
       transient crater rim, as long as the expanding shock waves
       and release waves are strong enough to eject or displace
       material
       from the developing cavity. However, these waves continually
       lose energy by deforming and ejecting the target rocks
       through which they pass. Eventually, a point is reached at
       which the shock and release waves can no longer excavate or
       displace target rock. At that point the growth of the transient
       crater ceases. There is an instant of theoretical balance
       in which the energies of the shock wave no longer act, and
       the waiting forces of gravity and rock mechanics have not
       yet reasserted themselves. At this instant, the transient crater
       reaches its maximum extent, the excavation stage ends,
       and the subsequent modification stage begins immediately.
       The excavation stage, although longer than the contact/
       compression stage, is still brief by geological standards. If
       the near-surface excavation flow has a minimum average velocity
       of 1 km/s, then a 200-km-diameter transient crater
       can be excavated in less than 2 min. More detailed calculations
       (Melosh, 1989, p. 123) indicate that excavation of a
       l-km-diameter crater (e.g., Barringer Meteor Crater [Arizona])
       will occur in about 6 s, while a 200-km-diameter
       crater requires only about 90 s.
       The concept of the transient crater has been developed
       from a combination of theoretical studies (Melosh, 1989,
       Chapter 5) and geological investigations (Dence, 1968; Grieve
       and Cintala, 1981; Grieve et al., 1981). The ideal transient
       crater is a bowl-shaped depression with a structurally uplifted
       rim (Figs. 3.4 and 3.5). Its shape is approximately
       hemispherical but is actually a paraboloid of revolution
       Formation of Impact Craters 21
       􀀀􀀀􀀀
       􀀀􀀀􀀀
       􀀀􀀀􀀀
       22 Traces of Catastrophe
       􀀀􀀀
       􀀀􀀀􀀀
       􀀀􀀀􀀀
       􀀀􀀀
       Fig. 3.4. Excavation stage: formation of transient crater.
       Theoretical cross section showing development of the transient
       crater
       immediately after the contact/compression stage. Original peak
       shock pressures (units in GPa) around the impact point are shown
       for
       simplicity as hemispherical isobars (for details, see Fig. 3.2).
       Complex interactions of the shock wave, the ground surface, and
       the
       subsequent rarefaction wave produce an outward excavation flow
       (dashed arrows) that opens up the transient crater. In the upper
       part of
       this region (excavated zone; ruled area), target material is
       fractured, excavated, and ejected beyond the transient crater
       rim. In the lower
       region (displaced zone), target material is driven downward and
       outward, more or less coherently, and does not reach the
       surface. This
       model yields two important geological results: (1) ejected
       material is derived only from the upper part (approximately the
       top one-third
       to one-half ) of the transient cavity; (2) because the
       excavation flow lines in the excavated zone cut across the
       initially hemispherical shock
       isobars, ejected material will reflect a wide range of original
       shock pressures and deformation effects, ranging from simple
       fracturing to
       complete melting and vaporization. (Modified from Grieve, 1987,
       Fig. 5; Hörz et al., 1991, Fig. 4.3a, p. 67.)
       Fig. 3.5. Transient crater: locations of shock-metamorphosed
       materials. Cross section through a theoretical transient crater,
       showing
       discrete zones from which various shock-metamorphosed materials
       are derived. The “vaporized” zone closest to the original impact
       point
       (stippled) contains a mixture of vaporized target rock and
       projectile, which expands upward and outward into the atmosphere
       as a vapor
       plume. The adjacent “melt” zone (solid black) consists of melt
       that moves downward and then outward along the floor of the
       final
       transient cavity (for details, see Fig. 6.2). Material in the
       upper “ejected” zones on either side of the melt zone, which
       contains a range of
       shock-metamorphic effects, is ejected outward to and beyond the
       transient crater rim. The lower “displaced” zone moves downward
       and
       outward to form the zone of parautochthonous rocks below the
       floor of the final transient crater. Hat = the final transient
       crater depth;
       Hexc = the depth of excavation, which is significantly less than
       the total depth. (From Melosh, 1989, Fig. 5.13, p. 78.)
       􀀀􀀀
       􀀀􀀀
       Formation of Impact Craters 23
       (Dence, 1973). Its maximum depth is approximately onethird
       its diameter, and this proportion seems to remain
       approximately constant for craters of widely different size
       (Maxwell, 1977; Croft, 1985).
       The theoretical instant of ideal overall balance in a transient
       crater at the end of the excavation stage may not be
       actually attained during formation of a real crater. For
       example,
       in these models, the maximum diameter is normally
       attained after the maximum depth is reached. Subsequent
       modification of one part of an actual transient crater might
       therefore begin while other parts are still being excavated.
       Even so, the transient crater is a key concept in models of
       crater formation. All impact structures, regardless of their
       final size or the complexity of their subsequent development,
       are assumed to pass through the transient-crater stage, making
       this stage of critical importance in comparing impact
       structures of different sizes or on different planets. Defining
       the transient crater is also an essential step in determining
       critical characteristics of an impact structure: its original
       (pre-erosion) diameter and depth, the energy of impact, the
       size and velocity of the projectile, the distribution of shock
       pressures and shock effects within the crater, the amount of
       material melted and ejected during formation of the crater,
       the amount of structural uplift during formation of the central
       peak of complex impact structures, and the depth from
       which excavated materials were derived.
       3.1.3. Modification Stage
       The excavation stage ends when the transient crater has
       grown to its maximum size, and the subsequent modification
       stage begins immediately. The expanding shock waves
       have now decayed to low-pressure elastic stress waves beyond
       the crater rim, and they play no further part in the
       crater development. Instead, the transient crater is immediately
       modified by more conventional factors like gravity and
       rock mechanics.
       The immediate part of the modification stage, during
       which the major impact-related changes occur, lasts only
       slightly longer than the excavation stage: less than a minute
       for a small structure, a few minutes for a large one (Melosh,
       1989, Chapter 8, pp. 141–142). (One simple definition is
       that the modification stage ends “when things stop falling.”)
       However, the modification stage has no clearly marked end,
       and the modification processes of uplift and collapse merge
       gradually into the normal processes of geological mass movement,
       isostatic uplift, erosion, and sedimentation.
       3.2. SIMPLE AND COMPLEX
       IMPACT STRUCTURES
       The extent to which the transient crater is altered during
       the modification stage depends on its size and (to a lesser
       extent) on the structure and properties of the target rock.
       Small transient craters are altered chiefly by the collapse of
       their upper walls, and the shape of the final crater is little
       changed from that of the original transient crater. In larger
       structures, modification may involve major structural
       changes: uplift of the central part of the floor and major
       peripheral collapse around the rim. Depending on the extent
       to which the transient crater is modified, three distinct
       types of impact structures can be formed: simple craters,
       complex craters, and multiring basins.
       3.2.1. Simple Craters
       The smallest impact structures occur as bowl-shaped depressions
       (simple craters) less than a few kilometers across,
       which help to preserve the shape and dimensions of the original
       transient cavity (Figs. 1.1 and 3.6). In evolving to a simple
       crater, the transient crater is modified only by minor collapse
       of the steep upper walls into the crater cavity and by
       redeposition of a minor amount of ejected material in the
       crater. As a result, the crater diameter may increase by as
       much as 20%, but the original transient crater depth remains
       largely unaffected (Fig. 3.7) (Melosh, 1989, p. 129).
       During modification, the simple crater is immediately
       filled, to perhaps half its original depth, by a mixture of
       redeposited
       (fallback) ejecta and debris slumped in from the
       walls and rim (Fig. 3.7). This crater-filling unit, variously
       called the breccia lens or crater-fill breccia, is a mixture of
       rock fragments, both shocked and unshocked, together with
       fragments or lenses of shock-melted rock (impact melt).
       Fig. 3.6. A simple lunar impact crater. This small,
       well-preserved
       crater (Moltke: D = 7 km) shows features typical of simple
       impact
       craters: a circular outline, a bowl-like shape, an uplifted rim,
       and
       hummocky deposits of ejecta around the rim. In the relatively
       low
       gravity of the Moon, this structure formed as a simple crater; a
       terrestrial structure of the same diameter, formed under Earth’s
       higher gravity, would have formed as a complex crater with a
       central
       uplift. (Apollo 10 image AS10-29-4324.)
       24 Traces of Catastrophe
       Fig. 3.7. Simple impact structure: locations of impactite types.
       Schematic cross section of a typical simple impact structure,
       showing
       the simple bowl shape and the locations of various types of
       impactites in and around the structure. The parautochthonous
       rocks below
       the true crater floor are fractured and brecciated but generally
       show no distinctive shock effects, except in a small zone (fine
       vertical
       ruling) in the center of the structure. The crater is filled, to
       approximately half its original height, with a variety of
       allogenic breccias and
       impact melts, which forms the crater-fill units or the breccia
       lens. A thinner layer of ejected material (fallout ejecta)
       overlies the uplifted
       crater rim and surrounds the crater. This unit is easily eroded
       and is present only in the youngest and best-preserved
       structures. D = final
       crater diameter, which is 10–20% greater than the diameter of
       the original, premodification transient crater; dt = true depth
       of the final
       crater, which is approximately the depth of the original
       transient crater; da = apparent depth of the crater, or the
       depth from the final rim
       to the top of the crater-fill units. The diagram represents the
       state of the final crater before any subsequent geological
       effects, e.g., erosion,
       infilling. The model is based on drilling studies at Barringer
       Meteor Crater (Arizona) (Roddy et al., 1975; Roddy, 1978), Brent
       Crater
       (Canada) (Dence, 1968; Grieve and Cintala, 1981), and similar
       structures (e.g., Masaitis et al., 1980; Gurov and Gurova,
       1991). (From
       Grieve, 1987, Fig. 1.)
       Depending on the subsequent geological history, the breccia
       lens may be eroded or may be covered and preserved by a
       cap of later sedimentary fill.
       3.2.2. Complex Craters
       The bowl-shaped form of simple craters appears only in
       relatively small structures less than a few kilometers across.
       Larger impact structures (complex craters) display a different
       and more complicated form, characterized by a centrally
       uplifted region, a generally flat floor, and extensive inward
       collapse around the rim (Figs. 1.3, 3.8, and 3.9) (Dence, 1968;
       Grieve et al., 1977, 1981; Grieve, 1991). For terrestrial
       structures,
       the transition between simple and complex craters
       occurs at a diameter of about 4 km in massive crystalline
       rocks, but at only about 2 km in sediments. (However, these
       values apply only to Earth. The transition diameter varies
       inversely with gravitational acceleration, and it is different
       on different planets.) The larger impact events that form
       complex craters apparently release enough energy to overcome
       the fundamental strength of the target rocks over a
       large volume beneath the large transient crater. As a result,
       late-stage modification involves complex interactions between
       shock-wave effects, gravity, and the strength and structure
       of the target rocks, and the modification is characterized
       by outward, inward, and upward movements of large volumes
       of the subcrater rocks.
       The details of these interactions are uncertain, but the
       general result is that the original bowl-shaped transient crater
       is immediately modified as deep-seated rocks beneath
       the center of the transient crater rise to form a central uplift
       (Dence, 1968; Grieve et al., 1981). At the same time, rocks
       around the periphery of the transient crater collapse downward
       and inward along concentric faults to form one or more
       depressed rings (ring grabens) and a series of terraces along
       the outer margins of the final structure (Fig. 3.10). [A simple
       model of the formation of a complex crater and its central
       uplift is presented by the familiar slow-motion movies of a
       drop of liquid hitting a liquid surface (e.g., Melosh, 1989,
       p. 148; Taylor, 1992, p. 168). There is the same initial cavity
       formation, the same outward and downward ejection of target
       material, the same upward rebound of the central cavity
       floor, and the same collapse of the periphery back into the
       cavity. However, in impact events, these processes take place
       in solid rock and may operate over distances of tens to hundreds
       of kilometers.]
       The idea that such rapid deformation and subsequent
       uplift can occur in large volumes of crustal rocks has been
       difficult for many geologists to appreciate. Key evidence has
       come from studies of impact structures formed in sedimentary
       rocks, in which the actual uplift of key stratigraphic
       markers has been established beyond question through drilling
       and geophysical studies (e.g., Milton et al., 1972, 1996a,b;
       Formation of Impact Craters 25
       Grieve et al., 1981; Grieve and Pilkington, 1996). Geological
       studies have also established that the amount of actual
       stratigraphic
       uplift (SU) in impact structures is about one-tenth
       the final diameter (D) of the structure. A detailed statistical
       relation derived from studies of well-constrained complex
       impact structures (Grieve et al., 1981, p. 44) is SU = 0.06 D1.1
       (both SU and D are in kilometers). A subsequent analysis,
       using more craters (Grieve and Pilkington, 1996, p. 404),
       gave SU = 0.086 D1.03. The two equations are virtually
       identical,
       and a value of SU = 0.1 D is a reasonable approximation
       to either. For large (D = 100–200 km) impact structures,
       these relations imply that the crustal rocks beneath the
       structure
       are uplifted vertically by 10–20 km during the impact
       event. An uplift of this magnitude has been estimated for
       the Vredefort (South Africa) structure on geological grounds
       (Reimold and Gibson, 1996; Therriault et al., 1997; Turtle and
       Pierazzo, 1998).
       Both theoretical and field studies indicate that central
       uplifts form in only a few minutes, almost instantaneously
       by geological standards, even in the largest structures (Melosh,
       1989, pp. 129 and 141–142). Theoretical studies also suggest
       that the central uplifts of structures 200–300 km in
       Fig. 3.8. A complex lunar crater. This relatively young crater
       (Theophilus: D = 100 km) displays well-preserved features that
       are typical of complex impact structures: a central uplift, a
       scalloped
       circular outline, ruggedly terraced walls with possible
       landslide
       deposits inside the rim, and hummocky ejecta deposits just
       outside
       the rim. This view also indicates the continuing nature of
       lunar cratering; an older impact crater (upper right) has been
       partly
       destroyed by Theophilus, while a younger small crater has formed
       within Theophilus itself (near rim, lower right). The flat dark
       area in the background (upper left) is made up of lava flows
       covering
       part of Mare Nectaris. The spiral-like rod at left center is an
       instrument boom on the Apollo 16 spacecraft, from which this
       orbital picture was taken. (Apollo 16 image AS16-M-0692.)
       Fig. 3.9. A complex impact basin on Venus. A large,
       wellpreserved
       multiring impact basin on the surface of Venus
       (Meitner: D = 150 km) is revealed beneath the planet’s opaque
       atmosphere by the imaging radar system of the Magellan
       spacecraft.
       Meitner, the third-largest impact structure identified on
       Venus, shows a flat smooth (dark-colored) interior, two circular
       rings, and a rough, irregular blanket of lobate ejecta
       (light-colored).
       The crater was formed on a surface of smooth plains, possibly
       underlain by lava flows and cut by abundant parallel fractures
       (white lines). (Magellan image F-MIDRP .55S319;201.)
       diameter, such as Vredefort (South Africa), formed in less
       than 15 minutes (Melosh, 1989, pp. 141–142; Turtle and
       Pierazzo, 1998).
       Despite the extensive evidence that central uplifts do form
       in large impact structures, the details of the process are still
       the subject of continuing uncertainty and active debate
       (Dence, 1968; Grieve et al., 1981; Melosh, 1989, Chapter 8;
       Hörz et al., 1991; Spudis, 1993). Even so fundamental a quantity
       as the ratio between the diameter of the initial transient
       crater and the diameter of the final complex impact structure
       has not been well established; values estimated by various
       workers, using both theoretical and geological studies,
       range from about 0.5 to 0.7 (see, e.g., Therriault et al., 1997,
       Table 2).
       At larger crater diameters, the resulting structures, and
       especially the centrally uplifted area, become even more
       complicated.
       As the crater size increases the character of the central
       uplift changes, and the single central peak is progressively
       replaced by a more complex series of concentric rings and
       basins. At least three types of complex impact structures can
       be distinguished with increasing crater diameter: centralpeak
       structures, central-peak-basin structures, and peak26
       Traces of Catastrophe
       Fig. 3.10. Development of a complex impact structure. Series of
       cross sections showing progressive development of a large,
       complex
       impact structure in a horizontally layered target: (a) formation
       of a large transient crater by the excavation process is
       virtually identical to
       transient crater formation in smaller structures (compare with
       Fig. 3.3a–d); (b) initial development of central uplift during
       the subsequent
       modification stage; (c) start of peripheral collapse,
       accompanied by continuing development of the central uplift and
       the thinning and
       draping of the original melt layer (black) over the uplifted
       rocks; (d) final structure, which is of the central-uplift type,
       consists of a central
       uplift of deeper rocks, surrounded by a relatively flat plain
       and by a terraced rim produced by inward movement along stepped
       normal
       faults. The central uplift is surrounded by an annular deposit
       of allogenic breccias and impact melt (black), which may be
       absent from the
       central peak itself. An ejecta layer (stippled) covers the
       target rocks around the structure. The diameter of the final
       structure, measured at
       the outer rim beyond the outermost fault, may be 1.5–2× the
       diameter of the original transient crater. This central-peak
       morphology is
       observed in terrestrial structures ranging from about 2–25 km in
       diameter; larger structures tend to develop one or more
       concentric rings
       within the crater (for details, see text).
       Formation of Impact Craters 27
       ring basin structures (Grieve at al., 1981; Melosh, 1989,
       Chapter 8; Spudis, 1993). As the terms suggest, these structures
       are characterized by the initial development of a basin
       in the central peak and eventually by the complete conversion
       of the central peak area to a ring structure (Figs. 1.3,
       3.9, and 3.11).
       These distinctions, and the transition diameters at which
       they occur, have been most clearly established on airless bodies
       like the Moon, where even large ancient structures have
       been well preserved (Figs. 3.6, 3.8, and 3.11) (e.g., Taylor,
       1982, 1992; Melosh, 1989, pp. 131–135; Spudis, 1993).
       Classification
       of large terrestrial structures (e.g., papers in Schultz
       and Merrill, 1981; Spudis, 1993, pp. 24–41) is more difficult
       and uncertain, because the impact structures, especially their
       critical upper parts, tend to be removed by erosion or buried
       by later sediments. Furthermore, the critical diameters at
       which one form changes to another depend inversely on the
       planetary gravity, making it difficult to apply data from
       structures
       on other planets to terrestrial features. For example,
       the transition between simple and complex craters occurs at
       about 20 km diameter on the Moon but at only 2–4 km on
       Fig. 3.11. A lunar impact basin. This large impact structure
       (Schrödinger: D = 320 km) is located on the lunar farside near
       the Moon’s South Pole. Although ancient and highly degraded,
       it still preserves features distinctive of larger complex impact
       structures: a central uplift and terraced walls. However, in
       this
       large structure, the central uplift appears as an interior peak
       ring
       about 150 km in diameter (arrows), in sharp contrast to the
       simpler
       central peak formed in smaller complex structures. (Lunar
       Orbiter
       image LO-IV-8M.)
       Earth. The subsequent transition between a central-peakbasin
       structure to a peak-ring structure occurs at about 150–
       200 km on the Moon, but at only about 20–25 km on Earth.
       Despite the various difficulties, it has been possible to
       establish rough boundaries for different types of terrestrial
       complex structures (Grieve et al., 1981, p. 42, Fig. 2). These
       limits, and some typical examples, are: central-peak structures
       (D = 4–22 km) [Steinheim (Germany), Sierra Madera
       (Texas)]; central-peak-basin structures (D = 22–30 km)
       [Mistastin (Canada)]; peak-ring-basin structures (D = 30–
       62 km) [West Clearwater (Canada); Fig. 1.3]. These values
       are only approximations, and they will almost certainly change
       as more structures are studied in detail and as the formation
       of complex craters is better understood.
       3.2.3. Multiring Basins
       The largest planetary impact structures so far identified
       have diameters of a few hundred kilometers to more than
       1000 km (e.g., papers in Schultz and Merrill, 1981; Melosh,
       1989, Chapter 9; Spudis, 1993). In contrast to smaller impact
       structures, they appear as huge geological bulls-eyes,
       composed of multiple concentric uplifted rings and intervening
       down-faulted valleys (ring grabens) (Fig. 3.12). These
       features, designated multiring basins, are defined as structures
       that have two or more interior rings in addition to the
       outer rim of the structure.
       Multiring impact basins have been produced by the impact
       of projectiles tens to hundreds of kilometers in diameter,
       and they date mainly from an early period in the solar
       system (>3.9 Ga), when such large objects were more abundant
       and collisions were more frequent. The best multiring
       basins are best observed on planets with well-preserved ancient
       surfaces, such as the Moon, Mercury, parts of Mars,
       and some of the moons of Jupiter. Mare Orientale, on the
       Moon, with a diameter of at least 900 km, is one of the most
       prominent and best-known multiring basins (Fig. 3.12),
       but even larger features exist, such as the Valhalla Basin
       (D ~4000 km) on Jupiter’s icy moon Callisto. In addition,
       there are numerous large basins in the solar system that
       do not display a pronounced multiring structure, possibly
       because they have been deeply eroded since they formed.
       These include the Caloris Basin (Mercury; D = 1300 km),
       the Argyre Basin (Mars; D > 900 km) (Fig. 1.9), and the
       recently identified South Pole-Aitken Basin on the Moon
       (D ~2500 km).
       On the Moon, the transition to multiring basins occurs
       at diameters of about 400–600 km. Because the transition
       diameters for different crater forms vary inversely with
       planetary
       gravity, this observation implies that multiring basins
       should begin to form on Earth at crater diameters greater
       than about 100 km. Because the few terrestrial impact structures
       in this size range have been deeply eroded or buried
       (e.g., Fig. 1.4), it has not yet been possible to demonstrate
       clearly that any multiring basins exist on the Earth. The
       few possible candidates (and their current estimated diameters)
       are Manicouagan (Canada, 100 km), Popigai (Russia,
       100 km), Vredefort (South Africa, >200 km), Sudbury
       28 Traces of Catastrophe
       Fig. 3.12. A lunar multiring impact basin. One of the largest,
       freshest, youngest, and best-known multiring impact basins in
       the
       solar system, Mare Orientale (D = 930 km) lies on the boundary
       between the Earth-facing lunar nearside (right) and the lunar
       farside. The structure, formed at about 3.8 Ga, is bounded by an
       outer ring about 930 km in diameter (Cordillera Mountains), and
       inner rings with diameters of 620, 480, and 320 km can be
       distinguished. Mare Orientale is surrounded by radial features
       (especially at lower right) that may have been produced by the
       low-angle ejection of large blocks of excavated material. The
       postimpact history of the structure is also complex, and much of
       the area inside the rings has been modified by later volcanic
       activity.
       The flat dark areas at upper right are the younger lava flows
       that
       cover Oceanus Procellarum. (Lunar Orbiter image LO-IV-187M.)
       (Canada, >200 km), and Chicxulub (Mexico, >180 km). It
       has not proved possible to establish beyond question the
       multiring character of these structures for various reasons,
       including deep erosion, postcrater deformation, or insufficient
       geological study. The strongest current candidate for a
       terrestrial multiring structure is Chicxulub, which, although
       buried, appears well preserved (Sharpton et al., 1993, 1996b;
       Morgan et al., 1997).
       Multiring basins represent the most energetic and catastrophic
       impact events in the solar system, and the postimpact
       movements — upward, downward, and inward — of
       the target rock that modify the transient crater are far more
       complex and widespread than in smaller structures. It is
       therefore
       not surprising that the formation of multiring basins is
       even more uncertain and hotly debated than is the origin of
       smaller complex impact structures (e.g., papers in Schultz
       and Merrill, 1981; Melosh, 1989, Chapter 9; Spudis, 1993).
       For example, it is not clear whether the transition between
       smaller impact structures and multiring basins is a
       natural development with increasing crater diameter (Herrick
       et al., 1997), or whether multiring basins only form when
       special conditions are present within the target, e.g., a
       crustmantle
       structure with a weak layer (asthenosphere) at depth
       within the planet (see Melosh, 1989, pp. 176–180). Nor is it
       understood why some planetary features in the 1000–2000-
       km-diameter range have a pronounced multiring form
       (Fig. 3.12) and others do not (Fig. 1.9). Finally, it is not yet
       established whether multiring impact structures — ancient
       or modern — do exist on Earth and which large structures
       they may be.
       3.3. SUBSEQUENT DEVELOPMENT OF
       IMPACT STRUCTURES
       When the crater formation process ends, the resulting
       circular structure, whether simple or complex, consists of
       deformed subcrater rocks covered by an ejecta blanket outside
       the crater and with crater-fill deposits (usually a mixture
       of breccias and bodies of impact melt) within it (Figs. 3.7
       and 3.13). This assemblage of distinctive near-surface rocks
       is immediately subject to more normal geological processes:
       erosion, burial, and tectonic deformation. If the crater
       forms on land and remains exposed after formation,
       erosion will quickly remove the surface ejecta blanket and
       destroy any surviving meteorite fragments. At the same time,
       however, a lake may form in the crater depression, covering
       the crater-fill material with a preserving cap of sediments,
       e.g., as at Brent (Canada) (Dence, 1968; Grieve, 1978) and
       the Ries Crater (Germany) (von Engelhardt, 1990).
       If the original impact site is covered by water, the formation
       and subsequent history of the resulting crater may be
       more complex. At the moment of impact, the overlying layer
       of water will be excavated with the underlying bedrock, and
       the development of the crater and the deposition of the impact-
       produced rock units will be modified by the immediate
       and violent resurge of this displaced water back into the crater
       cavity (Therriault and Lindström, 1995; Lindström et al.,
       1996). If the crater remains below the water level, it will
       immediately begin to fill with sediments, and its subsequent
       history will depend on whether it remains below water level
       (continuous sediment filling) or is uplifted at some future
       time (beginning of erosion). A number of such submarine
       impact structures have now been recognized; some have
       subsequently
       been raised above sea level [e.g., Lockne (Sweden)
       (Therriault and Lindström, 1995; Lindström et al., 1996)]
       and others still remain buried [e.g., Montagnais (Canada)
       (Jansa and Pe-Piper, 1987); the Chesapeake Bay Crater
       (USA) (Poag, 1996, 1997); and the recently discovered
       Mjølnir structure (Norway) in the Barents Sea (Dypvik et
       al., 1996)].
       Formation of Impact Craters 29
       Fig. 3.13. Complex impact structure: locations of impactite
       types. Schematic radial cross section across a complex impact
       structure of
       the central-uplift type, from the central uplift (right) to the
       outer, downfaulted rim (left). (Vertical scale is exaggerated.)
       The subcrater
       parautochthonous rocks, exposed in the central uplift, are
       highly fractured and brecciated and may contain distinctive
       shock features such
       as shatter cones. These rocks may also contain widespread
       pseudotachylite breccias and dike-like intrusive bodies of
       allogenic breccias
       and impact melts. Larger and thicker subhorizontal units of
       allogenic breccias and melts occur as an annular unit of
       crater-fill material
       that covers the parautochthonous rocks between the central
       uplift and the rim. The bulk of these crater-fill deposits
       consist of melt-free
       lithic breccias, with lesser amounts of melt-bearing suevite
       breccias. The melt component in the crater-fill deposits becomes
       more
       abundant toward the center and upward, and a discrete layer of
       impact melt (solid black) may occur at or toward the top of the
       crater fill.
       (Modified from Stöffler et al., 1988, Fig. 12, p. 290.)
       Because impact is a near-surface process, the deformation
       associated with impact structures dies away rapidly
       with depth. Typical impact structures are relatively shallow,
       and impact-produced rocks form comparatively thin units.
       The distinctive rock types and shock effects in a structure
       tens of kilometers in diameter may extend only a few kilometers
       below the original ground surface. Impact structures
       are therefore especially vulnerable to erosion. Initial erosion
       will preferentially remove the near-surface ejecta deposits
       and the distinctively shocked and melted materials they contain,
       thus rapidly destroying the most convincing evidence
       for impact. Deeper erosion over longer periods of time will
       eventually produce major destructive changes in the crater.
       The breccias and melt units that fill the crater, and the
       distinctive
       shocked materials they contain, together with any
       protecting cap of sediments, will be reduced to small remnants
       or completely removed. The original circular outline
       will disappear. Eventually, all trace of the crater will be
       removed
       except for the weakly shocked subcrater rocks. If
       erosion continues long enough, the whole impact structure
       will be erased.
       Impact structures that are not destroyed by erosion may
       be entirely filled and buried by younger sediments, so that
       their detection depends on geophysical methods and drilling
       rather than on surface field geology. About one-third of
       the presently known impact structures are subsurface (Grieve,
       1991, 1997; Grieve and Masaitis, 1994; Grieve et al., 1995);
       they were first discovered during geophysical explorations,
       and their impact origin has been verified by the discovery of
       shocked rocks in drill core samples. This group includes several
       continental structures that are actual or potential petroleum
       producers [Ames (Oklahoma); Avak (Alaska); Marquez
       (Texas); Red Wing Creek (North Dakota)] (Donofrio, 1997),
       as well as a few submarine impact structures [e.g., Montagnais
       (Canada) (Jansa and Pe-Piper, 1987)]. Several large and
       relatively
       young buried impact structures have also been identified
       by geophysical techniques: the 90-km-diameter
       Chesapeake Bay Crater (USA) (Poag, 1996, 1997); the larger
       (>180-km diameter) Chicxulub structure (Mexico), which
       is associated with the K/T event (Hildebrand et al., 1991;
       Sharpton et al., 1992; papers in Ryder et al., 1996); and the
       large (>70 km?) Morokweng structure (South Africa) (Corner
       et al., 1997; Koeberl et al., 1997a). Many more impact
       structures remain to be found, and the evidence for their
       existence may already be sitting unrecognized in existing
       drill cores and geophysical records around the world.
       Impact structures may also be caught up in subsequent
       tectonic deformation, with varying results. Horizontal
       compression
       may deform the original circular shape, making study
       and interpretation more difficult [as at Sudbury (Canada)].
       30 Traces of Catastrophe
       Tectonism can also break up regions of original shocked rocks
       and disperse them as large discrete areas across the geological
       landscape [e.g., the Beaverhead (Idaho) structure
       (Hargraves et al., 1990; Fiske et al., 1994)]. Sufficient
       tectonism
       and metamorphism could destroy even large impact
       structures or make them totally unrecognizable.
       Geologists must therefore be prepared to recognize impact
       structures in all states of preservation, from young, fresh,
       well-exposed circular structures filled with distinctive shocked
       breccias to older features in which distinctive shock effects
       are scattered, barely recognizable, or deeply buried. It is
       essential
       to be able to recognize the variety of distinctive shock
       effects associated with impact structures and to understand
       where different types of shock effects may be located in the
       original crater.
       #Post#: 80--------------------------------------------------
       Re: Traces of Cat.
       By: Admin Date: January 29, 2017, 6:00 am
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       4.1. FORMATION CONDITIONS AND
       GENERAL CHARACTERISTICS
       The growing recognition since the 1960s of the geological
       importance of meteorite impact events, and the large
       number of impact structures still preserved on Earth, is largely
       the result of two related discoveries: (1) The extreme physical
       conditions that are imposed by intense shock waves on
       the rocks through which they pass produce unique, recognizable,
       and durable shock-metamorphic effects; (2) such
       shock waves are produced naturally only by the hypervelocity
       impacts of extraterrestrial objects (French, 1968a, 1990b;
       French and Short, 1968). Shock-metamorphic effects (also
       called “shock effects” or “shock features”) have been critical
       to the identification of terrestrial impact structures because
       of their uniqueness, wide distribution, ease of identification,
       and especially their ability to survive over long periods of
       geologic time.
       With the acceptance of shock effects as a criterion for
       impact, the record of terrestrial impact events is no longer
       limited to small young structures that still preserve definite
       meteorite fragments. Equally convincing evidence for impact
       can now be provided by a wide variety of distinctive
       deformation effects in the rocks themselves, and it has become
       possible to identify numerous old impact structures
       from which weathering and erosion have removed all physical
       traces of the projectiles that formed them. The recognition
       of preserved shock effects has been the main factor
       behind the steady increase in the number of recognized impact
       structures since the 1960s (Grieve, 1991; Grieve et al.,
       1995; Grieve and Pesonen, 1992, 1996; for historical reviews,
       see Hoyt, 1987; Mark, 1987).
       The approximate physical conditions that produce
       shockdeformation
       effects in natural rocks have been established
       by a combination of theoretical studies, artificial explosions
       (both chemical and nuclear), and experiments with laboratory
       shock-wave devices (for details, see papers in French
       and Short, 1968 and Roddy et al., 1977; also Stöffler, 1972;
       Kieffer and Simonds, 1980; Melosh, 1989; Stöffler and
       Langenhorst, 1994). Peak shock pressures produced in an
       impact event range from >2 GPa ( >20 kbar) near the final
       crater rim to >100 GPa (>1000 kbar) near the impact point.
       These pressures, and the resulting shock-deformation effects,
       reflect conditions that are far outside the range of normal
       geological processes (Fig. 4.1, Table 4.1). In ordinary
       geological environments, pressures equivalent to those of
       typical shock waves are attained only under static conditions
       at depths of 75–1000 km within Earth, well below the shallow-
       crustal regions in which impact structures are formed.
       Shock-wave pressures differ in other important ways from
       pressures produced by more normal geological processes. The
       application of shock-wave pressures is both sudden and brief.
       A shock wave traveling at several kilometers per second will
       traverse the volume of a mineral grain or a rock sample in
       microseconds, and both the onset and release of pressure are
       highly transient. Shock-deformation effects therefore reflect
       transient stress conditions, high strain rates, and rapid
       quenching that are inconsistent with the rates of normal
       geological processes (Table 4.1). In addition, shock waves
       deposit energy in the materials through which they pass. A
       particular shock pressure will produce a specific postshock
       temperature, which depends chiefly on the nature of the target
       material. These postshock temperatures increase with increasing
       shock pressure (see the P-T curve labeled “Shock
       metamorphism” in Fig. 4.1). For large shock pressures, the
       resulting temperatures are high enough to produce melting
       and even vaporization within the target.
       The unique conditions of shock-wave environments produce
       unique effects in the affected rocks. The nature and
       intensity of the changes depend on the shock pressures
       Shock-Metamorphic Effects in
       Rocks and Minerals
       32 Traces of Catastrophe
       Fig. 4.1. Conditions of shock-metamorphism. Pressure-temperature
       plot showing comparative conditions for shock metamorphism
       and normal crustal metamorphism. [Note that the pressure axis
       (X-axis, in GPa) is logarithmic.] Shaded region at lower left (P
       < 5 GPa,
       T < 1000°C) encloses the conventional facies (labeled) for
       crustal metamorphism. Shock-metamorphic conditions (at right)
       extend from
       ~7 to >100 GPa and are clearly distinct from normal metamorphic
       conditions. Approximate formation conditions for specific shock
       effects (labeled) are indicated by vertical dashed lines, and
       the exponential curve (“Shock metamorphism”) indicates the
       approximate
       postshock temperatures produced by specific shock pressures in
       granitic crystalline rocks. Relatively high shock pressures (>50
       GPa)
       produce extreme temperatures, accompanied by unique mineral
       decomposition reactions (at left, near temperature axis).
       Stability curves
       for high-pressure minerals (coesite, diamond, stishovite) are
       shown for static equilibrium conditions; formation ranges under
       shock
       conditions may vary widely. (Adapted from Stöffler, 1971, Fig.
       1; Grieve, 1990, p. 72; Grieve and Pesonen, 1992, Fig. 9.)
       TABLE 4.1. Shock metamorphism: Distinction from other geological
       processes.
       Regional and Contact Metamorphism;
       Characteristic Igneous Petrogenesis Shock Metamorphism
       Geological setting Widespread horizontal and vertical regions
       Surface or near-surface regions of Earth’s crust
       of Earth’s crust, typically to depths of 10–50 km
       Pressures Typically <1–3 GPa 100–400 GPa near impact point;
       10–60 GPa in large
       volumes of surrounding rock
       Temperatures Generally >1000°C Up to 10,000°C near impact point
       (vaporization);
       typically from 500° to 3000°C in much of
       surrounding rock
       Strain rates 10–3/s to 10–6/s 104/s to 106/s
       Time for completion From 105–107 yr “Instantaneous”: Shock-wave
       passage through 10-cm
       of process distance, <10–5 s; formation of large
       (100-kmdiameter)
       structure <1 hr
       Reaction times Slow; minerals closely approach equilibrium
       Rapid; abundant quenching and preservation of
       metastable minerals and glasses
       Shock-Metamorphic Effects in Rocks and Minerals 33
       (Table 4.2). Lower shock pressures (~2–10 GPa) produce
       distinctive megascopic shatter cones in the target rocks
       (Milton, 1977; Roddy and Davis, 1977). Higher pressures
       (>10–45 GPa) produce distinctive high-pressure mineral
       polymorphs as well as unusual microscopic deformation features
       in such minerals as quartz and feldspar (Stöffler, 1972).
       Even higher pressures (>50 GPa) produce partial to complete
       melting and even vaporization (>100 GPa) of large
       volumes of the target rocks.
       An especially distinctive and convincing form of evidence
       for meteorite impact is the suite of unique microscopic
       deformation
       features produced within individual minerals by
       higher-pressure (~10–45 GPa) shock waves. During the
       impact event, such pressures develop in target rocks near the
       center of the crater, and most of these rocks are immediately
       broken up and incorporated into the excavation flow that is
       being initiated by the expanding release wave (Figs. 3.4 and
       3.5). As a result, these shock effects are found chiefly in
       individual
       target rock fragments in the breccias that fill the
       crater or in the ejecta deposited beyond the rim.
       A wide variety of shock-produced microscopic deformation
       features has been identified in the minerals of
       shockmetamorphosed
       rocks (for reviews, see Chao, 1967; papers
       in French and Short, 1968; Stöffler, 1972, 1974; Stöffler
       and Langenhorst, 1994; Grieve et al., 1996). These include
       (1) kink bands in micas and (more rarely) in olivine and
       pyroxene; (2) several types of distinctive planar
       microstructures
       and related deformation effects in quartz, feldspar, and
       other minerals; (3) isotropic mineral glasses (diaplectic or
       thetomorphic glasses) produced selectively, most commonly
       from quartz and feldspar, without actual melting; (4) selective
       melting of individual minerals. Kink bands, although
       common in impact environments (Fig. 4.2), can also be produced
       by normal tectonic deformation; they are not a unique
       criterion for shock metamorphism, and they will not be discussed
       further. The other effects, particularly the distinctive
       planar microstructures in quartz and the diaplectic glasses,
       are now generally accepted as unique criteria for shock waves
       and meteorite impact events.
       These shock-produced microscopic deformation features
       have several distinctive general characteristics. They are
       pervasive, and usually occur throughout a centimeter-sized
       rock sample, although they may be more erratically developed
       over larger distances (meters or tens of meters). They
       TABLE 4.2. Shock pressures and effects.
       Approximate Estimated
       Shock Pressure Postshock Effects
       (GPa) Temperature (°C)*
       2–6 <100 Rock fracturing; breccia formation
       Shatter cones
       5–7 100 Mineral fracturing: (0001) and {1011}
       in quartz
       8–10 100 Basal Brazil twins (0001)
       10 100*
       Quartz with PDFs {1013}
       12–15 150 Quartz ® stishovite
       13 150 Graphite ® cubic diamond
       20 170*
       Quartz with PDFs {1012}, etc.
       Quartz, feldspar with reduced refractive
       indexes, lowered birefringence
       >30 275 Quartz ® coesite
       35 300
       Diaplectic quartz, feldspar glasses
       45 900 Normal (melted) feldspar glass (vesiculated)
       60 >1500 Rock glasses, crystallized melt rocks (quenched
       from liquids)
       80–100 >2500 Rock glasses (condensed from vapor)
       * For dense nonporous rocks. For porous rocks (e.g.,
       sandstones), postshock temperatures = 700°C
       (P = 10 GPa) and 1560°C (P = 20 GPa). Data from Stöffler (1984),
       Table 3; Melosh (1989),
       Table 3.2; Stöffler and Langenhorst (1994), Table 8, p. 175.
       34 Traces of Catastrophe
       Fig. 4.2. Kink-banding; in biotite. Large biotite grain in
       basement granitic gneisses, northeast side of Sudbury structure
       (Canada),
       showing two sets of kink-banding at high angles to original
       cleavage (horizontal). Associated quartz (upper and lower left)
       and feldspar
       show no shock-deformation effects. Sample CSF-68-67
       (cross-polarized light).
       Fig. 4.3. Progressive shock metamorphism in sandstone (I).
       Unshocked Coconino Sandstone from the Barringer Meteor Crater
       (Arizona) is composed of well-sorted quartz grains with minor
       carbonate cement and pore space. The quartz grains are rounded
       to
       angular, clear, and undeformed; some grains display secondary
       overgrowths. (Black dots are bubbles in thin section mounting
       medium.)
       Ejecta sample from rim of crater. Sample MCF-64-4
       (plane-polarized light).
       0.5 mm
       0.5 mm
       Shock-Metamorphic Effects in Rocks and Minerals 35
       Fig. 4.4. Progressive shock metamorphism in sandstone (II).
       Moderately shocked Coconino Sandstone from the Barringer Meteor
       Crater (Arizona). The quartz grains are highly fractured and
       show numerous sets of subparallel fractures along cleavage
       planes. The
       original interstitial pore space has been collapsed and heated
       during passing of the shock wave, producing a filling of dark
       glass that
       frequently contains coesite. Ejecta sample from ground surface
       outside crater. Sample MCF-65-15-4 (plane-polarized light).
       Fig. 4.5. Progressive shock metamorphism in sandstone (III).
       Highly shocked, melted, and vesiculated Coconino Sandstone from
       the
       Barringer Meteor Crater (Arizona). The original sandstone has
       been converted to a light, frothy, highly vesicular pumice-like
       material
       composed dominantly of nearly pure silica glass
       (lechatelierite). The vesicular glass contains a few remnant
       quartz grains (e.g., upper
       center, arrow) that are highly fractured and show development of
       distinctive PDFs in addition to the open cleavage cracks. Ejecta
       sample
       from ground surface outside crater. Sample MCF-65-11-2
       (plane-polarized light).
       0.5 mm
       0.5 mm
       36 Traces of Catastrophe
       are mineralogically selective; a given effect (e.g.,
       isotropization)
       will occur in grains of a single mineral (e.g., quartz or
       feldspar), but not in grains of other minerals, even adjacent
       ones. Shock metamorphism is also characterized by a progressive
       destruction of original textures with increasing shock
       pressure, a process that eventually leads to complete melting
       or vaporization of the target rock (Figs. 4.3, 4.4, and 4.5).
       4.2. STAGES OF SHOCK METAMORPHISM
       The fact that different shock pressures produce a variety
       of distinctive shock features (Table 4.2) has made it possible
       to recognize different levels or stages of shock metamorphism
       (Chao, 1967; Stöffler, 1966, 1971, 1984; von Engelhardt
       and Stöffler, 1968; Stöffler and Langenhorst, 1994). These
       stages
       are not equivalent to the different facies recognized in normal
       metamorphism, because shock metamorphism is a rapid
       and nonequilibrium process and many of the most distinctive
       features produced by shock waves (e.g., high-pressure
       minerals and diaplectic glasses) are metastable under normal
       geological conditions. Nevertheless, key shock features
       occur frequently and consistently in natural impact structures,
       and the production of the same features in experimental
       studies has made approximate pressure and temperature
       calibrations possible. As a result, the stages of shock
       metamorphism
       have become an important concept for field studies
       of impact structures and for using certain features as
       approximate
       shock-wave barometers.
       Current classifications of shock-metamorphic stages are
       based almost entirely on features developed in nonporous,
       quartz-bearing, crystalline igneous and metamorphic rocks.
       These lithologies are abundant in many of the impact structures
       studied so far, and they develop a varied suite of shock
       features over a wide range of shock pressures. Individual
       classifications
       of shock-metamorphic stages in these rocks differ
       in details, but the following summary of distinctive shock
       features and their approximate shock pressures (based largely
       on Stöffler, 1966, 1971, 1984; Stöffler and Langenhorst, 1994)
       provides a useful classification based on field and petrographic
       characteristics. [Other effects observed with increasing shock
       pressure include decreases in refractive index and increasing
       structural disorder (shock mosaicism) in mineral grains; for
       details, see Stöffler, 1972, 1974; Stöffler and Langenhorst,
       1994).] It should be remembered that estimated pressures
       are only approximate, and that the formation of a given shock
       effect will also reflect such individual factors as rock type,
       grain size, and other structural features. The shock effects
       observed, and the inferred stages of shock metamorphism,
       will be different for other rock types, especially for
       carbonates,
       basaltic rocks, and porous rocks of any type.
       For nonporous crystalline rocks, the following stages have
       been distinguished (see Table 4.2):
       <2 GPa
       Fracturing and brecciation, without development of
       unique shock features (see Chapter 5).
       >2 GPa to <30? GPa
       Shatter cones. At lower pressures (2 to <10 GPa), occurring
       without distinctive microscopic deformation features.
       At higher pressures (10 to >30 GPa), shatter cones may also
       contain distinctive microdeformation features.
       ~8 GPa to 25 GPa
       Microscopic planar deformation features in individual
       minerals, especially quartz and feldspar. It has been possible
       to subdivide this zone on the basis of different fabrics of
       deformation features in quartz (Robertson et al., 1968; Stöffler
       and Langenhorst, 1994).
       >25 GPa to 40 GPa
       Transformation of individual minerals to amorphous
       phases (diaplectic glasses) without melting. These glasses
       are often accompanied by the formation of high-pressure
       mineral polymorphs.
       >35 GPa to 60 GPa
       Selective partial melting of individual minerals, typically
       feldspars. Increasing destruction of original textures.
       >60 GPa to 100 GPa
       Complete melting of all minerals to form a superheated
       rock melt (see Chapter 6).
       >100 GPa
       Complete rock vaporization. No preserved materials
       formed at this stage (e.g., by vaporization and subsequent
       condensation to glassy materials) have been definitely
       identified
       so far.
       4.3. MEGASCOPIC SHOCK-DEFORMATION
       FEATURES: SHATTER CONES
       Shatter cones are the only distinctive and unique
       shockdeformation
       feature that develops on a megascopic (hand
       specimen to outcrop) scale. Most accepted shock-metamorphic
       features are microscopic deformations produced at relatively
       high shock pressures (>10 GPa). Lower shock pressures
       (1–5 GPa) produce a variety of unusual fractured and brecciated
       rocks, but such rocks are so similar to rocks formed by
       normal tectonic or volcanic processes that their presence cannot
       be used as definite evidence for an impact event. However,
       such low shock pressures also generate distinctive conical
       fracturing patterns in the target rocks, and the resulting
       shatter
       cones have proven to be a reliable field criterion for
       identifying
       and studying impact structures (Dietz, 1947, 1959,
       1963, 1968; Milton et al., 1972, 1996a; Roddy and Davis,
       1977; Sharpton et al., 1996a; Dressler and Sharpton, 1997).
       Shatter cones are distinctive curved, striated fractures that
       typically form partial to complete cones (Figs. 4.6 and 4.7).
       They are generally found in place in the rocks below the
       crater floor, usually in the central uplifts of complex impact
       structures, but they are also rarely observed in isolated rock
       Shock-Metamorphic Effects in Rocks and Minerals 37
       Fig. 4.6. Shatter cones; small, well-developed. Small, finely
       sculptured shatter cones, developed in fine-grained limestone
       from the
       Haughton structure (Canada). The cone surfaces show the typical
       divergence of striae away from the cone apex (“horsetailing”).
       Photograph
       courtesy of R. A. F. Grieve.
       fragments in breccia units. Shatter cones occur as individuals
       or composite groups, and individual cones may range from
       millimeters to meters in length (Figs. 4.7, 4.8, and 4.9)
       (Dietz,
       1968; Sharpton et al., 1996a). Far more common, however,
       are partial cones or slightly curved surfaces with distinctive
       radiating striations (“horsetailing”) on them (Fig. 4.10).
       The details of shatter cone morphology are also distinctive.
       Smaller secondary (“parasitic”) cones commonly occur
       on the surfaces of both complete and partial shatter cones,
       forming a unique composite or “nested” texture. The surfaces
       of shatter cones, and the striations on them, are definite
       positive/negative features. The striations are also
       directional; they appear to branch and radiate along the surface
       of the cone, forming a distinctive pattern in which the
       acute angle of the intersection points toward the apex of the
       cone (Figs. 4.6, 4.8, and 4.10).
       Shatter cones form in all kinds of target rocks: sandstones,
       shales, carbonates, and crystalline igneous and metamorphic
       rocks. The most delicate and well-formed cones form in
       finegrained
       rocks, especially carbonates (Fig. 4.6). In coarser
       rocks, shatter cones are cruder, and their striations are
       larger,
       making the cones more difficult to recognize and distinguish
       from nonshock deformational features such as slickensides
       (Figs. 4.8 and 4.10).
       Shatter cones, especially well-formed examples, are
       easy to distinguish from similar nonimpact features (see
       Table 4.3). Some shatter cone occurrences may superficially
       resemble the “cone-in-cone” structures produced during
       38 Traces of Catastrophe
       lithification of carbonate-bearing clastic sediments. However,
       the cones in cone-in-cone features have their axes normal
       to the bedding of the host rocks and their apexes pointing
       down. Shatter cones generally point upward, and their axes
       may lie at any angle to the original bedding, depending on
       the preimpact orientation of the target rock and its location
       relative to the impact point. Furthermore, the occurrence of
       shatter cones in a variety of rock types, especially
       nonsedimentary
       ones, is a good indication of an impact origin.
       The horsetailing striations on shatter cone surfaces sometimes
       resemble slickensides formed on faults, especially when
       the surfaces are approximately flat (Figs. 4.8 and 4.10).
       However,
       unlike slickensides, shatter cone striations are nonparallel
       and often show strong radiation and directionality, so
       that it is easy to determine the direction of the cone apex.
       Shatter cones are now generally accepted as unique indicators
       of shock pressures and meteorite impact. They are
       especially valuable in this role because they form at relatively
       low shock pressures (typically 2–10 GPa, but perhaps as
       high as 30 GPa) and therefore develop throughout a large
       volume of target rock below the crater floor. They are typically
       widely and intensely developed in exposed central uplifts
       of large structures. Shatter cones form in a wide range
       of rock types, they are resistant to subsequent metamorphism,
       and (when well developed) they can be easily and immediately
       recognized in the field. Frequently, an initial discovery
       of shatter cones has spurred the search for, and discovery of,
       a range of equally definite shock effects produced at even
       higher pressures.
       For well-developed shatter cones, it is possible to measure
       the orientation of the cone axes and to statistically determine
       the varying orientations of shatter cones throughout
       an impact structure. Such measurements (e.g., Manton,
       1965; Guy-Bray et al., 1966; Milton et al., 1972, 1996a)
       have provided strong support for the use of shatter cones
       Fig 4.7. Shatter cones; large. Large shatter cone and crudely
       conical striated surfaces in Mississagi Quartzite from the South
       Range (Kelley Lake) of the Sudbury structure (Canada). Cone
       axes point upward and into the Sudbury Basin (toward viewer) at
       a high angle. Cone axes are nearly parallel to the original
       bedding
       in the quartzite, which dips steeply back and to the right.
       Fig. 4.8. Shatter cone; huge, wellstriated.
       A large shatter cone, 2–
       3 m long, in quartzite in the central
       uplift of the Gosses Bluff structure
       (Australia). The cone axis plunges
       gently to the left, nearly normal to
       the original bedding in the quartzite,
       which appears as parallel joints dipping
       steeply to the right. Despite the
       crudeness of the large cone, the direction
       of the apex (right), parasitic
       cones, and distinctive horsetailing are
       all visible. Scale rule (at top) is 15 cm
       long.
       Shock-Metamorphic Effects in Rocks and Minerals 39
       Fig. 4.9. Shatter cone; huge. Unusually large shatter cone
       (megacone) (light-colored area, center) exposed in a cliff along
       a wave-cut
       shoreline on Patterson Island, one of the islands in the Slate
       Islands impact structure, Lake Superior (Canada). The huge cone,
       developed
       in Archean felsic metavolcanic rocks, points nearly straight up
       and is at least 10 m in length. At the exposed base, the exposed
       surface of
       the cone is at least 7 m wide. Only ~25° of the cone’s basal
       perimeter is exposed, indicating that the true width of the
       feature may exceed
       20 m at its base. Horsetail striations and parasitic cones cover
       all exposed surfaces. Several other large, conical features are
       obvious on the
       near-vertical cliff, but because of the steep scree-covered
       slopes these features have not yet been examined in detail.
       Photograph courtesy
       of V. L. Sharpton.
       Fig. 4.10. Shatter cones; crude,
       striated surfaces. Poorly developed
       shatter cones in Serpent Quartzite,
       Sudbury (Canada). The cones are only
       partially developed, appearing as
       curved and striated surfaces. Divergence
       of the striae indicates that the
       cone apexes are to the right. Pen (at
       center) is 12 cm long.
       40 Traces of Catastrophe
       as a criterion for impact. In several impact structures that
       formed in originally flat-lying sediments, the apexes of shatter
       cones in the rocks point inward and upward when the rocks
       are graphically restored to their original horizontal preimpact
       position, indicating that the source of the shock wave
       that produced the shatter cones was located above the original
       ground surface (Guy-Bray et al., 1966; Dietz, 1968;
       Manton, 1965; Howard and Offield, 1968; Wilshire et al., 1972;
       Milton et al., 1972, 1996a). More recently, shatter cones in
       the Beaverhead (Idaho) structure (Hargraves et al., 1990)
       have been used to reconstruct the original shape and size
       of a large, ancient impact structure that was subsequently
       dissected and redistributed by major faulting during the
       Laramide Orogeny.
       The use of shatter cones to identify impact structures requires
       caution, especially in cases where no other shock effects
       can be identified. Poorly developed shatter cones
       (Figs. 4.8 and 4.10) can be easily confused with normal
       fractures
       and slickensides, and the latter may be misidentified
       as shatter cones. Even in well-established impact structures,
       shatter cones may be entirely absent or poorly developed, or
       their orientations may be locally diverse and ambiguous
       (Fig. 4.11). Detailed studies of shatter cone orientations need
       to be done at more impact structures where they are well
       developed, but such studies need to be done with care (see,
       e.g., Manton, 1965; Milton et al., 1972, 1996a).
       It is a paradox that, even though shatter cones are a proven
       and valuable indicator of shock metamorphism and impact
       structures, the exact mechanisms by which the radiating
       TABLE 4.3. Shatter cones: Distinction from other geological
       features.
       Cone-in-Cone Shatter Cones
       Conical secondary growth features formed during Conical fracture
       features formed by transient shock waves (P ~2 to
       diagenesis; found in undisturbed sedimentary rocks. >10 GPa) and
       found in meteorite impact structures, typically in uplifted
       central rocks.
       Restricted to carbonate-bearing rocks (limestones, Found in all
       rock types (sedimentary, igneous, metamorphic). Best
       limy shales); associated with secondary carbonate. developed in
       fine-grained rocks, especially limestones.
       Cone axes normal to bedding planes. Cone axes oriented at any
       angle to bedding, depending on orientation of
       rock at time of impact and on postimpact movements.
       Cones oriented point-down. Cones originally form pointing in
       direction of source of shock wave, i.e.,
       inward and upward. Orientation varies over structure.
       Orientation further
       modified by development of central uplift or later postcrater
       deformation.
       When beds restored to original horizontal position, cones point
       toward a
       focus above original surface, indicating external source of
       shock wave.
       Striations along cone surface generally continuous, Striations
       along cone surface typically show development of divergent
       uniform. radiations (“horsetailing”) along surface. Development
       of secondary
       (parasitic) cones on main cone is typical.
       Cone surfaces are growth surfaces against other cones Cone
       surfaces are actual fracture surfaces; rock splits into new
       shatteror
       fine matrix in rock. coned surfaces along cone boundaries.
       Unlike slickensides, striated cone
       surfaces show no relative motion, fit together without
       displacement.
       Rocks typically show no deformation, metamorphism. Frequently
       contain kink-banded micas or quartz (coarser grains) with
       shock-produced planar deformation features (PDFs).
       shock wave interacts with the target rock to generate shatter
       cones have not been studied in great detail and are still not
       understood (e.g., Dietz, 1968; Gash, 1971; Milton, 1977;
       Sharpton et al., 1996a). A further complication in shatter
       cone formation is the evidence that, although the cones
       themselves
       form at relatively low shock pressures, localized melting
       and glass formation can occur along the cone surfaces,
       probably as the result of a complex combination of shock
       and frictional mechanisms (Gay, 1976; Gay et al., 1978;
       Gibson and Spray, 1998). Combined theoretical, experimental,
       and field studies to understand the exact conditions of
       shatter cone formation are a major challenge for the future.
       4.4. HIGH-PRESSURE MINERAL
       POLYMORPHS
       When subjected to impact-produced shock waves, some
       minerals in target rocks (e.g., quartz, graphite) may transform
       to high-pressure minerals, just as they do under high
       static pressures produced in laboratory experiments or deep
       in Earth’s crust. Graphite (C) can be converted to diamond.
       Quartz can be converted to stishovite at shock pressures
       of >12–15 GPa and to coesite at >30 GPa (Stöffler and
       Langenhorst, 1994). [These numbers illustrate one of the
       many differences between shock processes and normal geological
       deformation. Under conditions of static equilibrium,
       where reaction rates are slower and kinetic factors less
       imShock-
       Metamorphic Effects in Rocks and Minerals 41
       Fig. 4.11. Shatter cones; small, diversely oriented. This
       specimen shows a group of small, well-developed shatter cones,
       formed in a
       sample of Precambrian crystalline target rock at the Slate
       Islands structure (Canada). The cones show two distinct
       orientations, and cone
       axes appear to diverge above and below the coin. This type of
       diverse orientation may reflect small-scale nonuniformities in
       the shock
       waves, produced by local heterogeneities (bedding planes,
       joints, etc.) in the rock sample. Coin is about 2 cm in
       diameter. Photograph
       courtesy of V. L. Sharpton.
       Fig. 4.12. Diaplectic quartz glass; with coesite. Diaplectic
       quartz glass (clear), with strings of small, high-relief
       crystals of coesite (“C”).
       From biotite granite inclusion in suevite breccia, Aufhausen,
       Ries Crater (Germany). Photograph courtesy of W. von Engelhardt
       (planepolarized
       light).
       0.1 mm
       42 Traces of Catastrophe
       portant, coesite forms from quartz at lower pressures
       (>2 GPa) than does stishovite (10–15 GPa).]
       The identification of coesite and stishovite at several sites
       in the early 1960s provided one of the earliest criteria for
       establishing the impact origin of several structures, most
       notably the Ries Crater (Germany) (Chao et al., 1960;
       Shoemaker and Chao, 1961) (Fig. 4.12). Most subsequent
       identifications of impact structures have been based on
       shock-produced planar deformation features (PDFs) in
       quartz, which are more widely distributed and simpler to
       identify. However, the discovery of both coesite and stishovite
       in the ancient Vredefort structure (South Africa) (Martini,
       1991) was an important step in the growing acceptance of
       this structure as an impact site. Diamond and other highpressure
       carbon compounds [e.g., lonsdaleite (hexagonal diamond)]
       produced from graphite in the shocked target rocks
       have also been identified at an increasing number of impact
       structures (Masaitis, 1998; Masaitis et al., 1972; Hough et al.,
       1995; Koeberl et al., 1997c).
       Coesite, stishovite, and diamond, when they are found in
       near-surface rocks, are unique and reliable indicators of
       meteorite
       impact. None of these minerals has been identified,
       for example, as the result of explosive volcanic eruptions. The
       use of coesite and diamond as impact criteria does require
       some care, however, because both minerals also occur naturally
       in deep-seated (depth >60 km) terrestrial rocks, where
       they have formed in stable equilibrium at the high static
       pressures
       (>2 GPa) present at these depths. Both minerals may
       then be transported to Earth’s surface: coesite by tectonic
       processes and diamond in fragments carried up by unusual
       mafic (kimberlite) volcanic eruptions. However, stishovite,
       formed only at pressures >10 GPa, has never been identified
       in a nonimpact setting. Such static pressures could be produced
       only at depths of 300–400 km within Earth. Furthermore,
       the occurrence of such high-pressure minerals as
       coesite, stishovite, or diamond in near-surface crustal rocks
       [e.g., coesite and stishovite in sandstone at Barringer Meteor
       Crater (Arizona)], particularly when they occur as a
       disequilibrium
       assemblage with other chemically equivalent
       minerals (e.g., coesite + stishovite + silica glass + quartz),
       is
       definite evidence for meteorite impact.
       4.5. PLANAR MICROSTRUCTURES
       IN QUARTZ
       Shock waves produce a variety of unusual microscopic
       planar features in quartz, feldspar, and other minerals. These
       features typically occur as sets of parallel deformation planes
       within individual crystals. The recognition and interpretation
       of these features, particularly those in quartz, as unique
       products of meteorite impact has been a critical factor in
       identifying most new impact structures, in recognizing the
       impact origin of large, ancient, or deeply eroded structures,
       and in demonstrating the role of meteorite impact in the
       K/T extinction event.
       Distinctive planar features in quartz (SiO2) have been one
       of the most widely applied criteria for recognizing impact
       structures (for reviews, details, and literature references, see
       papers in French and Short, 1968; also von Engelhardt and
       Bertsch, 1969; Stöffler and Langenhorst, 1994; Grieve et al.,
       1996). Quartz is an ideal mineral for this purpose. It is
       abundant
       in a wide range of sedimentary and crystalline rocks. It
       is stable over long periods of geologic time, and it resists
       change by alteration and metamorphism. It is an optically
       simple (uniaxial) mineral to study and to analyze on the
       Universal
       Stage (U-stage). In particular, it displays a variety of
       different planar features whose development can be correlated
       with shock pressure (Table 4.2) (Hörz, 1968; Robertson
       et al., 1968; Stöffler and Langenhorst, 1994), and can thus be
       used as a shock barometer to reconstruct the shock-pressure
       distribution that existed within an impact structure during
       the impact event (Robertson, 1975; Grieve and Robertson,
       1976; Robertson and Grieve, 1977; Grieve et al., 1996; Dressler
       et al., 1998).
       The production and properties of planar microstructures
       in quartz have been studied intensely since the early 1960s
       by geological investigations, shock-wave experiments, and
       both optical and electron microscopy (papers in French and
       Short, 1968; also Stöffler and Langenhorst, 1994). It is now
       recognized that shock waves produce several kinds of planar
       microstructures in quartz, and their detailed characterization
       and interpretation has been — and still is — an active
       and much-debated problem (e.g., Alexopoulos et al., 1988;
       Sharpton and Grieve, 1990). At present, two basic types of
       planar features can be recognized, planar fractures and planar
       deformation features (PDFs) (Table 4.2).
       4.5.1. Planar Fractures
       Planar fractures are parallel sets of multiple planar cracks
       or cleavages in the quartz grain; they develop at the lowest
       pressures characteristic of shock waves (~5–8 GPa)
       (Figs. 4.13 and 4.14). The fractures are typically 5–10 &#956;m
       wide and spaced 15–20 &#956;m or more apart in individual quartz
       grains. Similar cleavage also occurs rarely in quartz from
       nonimpact
       settings, and therefore planar fractures cannot be used
       independently as a unique criterion for meteorite impact.
       However, the development of intense, widespread, and closely
       spaced planar fractures (Fig. 4.15) is strongly suggestive of
       shock, and such fractures are frequently accompanied in
       impact structures by other features clearly formed at higher
       shock pressures (Robertson et al., 1968; Stöffler and
       Langenhorst, 1994; Grieve et al., 1996; French et al., 1997).
       4.5.2. Planar Deformation Features (PDFs)
       Planar deformation features (PDFs) is the designation
       currently used for the distinctive and long-studied
       shockproduced
       microstructures that were formerly given a variety
       of names (e.g., “planar features,” “shock lamellae”). In
       contrast
       to planar fractures, with which they may occur, PDFs
       are not open cracks. Instead, they occur as multiple sets of
       closed, extremely narrow, parallel planar regions (Fig. 4.16).
       Individual PDFs are both narrow (typically <2–3 &#956;m) and
       more closely spaced (typically 2–10 &#956;m) than planar
       fractures
       (Figs. 4.17 and 4.18). Detailed optical and TEM studies
       have shown that, within individual PDFs, the atomic
       Shock-Metamorphic Effects in Rocks and Minerals 43
       Fig. 4.13. Quartz; cleavage and PDFs. High-magnification view of
       relict deformed quartz grain in highly shocked and vesiculated
       Coconino Sandstone [Barringer Meteor Crater (Arizona)]. The
       quartz grain shows irregular, subparallel fractures (dark,
       near-vertical),
       combined with shorter cross-cutting light-and-dark planar
       features, possibly PDFs (upper right/lower left). Note the
       irregular extinction
       in the grain. Sample MCF-65-15-3 (cross-polarized light).
       0.05 mm
       Fig. 4.14. Quartz; cleavage. Quartz grain in moderately shocked
       Coconino Sandstone from Barringer Meteor Crater (Arizona),
       showing
       irregular extinction and multiple sets of cleavage fractures
       parallel to c(0001), m{1010}, r{1011}, and r'. c-axis direction
       (arrow) and
       directions of cleavage traces indicated in inset. Photograph
       courtesy of T. E. Bunch (cross-polarized light).
       0.1 mm
       44 Traces of Catastrophe
       Fig. 4.15. Quartz; fractured, in quartzite. Intense fracturing
       of quartz in a coarse-grained metamorphosed orthoquartzite
       target rock
       from the Gardnos structure (Norway). The large quartz grain
       (right) grades into a finer-grained recrystallized shear zone
       (left). The
       quartz grain is cut by numerous subparallel planar fractures
       (longer, dark, subhorizontal lines) and by much shorter planar
       features (short,
       dark, near-vertical lines) that originate along the fracture
       planes. These latter features may be relicts of actual PDFs or
       of Brazil twins
       parallel to the base (0001). Within the Gardnos structure, the
       originally white quartzite is dark gray to black and highly
       fractured, and the
       fractures within the quartz grains contain carbonaceous
       material. Sample NG-94-17B (cross-polarized light).
       and the Ries Crater (Germany) (age 15 Ma) (Fig. 4.16).
       However, preservation of fresh, continuous PDFs depends
       on geological circumstances, including cooling rate and
       postimpact temperatures. Fresh, well-preserved PDFs are
       also present in older structures, e.g., Sierra Madera (Texas)
       (age <100 Ma) (Fig. 4.19) and Gardnos (Norway) (age
       >400 Ma) (Fig. 4.20). The occurrence of striking fresh PDFs
       in quartz exactly at the K/T boundary, a worldwide layer of
       ejecta from the Chicxulub structure (Mexico) (age 65 Ma)
       (Figs. 4.17 and 4.18), provided some of the most important
       initial evidence that a large meteorite impact event had
       occurred at that time.
       In altered, geologically old, or metamorphosed samples,
       PDFs have an equally distinctive but discontinuous character.
       The original amorphous material in the PDF planes is
       recrystallized back to quartz, and in the process, arrays of
       small (typically 1–2 &#956;m) fluid inclusions (“decorations”)
       develop along the original planes (Figs. 4.21 and 4.22). The
       resulting features, called decorated PDFs (Robertson et al.,
       1968; Stöffler and Langenhorst, 1994) preserve the orientation
       of the original PDFs, and the distinctive shock-produced
       fabric can still be recognized in old rocks that have
       even undergone metamorphism [e.g., greenschist facies at
       Sudbury (Canada); Fig. 4.23]. More intense recrystallization
       produces arrays of small mosaic quartz crystals
       (subgrains), especially along PDFs originally parallel to the
       base c(0001) of the quartz grain (Leroux et al., 1994).
       A second type of PDF, oriented parallel to the base
       c(0001), has recently been identified, chiefly by studies of
       1 mm
       structure of the original crystalline quartz is severely
       deformed,
       so that the quartz has been transformed into a distinct
       amorphous phase (Müller, 1969; Kieffer et al., 1976a;
       Goltrant et al., 1991, 1992).
       The importance of PDFs arises from the fact that they
       are clearly distinct from deformation features produced in
       quartz by nonimpact processes, e.g., cleavage or tectonic
       (metamorphic) deformation lamellae (Böhm lamellae)
       (Carter, 1965, 1968; Alexopoulos et al., 1988; Stöffler and
       Langenhorst, 1994). Cleavages are open fractures; they tend
       to be relatively thick (~10 &#956;m) and widely spaced (>20
       &#956;m).
       Deformation lamellae consist of bands of quartz typically
       10–20 &#956;m thick and >10 &#956;m apart that are optically
       distinct
       and slightly misoriented relative to the host grain. In
       contrast to these features, shock-produced PDFs are narrow
       (<2–3 &#956;m) straight planes consisting of highly deformed or
       amorphous quartz, and they are generally oriented parallel
       to specific rational crystallographic planes in the host quartz
       crystal, especially to the base c(0001) or to low-index
       rhombohedral
       planes such as w{1013}, p{1012}, and r{1011}
       (Table 4.4).
       The presence of well-developed PDFs produces a striking
       and distinctive appearance in thin section. Unaltered
       PDFs form multiple sets of continuous planes that extend
       across most or all of the host grain (Figs. 4.16, 4.17, and
       4.18). These fresh, continuous PDFs tend to be observed
       only in unaltered material from shock-wave experiments
       and from younger, well-preserved impact structures, e.g.,
       Barringer Meteor Crater (Arizona) (age 50 ka) (Fig. 4.13)
       Shock-Metamorphic Effects in Rocks and Minerals 45
       Fig. 4.17. Quartz; multiple PDFs, fresh. Small quartz grain
       (0.20 mm long) from K/T boundary ejecta layer, showing two
       prominent sets of fresh (undecorated) PDFs. (Small dots with
       halos are artifacts.) Specimen from Starkville South, a few
       kilometers
       south of Trinidad, Colorado. Photograph courtesy of
       G. A. Izett. Spindle stage mount (plane-polarized light).
       Fig. 4.18. Quartz; multiple PDFs, fresh. Small quartz grain
       (0.36 mm long) from K/T boundary ejecta layer, containing one
       opaque inclusion and multiple (3–5?) prominent sets of fresh
       (undecorated) PDFs. Specimen from Clear Creek North, a few
       kilometers south of Trinidad, Colorado. Photograph courtesy of
       G. A. Izett. Spindle stage mount (plane-polarized light).
       0.1 mm
       Fig. 4.16. Quartz; multiple PDFs, fresh. Striking multiple sets
       of PDFs developed in a quartz grain from a shocked granite
       inclusion
       in suevite from the Ries Crater (Germany). “A” indicates PDFs
       parallel to {1013} or {0113}; “B” indicates PDFs parallel to
       {1011} or
       {0111}. Note the irregular mottled extinction within the quartz
       grain. From von Engelhardt and Stöffler (1965), Fig. 1.
       Photograph
       courtesy of W. von Engelhardt (cross-polarized light).
       46 Traces of Catastrophe
       Fig. 4.19. Quartz; multiple PDFs, fresh. Shocked quartz grain
       containing multiple sets of fresh PDFs. The grain is included
       with rare
       sandstone fragments in a carbonate breccia dike that cuts the
       deformed basement rocks at Sierra Madera (Texas), an impact
       structure
       developed in a target composed dominantly of carbonate rocks.
       The closely spaced PDFs give a distinctive darkened, yellowish
       appearance
       to the quartz grain. Sample SMF-65-2-2 (plane-polarized light).
       0.1 mm
       TABLE 4.4. Typical crystallographic orientations of planar
       microstructures in shocked quartz (modified from
       Stöffler and Langenhorst, 1994, Table 3, p. 164).
       Polar Angle
       (Angle Between Pole to Plane
       Symbol Miller Indexes and Quartz c-axis)
       c * (0001) 0°
       w, w' * {1013},{0113} 23°
       p, p' * {1012},{0112} 32°
       r, z * {1011},{0111} 52°
       m {1010} 90°
       x {1122},{2112} 48°
       s {1121},{2111} 66°
       a {1120},{2110} 90°
       * {2241},{4221} 77°
       t {4041},{0441} 79°
       k {5160},{6150} 90°
       x {5161},{6511} 82°
       {6151},{1561}
       — {3141},{4311} 78°
       {4131},{1341}
       — {2131},{3211} 74°
       {3121},{1231}
       *Prominent planes in typical shock fabrics.
       Shock-Metamorphic Effects in Rocks and Minerals 47
       Fig. 4.21. Quartz; multiple PDFs, decorated. Large compound
       quartz grain from shocked basement rock inclusion in suevite
       breccia
       from Rochechouart (France), showing two prominent sets of
       partially decorated PDFs (north-northeast/south-southwest;
       northeast/
       southwest). Original, partly continuous PDF traces are still
       recognizable from the location of small fluid inclusions (black
       dots) along the
       original PDF planes. Sample FRF-69-16 (cross-polarized light).
       0.1 mm
       0.1 mm
       Fig. 4.20. Quartz; multiple PDFs, slightly decorated. Quartz
       grain in a carbon-bearing crater-fill breccia from Gardnos
       (Norway),
       showing two well-developed sets of {1013} PDFs. In places, the
       normally continuous PDFs break down into a string of small fluid
       inclusions (small black dots) that follow the original trace of
       the PDFs. This process, by which the originally glassy material
       in the PDFs
       is recrystallized and replaced by fluid inclusions, has produced
       decorated PDFs, in which the original PDFs are visible only by
       the arrays
       of fluid inclusions that reproduce their original orientations.
       Sample NG-94-31 (plane-polarized light).
       48 Traces of Catastrophe
       Fig. 4.22. Quartz; multiple PDFs, decorated. Compound quartz
       grain showing two prominent sets of decorated PDFs (north/south;
       northwest/southeast). The original PDF planes are now largely
       replaced by arrays of small fluid inclusions that preserve the
       original PDF
       orientations. Sample from Precambrian basement gneiss in the
       central uplift of the Carswell Lake structure (Canada).
       Photograph
       courtesy of M. R. Dence. Sample DCR-11-63B (cross-polarized
       light).
       Fig. 4.23. Quartz; multiple PDFs, decorated. High-magnification
       view of shocked quartz from ejecta block in metamorphosed
       suevite,
       showing multiple sets of recrystallized PDFs
       (northwest/southeast; east/west) now expressed by arrays of
       small fluid inclusions
       (black dots). Quartz grain also contains numerous random larger
       fluid inclusions scattered through the grain. Sample from a
       small
       granitic gneiss inclusion in the Onaping Formation “Black
       Member,” from the type locality, Onaping Falls (Highway 144,
       Dowling
       Township), northwestern corner of the Sudbury structure
       (Canada). Photograph courtesy of N. M. Short. Sample CSF-66-39
       (crosspolarized
       light).
       0.1 mm
       0.1 mm
       Shock-Metamorphic Effects in Rocks and Minerals 49
       Fig. 4.24. Quartz; basal PDFs. Large irregular quartz grain
       associated with sericitized feldspar (dark) in footwall granitic
       rocks on
       North Range of Sudbury structure (Canada), together with shatter
       cones and pseudotachylite. Grain shows one well-developed set of
       PDFs (upper left/lower right), which appear as linear arrays of
       small fluid inclusions parallel to the base (0001) of the quartz
       grain.
       Sample CSF-67-55-2 (cross-polarized light).
       shocked quartz with transmission election microscopy
       (TEM), as Brazil twins (Fig. 4.24) (Leroux et al., 1994; Joreau
       et al., 1996). This form of twinning also occurs in natural
       unshocked quartz, but it has never been observed parallel to
       the base in such samples. Experimental formation of
       basaloriented
       Brazil twins in quartz requires high stresses (about
       8 GPa) and high strain rates, and it seems probable that such
       features in natural quartz can also be regarded as unique
       impact indicators (Stöffler and Langenhorst, 1994).
       4.5.3. PDF Orientations
       Despite the distinctive appearance of PDFs in thin section,
       appearance alone is not adequate to distinguish them
       from nonshock features or to argue that they are impact
       produced. An additional and definitive characteristic of PDFs
       is their tendency to form along specific planes in the quartz
       crystal lattice. Measurements of PDF orientations within the
       host quartz grain therefore provide a simple and reliable
       method to distinguish them from planar structures produced
       by nonshock processes. PDF orientations can be measured
       using standard petrofabric procedures on a U-stage (for details,
       measurement techniques, and specific studies, see Carter,
       1965, 1968; Robertson et al., 1968; von Engelhardt and Bertsch,
       1969; Alexopoulos et al., 1988; Stöffler and Langenhorst, 1994)
       or on the related spindle stage (Bloss, 1981; Medenbach, 1985;
       Bohor et al., 1984, 1987; Izett, 1990).
       The procedures involve measuring, in a single quartz grain,
       both the orientation of the pole (normal) to each set of PDFs
       0.2 mm
       and the orientation of the c-axis (= optic axis) of the grain.
       The measurement data are then plotted on a standard
       stereonet, and the results are expressed as the location of the
       pole to the PDFs relative to the c-axis. If a large number of
       PDF measurements can be made on a sample, a convenient,
       although not entirely rigorous, method to present comparative
       results is to plot a frequency diagram (histogram) of the
       angles between the c-axis and the pole to each set of PDFs.
       Because shock-produced PDFs in a given quartz grain
       are parallel to only a few specific crystallographic planes, the
       angles measured between the quartz c-axis and the poles to
       the PDFs tend to concentrate at a few specific values. In a
       histogram plot, the poles appear as sharp concentrations at
       specific angles, each of which corresponds to a particular
       plane (Figs. 4.25 and 4.26).
       This sharply peaked pattern of PDF orientations, typically
       characterized by peaks at c(0001) (0°), w{1013} (23°),
       and p{1012} (32°), is one of the most useful and most-used
       indicators of meteorite impact. Such plots clearly demonstrate
       the great difference between PDF distributions
       (Figs. 4.25a–c) and the more widely distributed, bell-shaped
       distribution characteristic of metamorphic deformation
       lamellae (Fig. 4.25e). Such plots are also used to distinguish
       different shock-produced fabrics that reflect different shock
       pressures (Fig. 4.26).
       Experimental and geological studies have demonstrated
       that PDFs form in quartz at pressures of ~7–35 GPa, or at
       the lower end of the range of shock-metamorphic pressures
       50 Traces of Catastrophe
       Fig. 4.25. Quartz; PDF orientations. Comparative histograms
       showing orientations of shock-produced PDFs and other planar
       deformation features in quartz (from Carter, 1965). In each
       diagram, the angle between the quartz c-axis and the pole to the
       planar
       feature is plotted on the x-axis; y-axis indicates frequency for
       each given angle. Shock-produced fabrics are characterized by
       strong
       orientations parallel to a few specific crystallographic planes.
       (a) and (b) Basal-oriented sets of deformation lamellae in
       shocked sandstones
       from the Vredefort (South Africa) and Barringer Meteor Crater
       (Arizona) structures; (c) distinctive PDFs showing the
       distinctive
       concentration parallel to w{1013} [shocked crystalline rocks;
       Clearwater Lakes (Canada)]; (d) low-angle, near-basal fabric of
       deformation
       lamellae generated under high-strain experimental conditions;
       (e) broad distribution of metamorphic deformation lamellae (Böhm
       lamellae)
       produced by normal metamorphic conditions. The distinctive
       differences between shock-produced fabrics (a), (b), and (c) and
       those of
       normal metamorphism (e) have been one of the strongest arguments
       for the meteorite impact origin of suspected impact structures.
       Shock-Metamorphic Effects in Rocks and Minerals 51
       Fig. 4.26. Quartz; PDF orientations. Comparative histograms
       showing different fabrics displayed by PDFs in quartz produced
       at
       different shock pressures, based on measurements of shocked
       crystalline rocks from several Canadian impact structures (from
       Robertson
       et al., 1968). With increasing shock pressures, both the total
       number of PDFs and the number of different orientations
       increase. The
       following fabrics, and the minimum shock pressures estimated to
       form them (Grieve and Robertson, 1976, pp. 39–40), can be
       recognized:
       type A (P > 7.5 GPa): basal PDFs only; type B (P > 10 GPa),
       appearance of w{1013} planes, typically with basal planes; type
       C
       (P > 14 GPa), appearance of {2241} planes with others; type D (P
       > 16 GPa), appearance of p{1012} planes with others. These
       fabrics
       have been used as shock barometers to measure the intensity and
       distribution of shock pressures in several structures (Grieve
       and Robertson,
       1976; Robertson and Grieve, 1977; Dressler and Sharpton, 1997).
       From Carter (1965).
       52 Traces of Catastrophe
       been observed in sedimentary rocks from several impact
       structures (Kieffer, 1971, Kieffer et al., 1976a; Grieve et al.,
       1996).
       Despite these similarities, a growing amount of data now
       indicates that sedimentary rocks, especially porous ones,
       respond
       differently to shock waves than do nonporous crystalline
       rocks. One indication of significant differences is that
       PDF fabrics measured in sediments show a large proportion
       of PDFs whose poles are oriented at high angles (>45°) to
       the quartz c-axis (Grieve et al., 1996; Gostin and Therriault,
       1997). Other possible differences are that PDFs may first
       appear, or a particular PDF fabric may develop, at different
       shock pressures in sedimentary rocks than in crystalline rocks.
       A more important difference between porous and nonporous
       rocks is that a shock wave passing through porous
       sediments will generate more heat than in passing through
       crystalline rocks, chiefly because more of the shock-wave
       energy is absorbed by the numerous grain interfaces and pore
       spaces in the sediment (Kieffer, 1971; Kieffer et al., 1976a;
       Kieffer and Simonds, 1980; Stöffler, 1984). As a result,
       extensive
       melting will occur at lower shock pressures in sediments
       than in crystalline rocks, i.e., at about 15–20 GPa in sandstone
       vs. 50–60 GPa in crystalline rocks (Stöffler, 1972, 1984).
       Therefore, the higher-pressure fabrics of quartz PDFs, which
       form at 20–30 GPa in crystalline rocks, may not be found in
       sediments, either because they did not form or because they
       Fig. 4.27. Quartz; multiple PDFs, fresh. Photomicrograph showing
       at least four sets of fresh PDFs in a shocked quartz grain from
       crystalline target rocks at the Lake St. Martin impact
       structure, Manitoba (Canada). Two prominent PDF sets
       (northwest/southeast and
       west-northwest/east-southeast) are accompanied by less obvious
       sets oriented approximately north/south and east/west.
       Petrofabric
       measurements with a U-stage show that the PDFs are oriented
       parallel to both w{1013} and p{1012}, indicating moderately high
       shock
       pressures (>15 GPa). Patches of diaplectic glass, associated
       with the shocked quartz, appear as dark zones (e.g., upper
       right). Width of
       field is ~100 &#956;m. Photograph courtesy of V. L. Sharpton
       (cross-polarized light).
       (e.g., Hörz, 1968; Stöffler and Langenhorst, 1994). However,
       the relative abundance of different PDF orientations varies
       significantly with shock pressure. Basal Brazil twins, although
       little studied so far, appear restricted to shock pressures
       below
       10 GPa. PDFs parallel to w{1013} develop at about >7–
       10 GPa, and PDFs parallel to p{1012} at about >20 GPa.
       At higher pressures, e.g., 20–35 GPa, the total number of
       PDF sets increases, and additional orientations appear
       (Fig. 4.26). The PDFs formed at these higher levels tend to
       be intensely developed and very closely spaced within the
       quartz grains (Figs. 4.16, 4.18, and 4.27).
       4.5.4. PDFs in Sedimentary Rocks
       Although PDFs and their orientations can be reliably used
       as indicators of shock and impact events, it is becoming clear
       that our current knowledge about such features is incomplete
       and unrepresentative. Nearly all our information to date
       has come from impact structures formed in dense, coherent,
       quartz-bearing crystalline rocks. There is relatively little
       information
       about the effects of shock deformation in other
       kinds of quartz-bearing rocks, e.g., porous sandstones or
       finegrained
       shales.
       Several studies have demonstrated that shocked sandstones
       and shales also develop PDFs in quartz, and even
       diaplectic quartz and feldspar glasses, similar to those
       observed
       in shocked crystalline rocks, and these features have
       Shock-Metamorphic Effects in Rocks and Minerals 53
       were immediately destroyed by postshock melting. The
       unique shock effects observed in sedimentary rocks can still
       provide conclusive evidence for an impact origin [e.g., at
       Barringer Meteor Crater (Arizona) (Kieffer, 1971)], but the
       details of such occurrences cannot be accurately interpreted
       on the basis of results from shocked nonporous crystalline
       rocks (Grieve et al., 1996).
       4.6. PLANAR MICROSTRUCTURES IN
       FELDSPAR AND OTHER MINERALS
       Similar planar microstructures are produced by shock in
       many other minerals (e.g., Stöffler, 1972, 1974), but such
       features have been less used as indicators of meteorite impact.
       Feldspars of all kinds (both alkali varieties and plagioclase)
       display various shock-produced planar microstructures:
       fractures, deformation bands, kink bands, and actual PDFs.
       Frequently, short and closely spaced PDFs may be combined
       with longer and more widely spaced features (deformation
       bands or albite twinning) to produce a distinctive ladder
       texture
       (Figs. 4.28, 4.29, and 4.30).
       Although several studies have been made of shock-produced
       planar features in feldspars (e.g., Stöffler, 1967, 1972;
       papers in French and Short, 1968), these features have been
       less studied and less well characterized than those in quartz.
       There are several reasons for this: the greater diversity and
       complexity of such features, the greater optical complexity
       (biaxial) of feldspars, and the common secondary alteration
       of the feldspar and its planar features to clays, iron
       oxides, etc. (Figs. 4.29 and 4.30). Another factor in studies
       focused on identifying new impact structures is the fact
       that shocked feldspar in crystalline rocks is generally
       associated
       with shocked quartz, whose features (especially PDFs)
       provide a quicker and simpler method for establishing an
       impact origin.
       Planar microstructures, both planar fractures and true
       PDFs, have also been observed in other minerals, including
       pyroxene, amphiboles, and several accessory phases (apatite,
       sillimanite, cordierite, garnet, scapolite, and zircon)
       (Stöffler,
       1972). Less is known about PDF formation and orientations
       in these minerals, because appropriate rocks are less
       abundant in most impact structures, and because the specific
       minerals have not been studied in detail. However, recognition
       of shock-produced PDFs in zircon has been
       especially important in applying U-Th-Pb dating methods
       to individual zircons in shocked target rocks to determine
       the ages of impact structures (e.g., Krogh et al., 1984, 1993;
       Kamo and Krogh, 1995).
       The development of distinctive shock-metamorphic features
       such as PDFs in denser mafic minerals like amphibole,
       pyroxene, and olivine apparently occurs at higher pressures
       and over a more limited pressure range than in quartz and
       feldspar. At pressures <30 GPa, sufficient to form PDFs in
       both quartz and feldspar, the most common shock effects
       observed in mafic minerals are planar fractures, mechanical
       twins, and general comminution (Stöffler, 1972); features
       Fig. 4.28. Feldspar; multiple PDFs and diaplectic glass
       (maskelynite). Shocked plagioclase feldspar grain from the Ries
       Crater (Germany), showing development of multiple sets of PDFs
       (lower right) and gradational conversion of the same crystal to
       diaplectic glass (maskelynite) (upper left). Original
       polysynthetic
       albite twin lamellae (northwest/southeast) are still preserved
       in
       part of the crystal (lower right), but alternate twin lamellae
       have
       either been converted to maskelynite (clear) or are crosscut by
       short,
       closely spaced PDFs to form a distinctive “ladder” structure.
       Elsewhere in the crystal (upper left), both the original twins
       and
       the subsequent shock-produced PDFs disappear, and the whole
       crystal consists of maskelynite. Sample from a moderately
       shocked
       amphibolite fragment in suevite breccia. From Stöffler (1966),
       Fig. 4
       (plane-polarized light).
       resembling true PDFs are only rarely observed. At higher
       pressures, mafic minerals in naturally and experimentally
       shocked basalts generally show only extreme comminution,
       accompanied by the melting and flow of associated feldspar
       (Kieffer et al., 1976b; Schaal and Hörz, 1977). PDFs are
       therefore
       unlikely to be observed in mafic minerals in impact structures.
       The higher pressures apparently required for their
       formation imply that they will form in a correspondingly
       smaller volume of shocked rock in the structure. Furthermore,
       the higher shock pressures required are closer to pressures
       that produce partial to complete melting of the rock,
       so that PDFs, even if formed, would not survive any subsequent
       melting episode.
       0.1 mm
       54 Traces of Catastrophe
       Fig. 4.29. Feldspar; multiple PDFs, “ladder” texture. Shocked
       K-feldspar, showing multiple sets of altered PDFs. Two types of
       planar
       deformation features are present: (1) long, thicker, widely
       spaced planes (clear areas, approximately east/west) that may be
       deformation
       bands or kink bands; (2) short, narrower, closely spaced
       features (northeast/southwest and
       north-northwest/south-southeast) that combine
       with the first type to form a distinctive “ladder” texture. The
       planar features have a brownish-red color, possibly caused by
       alteration of the
       feldspar to clay minerals and iron oxides. Sample from a small
       granitic gneiss inclusion in the Onaping Formation “Black
       Member” from
       the type locality, Onaping Falls (Highway 144, Dowling
       Township), northwestern corner of the Sudbury structure
       (Canada). Photograph
       courtesy of N. M. Short. Sample CSF-66-39 (cross-polarized
       light).
       Fig. 4.30. Feldspar; twinning and PDFs. Large deformed feldspar
       crystal (microcline?) in granitic fragment in suevite breccia.
       Original
       twinning in the feldspar (light/dark pattern,
       northwest/southeast) is deformed and faulted along multiple
       parallel fractures (east-northeast/
       west-southwest). Elsewhere, the feldspar is cut by a single set
       of short, narrow, closely spaced planar features
       (northeast/southwest) that
       may be actual PDFs. Sample from a small block of granitic gneiss
       from the Onaping Formation “Black Member,” Sudbury (Canada).
       Sample CSF-67-73 (cross-polarized light).
       0.1 mm
       0.1 mm
       Shock-Metamorphic Effects in Rocks and Minerals 55
       4.7. SHOCK ISOTROPIZATION AND
       DIAPLECTIC GLASSES
       Planar microstructures form at relatively low shock pressures
       (>7–35 GPa) (Table 4.2) (Stöffler and Langenhorst,
       1994) and involve only partial and localized deformation of
       the host crystal. PDFs, which develop in the upper part of
       this range (10–35 GPa), involve actual conversion of the
       quartz crystal structure to an amorphous phase within the
       individual planes. Higher shock pressures (35–45 GPa),
       which transmit more energy into the crystal, do not form
       PDFs. Instead, the shock waves convert the entire crystal to
       an amorphous (glassy) phase.
       This shock-produced diaplectic glass (also called thetomorphic
       glass) (Stöffler, 1966, 1967, 1972, 1984; Chao, 1967;
       papers in French and Short, 1968) is completely different from
       conventional glasses produced by melting a mineral to a liquid
       at temperatures above its melting point. Diaplectic glasses
       do not melt or flow; they preserve the original textures of the
       crystal and the original fabric of the mineral in the rock. In
       addition, although diaplectic glasses are optically isotropic
       (i.e., they show no birefringence when examined petrographically
       under crossed polarizers), studies of quartz and feldspar
       diaplectic glasses by X-ray diffraction and infrared
       spectrometry have shown that they retain much of the ordered
       atomic structure of the original crystal (e.g., Bunch et
       al., 1967, 1968; Stöffler, 1974, 1984; Arndt et al., 1982).
       Samples of diaplectic feldspar glasses have also been
       experimentally
       annealed by heating at ambient pressure to produce
       original single crystals (Bunch et al., 1967, 1968; Arndt
       et al., 1982) or microcrystalline aggregates that preserve the
       shapes of the original feldspar crystals (Arndt et al., 1982;
       Ostertag and Stöffler, 1982).
       Quartz and feldspar are the most common examples of
       minerals converted to diaplectic glasses by shock waves.
       Diaplectic plagioclase feldspar glass, called maskelynite, was
       in fact observed in meteorites more than a century before it
       was discovered in shocked terrestrial rocks. The same material,
       often well preserved, is also observed at several impact
       structures where highly shocked rocks are preserved, e.g.,
       the Ries Crater (Germany) (Figs. 4.28, 4.32, and 4.33) and
       Manicouagan (Canada) (Fig. 4.31).
       In these occurrences, the unique textures of the diaplectic
       glasses clearly indicate formation without melting to the liquid
       state. The overall grain fabric of the rock is unchanged,
       and the diaplectic glasses preserve the shapes of the original
       quartz and feldspar grains. In some grains, the transformation
       to diaplectic glass is incomplete, and areas of relict
       birefringence
       remain in the otherwise isotropic material
       (Figs. 4.28 and 4.31). In some shocked plagioclase grains,
       one set of alternating albite twins is converted to maskelynite,
       while the twins of the other set remain birefringent. Other
       minerals (e.g., amphibole, garnet, micas), associated with (or
       even in contact with) grains of diaplectic glass, show little
       Fig. 4.31. Feldspar; diaplectic glass (maskelynite). Shocked
       plagioclase feldspar, partially converted to isotropic
       diaplectic feldspar
       glass (maskelynite). Parts of the original coarse feldspar
       grains remain crystalline and birefringent (light areas); these
       regions grade into
       adjoining areas of maskelynite (dark). Drill-core sample from
       coarse-grained basement anorthosite, exposed in the central
       uplift of the
       Manicouagan structure (Canada). Photograph courtesy of M. R.
       Dence. Sample DMM-73-63B (cross-polarized light).
       0.05 mm
       56 Traces of Catastrophe
       Fig. 4.32. Feldspar and quartz; diaplectic glasses. Biotite
       gneiss containing diaplectic feldspar glass (maskelynite)
       (clear, low relief;
       e.g., upper right) and diaplectic quartz glass (clear, higher
       relief, e.g., lower right). The associated biotite crystals
       (dark) have retained
       their original shape and have remained crystalline and
       birefringent, despite the complete transformation of adjacent
       quartz and plagioclase
       into glassy phases (compare with Fig. 4.33). Biotite gneiss
       inclusion in suevite breccia, Otting, Ries Crater (Germany).
       From Stöffler
       (1967), Fig. 12a. Photograph courtesy of D. Stöffler
       (plane-polarized light).
       Fig. 4.33. Feldspar and quartz; diaplectic glasses. Biotite
       gneiss containing diaplectic feldspar glass (maskelynite) and
       diaplectic quartz
       glass (compare with Fig. 4.32). Both phases are isotropic (dark)
       under crossed polarizers. The associated biotite crystals have
       retained
       their original shape and have remained crystalline and
       birefringent, despite the complete transformation of adjacent
       quartz and plagioclase
       into glassy phases. Biotite gneiss inclusion in suevite breccia,
       Otting, Ries Crater (Germany). From Stöffler (1967), Fig. 12b.
       Photograph
       courtesy of D. Stöffler (cross-polarized light).
       0.1 mm
       0.1 mm
       Shock-Metamorphic Effects in Rocks and Minerals 57
       deformation and retain their original form (Figs. 4.32 and
       4.33), although they may show reduced birefringence and
       reddening produced by the formation of hematite (e.g.,
       Feldman, 1994) and cordierite (Stähle, 1973).
       Diaplectic glasses formed from other minerals (e.g., scapolite)
       have rarely been observed. Mafic minerals (e.g., pyroxene,
       amphibole, and biotite) do not seem to form diaplectic
       glasses, probably because the pressures required are higher
       than those for quartz and feldspar, high enough so that
       shockproduced
       melting occurs instead.
       Diaplectic quartz and feldspar glasses are metastable. They
       apparently do not survive if they are exposed to even relatively
       mild postimpact thermal effects. Diaplectic glasses are
       not observed in impact structures that have been even slightly
       metamorphosed, even though decorated PDFs may still be
       preserved in associated quartz. In such settings, instead of
       diaplectic glasses, one observes quartz and feldspar grains
       that are recrystallized to microcrystalline aggregates that
       replace
       the original crystal (Figs. 4.34, 4.35, and 4.36). Textures
       in the altered feldspars sometimes suggest intense plastic
       deformation and flow within the original grain. These features
       are often accompanied by the development of plumose
       or spherulitic microcrystalline textures that may reflect
       significant
       thermal effects as well. Such grains of quartz and
       Fig. 4.34. Feldspar; possible diaplectic glass, recrystallized.
       Large, highly deformed and recrystallized feldspar clast in
       suevite breccia,
       surrounded by finer fragments in an opaque carbon-bearing
       matrix. The feldspar shows deformation and recrystallization
       throughout, as
       indicated by the intensely mosaic extinction. The crystal is
       subdivided by thin irregular zones of nearly isotropic material,
       possibly
       original melt. Plastic behavior of the fragment is also
       suggested by indentations of the matrix into the clast (e.g., at
       top). This clast can be
       interpreted as a fragment of diaplectic feldspar glass that has
       subsequently been recrystallized to form a fine-grained
       microcrystalline
       texture that is still similar to the original crystal. Similar
       reactions have been produced in experimentally annealed
       maskelynite. Another
       possibility is that the fragment was shock-heated above its
       melting point, but was rapidly quenched (perhaps during
       deposition) before
       extensive flow could occur. In any case, the unusual texture has
       been preserved despite subsequent metamorphism of the unit in
       which it
       occurs. Fragment in Onaping Formation “Black Member” from type
       locality, Onaping Falls (Highway 144, Dowling Township),
       northwestern corner of Sudbury structure (Canada). Sample
       CSF-66-37-2 (cross-polarized light).
       feldspar have been tentatively interpreted as original
       diaplectic
       glasses that have been annealed and recrystallized,
       either by immediate postshock thermal effects or by subsequent
       metamorphism (McIntyre, 1968; French, 1968b,
       pp. 401–404).
       4.8. SELECTIVE MINERAL MELTING
       The high-pressure (35–45 GPa) shock waves that produce
       diaplectic glasses also generate significant and sudden
       postshock temperature rises of several hundred degrees
       Celsius in the rocks and minerals through which they pass
       (Fig. 4.1). In the region of diaplectic glass formation,
       postshock temperatures are still low enough (300°–900°C)
       that virtually no actual melting occurs, and rapidly quenched
       samples of diaplectic glasses suffer no further immediate
       alteration. However, at slightly higher shock pressures
       (~45–50 GPa), the higher postshock temperatures (>1000°C)
       begin to exceed the melting points of typical rock-forming
       minerals, and distinctive localized melting effects appear in
       the affected rocks.
       This shock-produced selective mineral melting differs
       significantly from normal equilibrium melting. Under nor-
       0.5 mm
       58 Traces of Catastrophe
       Fig. 4.35. Feldspar; possible diaplectic glass, recrystallized.
       Shock-deformed and recrystallized feldspar and quartz from a
       coarse-grained granitic fragment in suevite breccia. Large
       original
       quartz grains (lower center; gray, higher relief ) are
       recrystallized
       to finely crystalline mosaic quartz. Original feldspar grains
       (clear,
       lower relief ) are generally finely recrystallized and virtually
       isotropic
       in some areas (compare with Fig. 4.36), although some areas of
       original feldspar crystals are preserved. From granitic
       inclusion in
       Onaping Formation “Black Member” at type locality, Onaping
       Falls (Highway 144, Dowling Township), northwestern corner of
       Sudbury structure (Canada). Sample CSF-66-50-13 (planepolarized
       light).
       Fig. 4.36. Feldspar; possible diaplectic glass, recrystallized.
       Shock-deformed and recrystallized feldspar and quartz from a
       granitic fragment in suevite breccia. Large original quartz
       grains
       are recrystallized to finely crystalline mosaic quartz. Original
       feldspar grains are generally finely recrystallized and
       virtually
       isotropic in some areas, although some areas of original
       feldspar
       crystals are preserved (compare with Fig. 4.35). In one such
       area
       (right center), a plagioclase crystal has been plastically
       deformed,
       bending the original polysynthetic albite twinning (light/dark
       bands) through a large angle. Despite the intense deformation of
       quartz and feldspar, a single apatite grain (lower right) shows
       no
       deformation. Sample from granitic inclusion in Onaping Formation
       “Black Member” at type locality, Onaping Falls (Highway 144,
       Dowling Township), northwestern corner of Sudbury structure
       (Canada). Sample CSF-66-50-13 (cross-polarized light).
       mal conditions of increasing overall temperature, melting
       occurs first at the boundaries between different mineral
       grains. Two or more different minerals are involved, and the
       resulting eutectic melt has a composition intermediate between
       that of the adjacent minerals and forms at a temperature
       well below that of their individual melting points. In a
       shock-wave environment, each mineral grain is instantaneously
       raised to a postshock temperature that depends on
       the shock-wave pressure and on the density and compressibility
       of the mineral itself. If the postshock temperature produced
       in a mineral exceeds its normal melting temperature,
       each grain of that mineral in the rock will melt, immediately
       and independently, after the shock wave has passed. The melt
       will have approximately the same composition as the original
       mineral before any flow or mixing takes place, and the
       melt regions will initially be distributed through the rock in
       the same pattern as the original mineral grains.
       Selective melting therefore produces unusual textures in
       which one or more minerals in a rock show typical melting
       features while others — even immediately adjacent ones —
       do not. Shocked granitic inclusions from the Ries Crater
       (Germany) frequently show a texture in which feldspar has
       melted, flowed, and vesiculated, but the adjacent quartz remains
       in the form of unmelted diaplectic glass (Chao, 1967;
       Stöffler, 1972, 1984). Similar textures can be preserved even
       in subsequently metamorphosed rocks, in which flowed and
       recrystallized feldspar is accompanied by recrystallized but
       undeformed grains of quartz (Fig. 4.37).
       0.5 mm 0.5 mm
       Shock-Metamorphic Effects in Rocks and Minerals 59
       Fig. 4.37. High-temperature effects; plastic deformation,
       grain-boundary melting. Highly shocked and recrystallized
       quartzofeldspathic
       inclusion in metamorphosed suevite breccia, showing extreme
       deformation of quartz and feldspar. Quartz (gray, higher relief,
       lower right)
       is recrystallized to a fine mosaic of small quartz grains.
       Feldspar (clear, lower relief, top) shows intense, contorted
       flow structure, indicating
       either incipient melting or extreme plastic flow. Definite
       incipient melting has occurred at the grain boundaries, forming
       a brown melt
       (dark) with lath-like microlites (white; feldspar?). (Circular
       feature at center is a bubble in the thin section.)
       Coarse-grained granitic
       inclusion in Onaping Formation “Black Member,” Sudbury structure
       (Canada). Sample CSF-67-67 (plane-polarized light).
       At higher shock pressures, where temperatures are higher
       and cooling times may be longer, these selective melting
       textures
       may be complicated by the effects of normal eutectic
       melting at grain boundaries (Fig. 4.37). In some shocked
       rocks, postshock temperatures may exceed the melting points
       of all the minerals present, and the rock will melt to a mixture
       of heterogeneous glasses that may preserve (depending
       on the amount of subsequent flow and mixing) the original
       shapes and mineral compositions. If such rocks are quenched
       before flow and mixing can occur, the chemically diverse
       glasses can survive and be recognized, even after significant
       metamorphism (Fig. 4.38) (Peredery, 1972).
       Such distinctive selective melting textures are relatively
       uncommon in rocks from impact structures. The region of
       shock pressures that produces them is relatively narrow (~45–
       55 GPa), and their preservation, once formed, requires rapid
       quenching, most commonly as small inclusions in crater-fill
       breccias. At progressively higher shock pressures (>55 GPa),
       postshock temperatures increase rapidly, melting becomes
       complete, flow and mixing processes become dominant in
       the melted rock, and more chemically homogeneous bodies
       of impact melt are produced (see Chapter 6).
       0.5 mm
       60 Traces of Catastrophe
       Fig. 4.38. High-temperature effects; complete melting. Highly
       shocked, melted, and recrystallized rock inclusion in
       metamorphosed
       suevite breccia. Postshock temperatures apparently exceeded the
       melting points of all component minerals, converting the
       originally
       crystalline rock into an initially heterogeneous glass that
       developed limited flow textures before it was quenched. The
       inclusion was
       subsequently recrystallized to secondary minerals such as
       quartz, feldspar, amphibole, and chlorite, but the original
       mineralogy and the
       character of the shock-formed heterogeneous glass are still
       detectable in the distribution and chemical variations in the
       secondary mineral
       assemblage. Inclusion in Onaping Formation “Black Member” at the
       type locality, Onaping Falls (Highway 144, Dowling Township),
       northwestern corner of Sudbury structure (Canada). Sample
       CSF-66-50-3 (plane-polarized light).
       0.5 mm
       #Post#: 81--------------------------------------------------
       Re: Traces of Cat.
       By: Admin Date: January 29, 2017, 6:03 am
       ---------------------------------------------------------
       Shock-Metamorphosed Rocks (Impactites) in Impact Structures 61
       61
       5.1. ROCK TYPES IN THE FINAL
       IMPACT STRUCTURE
       A wide variety of distinctive rock types — breccias, melts,
       and shock-metamorphosed target rocks — are produced
       during formation of impact structures. The classification
       of these complex and diverse rocks is an active and muchdebated
       activity (see below). However, the general term
       impactite is used here as a convenient overall designation
       for all rocks affected by, or produced by, the shock waves
       and other processes generated by hypervelocity meteorite
       impact events.
       Different varieties of impactites are produced at different
       times during the impact process, and they occur in different
       locations beneath, within, and around the final impact
       structure.
       The diverse features of impactites reflect, in varying
       ways, different aspects of the impact event itself: (1) the
       initial shock-wave distribution around the impact point;
       (2) the subsequent excavation flow, formation of the transient
       crater, and ejection of material from it; (3) the crater
       modification processes. The general model described below
       will be modified, in actual impact structures, by such
       individual
       factors as the target lithology, stratigraphy, and the
       nature and impact angle of the projectile, but the model
       provides
       a general basis for the identification and classification
       of impactites (see also Dence, 1968; Grieve, 1991; Stöffler et
       al., 1988).
       The basic distribution of shock-wave pressures around
       the impact point is largely established by the end of the
       contact/
       compression stage. The expanding shock waves deposit
       energy continuously in the target rocks through which they
       pass, and both their peak pressures and the resulting postshock
       temperatures drop rapidly with distance from the impact
       point. As the contact/compression stage ends, and the
       transient crater begins to form, the zones of shock pressure
       form a series of approximately hemispherical shells around
       the impact point, with the peak shock pressure decreasing
       rapidly outward (Fig. 3.2).
       During the subsequent excavation stage and formation
       of the transient crater, virtually all the target rock exposed
       to
       shock pressures of >25–30 GPa, which now consists of a
       mixture of vapor, superheated rock melt, and coherent but
       highly shocked target rock, is broken up and accelerated
       outward (Dence, 1968; Dence et al., 1977; Grieve and Cintala,
       1981). Because the excavation flow lines cut across the
       originally
       hemispherical shock-pressure zones (Fig. 3.4), the excavated
       material will consist of a mixture of target rocks
       subjected to widely differing shock pressures and showing a
       wide range of shock effects. A melt-rich portion flows downward
       and outward from the center to form a coating along
       the floor and walls of the growing crater (Grieve et al., 1977).
       The remainder, a mixture of rock fragments and smaller bodies
       of melt, is impelled outward from the center of the cavity.
       Much of this material may be entirely ejected from the transient
       crater; some may remain within the crater as a unit of
       mixed rubble and melt above the fractured crater floor.
       The subcrater rocks beneath the zone of excavation are
       subjected to lower shock pressures ( >30 GPa), and the dominant
       effects produced are shatter cones, brecciation, and inplace
       fracturing. As the upper part of the target rocks are
       excavated from the transient crater, these rocks are displaced
       downward, more or less coherently, to form the floor of the
       transient crater and the zone of parautochthonous rocks
       beneath it.
       The final modification of the transient crater into a simple
       or complex impact structure involves several distinct gravity-
       related processes that influence the distribution of
       impactite units: (1) rapid relative movements of large blocks
       of subcrater target rocks downward, inward, and upward
       along relatively narrow faults; (2) collapse of oversteepened
       Shock-Metamorphosed Rocks (Impactites)
       in Impact Structures
       62 Traces of Catastrophe
       crater walls into the crater cavity; (3) deposition of a minor
       amount of ejected material within the crater. The first process
       may create additional breccias and related rock types
       beneath the crater. The other two processes produce a large
       portion of the crater-fill deposits, which are characterized
       by a generally fragmental character and the presence of
       shockmetamorphic
       effects that range from simple fracturing to
       complete melting.
       5.2. CLASSIFICATION OF IMPACTITES
       The definition and classification of impact-produced
       materials, both individual rock fragments and large formations,
       is a complex, longstanding, and difficult subject (for
       details, see Stöffler, 1971; Stöffler et al., 1979; Taylor et
       al.,
       1991; Stöffler and Grieve, 1994, 1996; Reimold, 1995). No
       attempt will be made here to develop a complete and unanimously
       acceptable system. The simplified system presented
       here emphasizes field and petrologic characteristics and is
       based, as far as possible, on objective features that are
       observable
       in outcrop, hand specimen, and thin section. This
       classification also uses, as much as possible, traditional terms
       already applied to equivalent rocks (e.g., breccias, melt rocks)
       formed by common geological processes. Although this system
       is generally consistent with more detailed classifications
       (e.g., Stöffler and Grieve, 1994), it is restricted to
       terrestrial
       rock types produced in single impact events and does not
       consider the special complexities of cratering on other planets,
       including the effects of multiple impacts or the absence
       of an atmosphere (see Taylor et al., 1991; Stöffler and Grieve,
       1994, 1996).
       The term impactite is used here to designate all rocks
       produced during an impact event, including shock-metamorphosed
       (but still recognizable) target rocks (both in place
       and as fragments in breccias), breccias, and impact melts.
       Under this umbrella, the classification and terminology of
       impactite formations are based on a few key features: location
       with respect to the crater, source(s) of component materials,
       and lithologic characteristics (Table 5.1).
       More detailed discriminators, used in other classifications,
       include (1) particle sizes and size ranges; (2) relative
       percentages
       of components in breccias, e.g., ratios of fragments/
       matrix, and lithic/glassy fragments; (3) shock-metamorphic
       effects in individual breccia fragments (both the shock level
       in individual fragments and the range of shock effects in
       multiple fragments); and (4) textures and crystallinity of
       melt rocks.
       In earlier discussions of impactites and the cratering process
       (Dence, 1965, 1968; Grieve, 1991), a fundamental and
       useful distinction has been made between the parautochthonous
       rocks beneath the crater floor and the allogenic (or
       allochthonous) units (breccias and melt rocks) that fill the
       crater (crater-fill units) and form the units of ejecta outside
       it (Figs. 3.7 and 3.13). The observed characteristics of these
       different rock types are frequently distinctive enough that
       they can be distinguished, even in isolated hand specimens
       or outcrops.
       The parautochthonous rocks beneath the crater have
       remained relatively coherent during crater formation, although
       they have been deformed and displaced. These rocks,
       which correspond to the lower displaced zone of the transient
       crater, are subjected to relatively lower shock pressures,
       and observed shock-deformation effects are generally
       limited to fracturing, brecciation, and the formation of shatter
       cones, although higher-pressure mineral-deformation
       features may be developed in a relatively small volume beneath
       the crater floor. The allogenic rocks, chiefly breccias
       and melts, that fill the crater and make up the ejecta beyond
       the crater rim, are characterized by a more diverse lithology,
       a fragmental or melted character, and a wide range
       of observed shock effects. In particular, the crater-fill
       breccias
       are a complex mixture of materials with different histories
       of shock pressures and transport: unshocked rocks
       derived from the distant parts of the crater rim and walls,
       more highly shocked and melted fragments excavated from
       the transient crater and redeposited, and large and small
       bodies of impact-generated melt.
       The following sections discuss impactites on the basis of
       location with respect to the impact structure: (1) subcrater:
       parautochthonous rocks, cross-cutting allogenic
       units, and pseudotachylite; (2) crater interior: allogenic
       crater-fill deposits (lithic breccias, suevite breccias, and
       impact
       melt breccias); (3) crater rim region: proximal ejecta
       deposits; (4) distant from crater: distal ejecta. A detailed
       discussion of impact melt rocks in these different environments
       is provided in Chapter 7.
       5.3. SUBCRATER ROCKS
       5.3.1. Formation Conditions
       During formation of the transient crater, the rocks located
       in the displaced zone below the zone of excavation are
       driven downward and outward, more or less coherently
       (Fig. 3.4), but they are not completely broken up or excavated.
       Instead, they are deformed, thinned, and moved downward
       and outward as the transient crater forms, and then (in
       the central parts of larger structures) rapidly elevated as the
       central uplift forms (Dence, 1968; Dence et al., 1977; Kieffer
       and Simonds, 1980; Grieve and Cintala, 1981; Grieve et al.,
       1981; Stöffler et al., 1988).
       During these movements, the subcrater rocks are generally
       displaced as large individual blocks typically tens to hundreds
       of meters (or even larger) in size. However, adjacent
       regions within this zone may display little displacement
       relative
       to each other, and original stratigraphy and structural
       features may be well preserved within individual blocks. The
       term parautochthonous has therefore been applied to these
       rocks to indicate their general relative coherence.
       The shock pressures imposed on the parautochthonous
       rocks vary widely because of the complex relationship beShock-
       Metamorphosed Rocks (Impactites) in Impact Structures 63
       tween the original shock-wave distribution and the subsequent
       crater modification. Shock pressures in the parautochthonous
       rocks are therefore highest near the center of
       the structure and decrease rapidly outward toward the margin.
       Along the floor of the transient cavity (approximately
       the floor of the final crater), shock pressures may exceed 25–
       30 GPa in the center, decreasing to >2 GPa at the rim, the
       minimum pressure needed to excavate material from the transient
       crater (Grieve and Robertson, 1976; Robertson and
       Grieve, 1977; Kieffer and Simonds, 1980; Dressler et al., 1998).
       Shock pressures also drop off rapidly with increasing depth
       below the crater floor. In the center, pressures typically drop
       from about 25–30 GPa to a few GPa over distances of less
       than a few hundred meters in small structures (Dence et al.,
       1977; Grieve et al., 1981) and over no more than a few
       kilometers
       in larger ones (Stöffler et al., 1988).
       5.3.2. In-Place Shock-Metamorphosed Rocks
       The shock effects preserved in the parautochthonous
       subcrater rocks therefore reflect a wide range of shock
       pressures.
       In a small region immediately below the central part
       of the crater floor (i.e., at the base of the excavation zone),
       TABLE 5.1. Criteria for impactite classification.
       1. Location with respect to crater (Rc = crater radius)
       Crater Floor and Subcrater Within Crater Crater Rim and
       Near-Surface
       Parauthochtonous rocks: Allogenic rocks: Allogenic rocks:
       target rocks (coherent) Crater-fill deposits Ejecta:
       lithic breccias (= crater-fill breccias) proximal (<5 Rc)
       (= “breccia lens”) distal (>5 Rc)
       Allogenic rocks (cross-cutting) lithic breccias
       breccia dikes melt-bearing breccias
       impact melt dikes suevites
       impact melt breccias
       Pseudotachylite (= melt-matrix breccias)
       impact melt rocks
       2. Sources of component materials
       Parautochthonous rocks Allogenic rocks
       Approximately in place (local). Original stratigraphy Derived
       from single or multiple sources elsewhere.
       and structure (largely) preserved.
       3. Breccia characteristics
       a. Fragment character Lithic breccia Suevite (breccia)
       Rock/mineral fragments only Melt/glass fragments present
       Rock/mineral fragments
       b. Fragment lithology Monomict (breccia) Polymict (breccia)
       Single rock type Multiple rock types
       c. Matrix character Clastic-matrix (breccia) Impact melt breccia
       (= melt-matrix breccia)
       Discrete fragments Coherent melt (glassy or crystalline)
       4. Melt rock character (standard geological terms)
       Holohyaline (glassy) For grain size, texture, etc., use other
       standard igneous rock
       Hypocrystalline (mixed glassy/crystalline) discriminators, e.g.:
       Holocrystalline (completely crystalline) Microcrystalline
       Porphyritic
       Trachytic, etc.
       64 Traces of Catastrophe
       pressures of 10–30 GPa produce distinctive microscopic
       deformation effects in quartz and feldspar, while creating
       postshock temperatures of >300°C. In smaller impact structures,
       this zone of identifiably high shock pressures is less
       than a few hundred meters thick, partly because of the rapid
       decay of the original shock wave with distance from the impact
       point, and partly because of the subsequent compression,
       thinning, and displacement of the subcrater rocks during
       transient crater formation (Dence et al., 1977; Grieve and
       Cintala, 1981). Beneath this zone, lower shock pressures
       (possibly 2–6 GPa) produce distinctive megascopic deformation
       features (shatter cones) in a deeper region near the
       center of the crater.
       Shock pressures over most of the zone of parautochthonous
       rocks are too low ( >2 GPa) to produce distinctive
       shock-deformation effects, but they are high enough to exceed
       the yield strengths of near-surface crustal rocks (typically
       <1–2 GPa; Kieffer and Simonds, 1980). As a result, large
       volumes of rock beneath the crater floor are broken and
       crushed during the early stages of crater formation, producing
       units of in-place lithic breccia that generally lack distinctive
       high-pressure shock-metamorphic effects. At the
       same time, and subsequently, larger fractures that develop in
       this zone may be intruded by allogenic materials (rock fragments
       and/or melt) to form cross-cutting dike-like bodies
       (e.g., Lambert, 1981; Bischoff and Oskierski, 1987; Dressler
       and Sharpton, 1997).
       The parautochthonous rocks below the crater may also
       be strongly affected by subsequent large-scale movements
       during the crater modification stage. Such movements may
       produce equally striking but different breccias. In large
       structures,
       where modification involves the development of a central
       uplift, deep-seated parautochthonous rocks may be
       suddenly uplifted for distances of hundreds of meters to several
       kilometers. This uplift may bring distinctively shocked
       rocks (e.g., containing shatter cones) to the surface, where
       they may provide definite evidence for the impact origin of a
       large structure. However, these rapid movements may also
       generate additional varieties of breccias and destroy the
       original
       spatial relations of the parautochthonous rocks to each
       other, making the geology and history of the structure more
       difficult to decipher.
       Understanding the variety of breccias in subcrater rocks
       is complicated by several factors (e.g., Lambert, 1981; Bischoff
       and Oskierski, 1987; Dressler and Sharpton, 1997). Breccias
       may form at various stages in the cratering process: (1) during
       the initial shock-wave expansion and transient crater
       formation; (2) during the subsequent modification of the
       transient crater, including (in large structures) movements
       associated with the rise of the central uplift and peripheral
       collapse around the rim. Even within the brief formation
       time of an impact crater, it is possible for multiple
       generations
       of breccia to develop and to produce distinctive crosscutting
       relations, even though the time between one breccia
       generation and the next may be measured in seconds or minutes
       (Lambert, 1981; Bischoff and Oskierski, 1987; Dressler
       and Sharpton, 1997). Another problem is melt formation;
       rocks can be shock-melted by the initial impact and then
       distributed as melts or melt-bearing breccias throughout the
       crater basement, but rocks can also be melted subsequently
       by friction generated during the rapid movements of large
       volumes of rock involved in crater modification and central
       uplift formation.
       5.3.3. Lithic Breccias (Parautochthonous)
       Impactite breccias that form by the shattering and pulverizing
       of target rock essentially in place (autoclastic) typically
       form irregular bodies tens to hundreds of meters in size,
       which show gradational contacts against areas of similar
       but more coherent target rocks. These lithic breccias are
       composed entirely of rock and mineral fragments in a clastic
       matrix of smaller, but similar, fragments. Fragments tend
       to be angular to sharp, although fragments of softer rocks
       like carbonates and shales may be well rounded. The breccias
       themselves tend to be poorly sorted. The fragments are
       derived from local target rocks, and the breccias may be
       monomict or polymict, depending on the lithologic variety
       present in the nearby target rocks. Distinctive
       shock-metamorphic
       effects (e.g., PDFs in quartz) are generally absent
       in the fragments. The breccias show no evidence of significant
       transport, and they contain no exotic fragments or
       glassy material.
       These rocks often resemble breccias formed by more normal
       geological mechanisms such as volcanic explosions or
       tectonic movements, and their identification as impact products
       is often difficult and uncertain. In general, the subcrater
       regions of impact structures display highly localized and
       variable
       deformation over short distances, a close association of
       different kinds of breccias developed from basement rocks,
       and the presence of allochthonous dike-like bodies of breccia
       and melt. This variability in deformation and rock types
       contrasts with the more uniform or gradational effects produced
       by endogenic mechanisms. Even so, identification of
       these rocks as impact breccias can generally not be done
       directly, but depends on demonstrating their association with
       more highly shocked rocks whose impact origin is clear (e.g.,
       French et al., 1997).
       5.3.4. Cross-Cutting (Allogenic) Breccias
       Other bodies of breccia in the subcrater rocks contain
       significant amounts of material that have clearly been
       introduced
       into them from elsewhere, and they are therefore considered
       here as allogenic breccias. These bodies tend to have
       more regular shapes and to show sharp contacts and clear
       cross-cutting relations against the subcrater rocks. Such
       breccias
       often occur as distinctive breccia dikes, which typically
       range from less than a meter to tens of meters in width and
       may be as much as a kilometer long (Lambert, 1981; Bischoff
       and Oskierski, 1987; Dressler and Sharpton, 1997). These bodies
       contain fragments of target rock that are angular to
       rounded and range in size from <1 mm to several meters.
       These breccias tend to be polymict, with lithologically diverse
       fragments, indicating mixing over distances of at least
       several hundred meters. In addition, they frequently contain
       Shock-Metamorphosed Rocks (Impactites) in Impact Structures 65
       significant amounts of allogenic material, such as fragments
       from even more distant rock units. This allogenic material is
       frequently derived from more central regions of the crater,
       often from above the present location of the dike, and it often
       consists of distinctive highly shocked rock fragments
       or melt.
       A wide variety of such cross-cutting breccias has been
       reported from several impact structures (Lambert, 1981;
       Bischoff and Oskierski, 1987; Dressler and Sharpton, 1997):
       (1) melt-free, typically polymict, lithic breccias with a
       clastic
       matrix; (2) melt-fragment breccias containing fragments
       of heterogeneous glass, rocks, and minerals in a clastic matrix;
       (3) melt-matrix breccias (impact melt breccias), composed
       of rock and mineral fragments in a matrix of glassy or
       crystalline melt; (4) impact melt rocks, composed of glassy
       or crystalline melt with few or no inclusions (e.g., Dence,
       1971). Many of these dikes are similar to units of breccia or
       melt in the crater-fill units above the crater floor, and they
       may in fact be continuous with them (e.g., Lambert, 1981).
       Subcrater breccia dikes often contain materials (e.g., rock
       fragments or melt) that were originally located at higher
       stratigraphic levels closer to the impact point, indicating that
       the materials in the dikes have been emplaced downward
       and/or outward into fractures that opened in the crater floor
       during formation and modification of the crater. In many
       structures, more than one generation of dikes occurs, with
       later ones cutting earlier ones (Lambert, 1981; Dressler and
       Sharpton, 1997). These relations indicate that, even during
       the brief duration (seconds to minutes) of crater formation
       and modification, a variety of distinct breccia types can be
       generated and emplaced. However, in the crater environment,
       cross-cutting relations between breccia bodies do not
       imply the passage of significant amounts of time between
       emplacements, a conclusion supported by the fact that the
       cross-cutting relations between different types of breccia may
       not be consistent from place to place within the whole structure
       (Dressler and Sharpton, 1997).
       5.3.5. Pseudotachylite
       Pseudotachylite is an unusual, much-studied, and longdebated
       type of impactite breccia that occurs in the parautochthonous
       rocks of large impact structures (for recent
       reviews, see Reimold, 1991, 1995; Spray, 1995). Pseudotachylite
       is most strikingly developed at two large, ancient
       impact structures: Vredefort (South Africa) (Shand, 1916;
       Reimold, 1991; Reimold and Colliston, 1994) and Sudbury
       (Canada) (Fairbairn and Robson, 1941; Speers, 1957; Dressler,
       1984; Thompson and Spray, 1994; Spray and Thompson, 1995),
       where it forms striking and extensive exposures (Figs. 5.1
       and 5.2). The Vredefort pseudotachylite, first described more
       than 80 years ago (Shand, 1916), typically occurs as abundant
       irregular, anastomosing, and dike-like bodies that
       contain numerous large and small rounded inclusions of
       target rock set in a dense, aphanitic or crystalline matrix that
       is generally black to blackish-green in color. Similar breccias,
       although developed on a much smaller scale, have been
       observed in other impact structures, e.g., Rochechouart
       (France) (Reimold et al., 1987), Manicouagan (Canada)
       (Dressler, 1990), and Slate Islands (Canada) (Dressler and
       Sharpton, 1997).
       At Sudbury and Vredefort, pseudotachylite is extensive.
       Pseudotachylite exposures at Sudbury cover as much as 100–
       200 km2, or a few percent of the total area of the structure.
       Individual pseudotachylite bodies can also be large; the largest
       body so far recognized at Sudbury is more than 11 km
       long, more than 400 m wide, and contains discrete fragments
       that are hundreds of meters in size (Dressler, 1984). In smaller
       impact structures, pseudotachylite bodies are smaller and less
       abundant; the material typically occurs as irregular dike-like
       bodies less than a meter across.
       The individual pseudotachylite bodies in impact structures
       are not uniform over long distances and may change
       size and shape radically within meters or tens of meters.
       The more elongate dike-like bodies show little or no preferred
       orientation in direction. The fragment/matrix ratio in
       Fig. 5.1. Pseudotachylite in granitic gneisses. Pseudotachylite
       exposure, showing rounded gneiss inclusions from a few
       centimeters
       up to a few meters in size in a dense black matrix. The
       inclusions
       show a significant amount of rotation relative to each other.
       Southwest
       sector of the Vredefort structure (South Africa) (farm Samaria
       484). Black pen on large inclusion in center (arrow) is 15 cm
       long;
       inclusion itself is about 50 cm long. From Reimold and Colliston
       (1994); photograph courtesy of W. U. Reimold.
       66 Traces of Catastrophe
       pseudotachylite bodies also varies significantly over short
       distances, and some pseudotachylite breccias consist only of
       fractured target rocks cut by thin veins of black matrix less
       than a few millimeters wide. (The descriptive term “cobweb
       breccias” has been used as a convenient field label for such
       occurrences.)
       Contacts between pseudotachylite bodies and the enclosing
       target rock are irregular and generally not parallel on
       opposite sides. Offsets of wallrock along pseudotachylite
       bodies are uncommon, and observed displacements are minor
       (e.g., <100 m). In very large pseudotachylite bodies with
       large inclusions, the boundary between the breccia body and
       the unbrecciated wallrock may not be clear. In such occurrences,
       e.g., at Sudbury, the exact boundaries between breccia
       and undisturbed wallrock may be difficult to establish
       (Dressler, 1984).
       Inclusions in pseudotachylite range from submicroscopic
       to hundreds of meters in size. They invariably consist of local
       bedrock, and there is generally no evidence for significant
       long-distance (>100 m) transport of fragments during
       formation. The inclusions are irregularly oriented, and outcrops
       of the breccia give the strong impression of an overall
       tensional or explosive environment (Figs. 5.1 and 5.2), rather
       than the narrower compressional/shear environment that is
       characteristic of zones of major thrust faulting (Philpotts,
       1964; Sibson, 1975; Spray, 1995). Larger inclusions (>1 cm)
       are generally rounded, while smaller ones tend to be angular
       or sharp. Contacts between both large and small inclusions
       and the surrounding matrix are generally sharp. However,
       some inclusions may be deformed at the rims, forming a
       flow structure that can be observed, both megascopically
       and microscopically, to grade into the surrounding matrix
       (Fig. 5.3).
       The matrix between larger rock fragments is dense and
       coherent. In hand specimen, the matrix often shows a conchoidal
       or hackly texture on broken surfaces. The color is
       commonly black to blackish green on fresh surfaces, although
       the color may vary slightly with the host rock involved. The
       matrix occurs in a wide variety of forms. It may cover large
       (meter-sized) areas of inclusion-poor material, or it may form
       tiny submillimeter filaments that penetrate bedrock and
       inclusions
       and often terminate within them. In hand specimen
       and thin section, the matrix is commonly structureless
       (Fig. 5.4), but flow-banding is often observed, especially in
       thin section (Fig. 5.3). This flow-banding may involve
       inclusions
       that have been plastically deformed and possibly
       melted (Fig. 5.5).
       The matrix, generally aphanitic in hand specimen, is extremely
       fine-grained and difficult to characterize, even in
       thin section. In some samples, the matrix shows definite mi-
       Fig. 5.2. Pseudotachylite; metamorphosed, in quartzite. Dark
       pseudotachylite (“Sudbury Breccia”) in Mississagi Quartzite on
       South
       Range of Sudbury structure (Canada). Exposure shows large
       rounded blocks of quartzite in a pervasive black matrix (note
       penetration of
       matrix into large quartzite block at lower right). Hammer (upper
       right) gives scale. Photograph courtesy of W. Peredery.
       Shock-Metamorphosed Rocks (Impactites) in Impact Structures 67
       Fig. 5.3. Pseudotachylite; flow-banded texture. Pseudotachylite
       (“Levack breccia”) in granitic gneisses from the North Range of
       the
       Sudbury structure (Canada). In thin section, the black
       pseudotachylite matrix material consists of small irregular rock
       and mineral
       inclusions in a dark microcrystalline to aphanitic groundmass.
       Numerous inclusions (white) show plastic deformation and
       alignment to
       form a flow structure; note concentric deformation of the flow
       structure around larger inclusions (e.g., top right). Thin
       vertical white lines
       are filled hairline fractures in the specimen. Sample CSF-67-53
       (plane-polarized light).
       Fig. 5.4. Pseudotachylite; structureless matrix. Pseudotachylite
       from Vredefort (South Africa), showing typical irregular to
       rounded
       inclusions, ranging in size from <100 &#956;m to several
       millimeters, in a dark aphanitic groundmass. Inclusions, which
       are rock and mineral
       fragments from granitic gneisses, show sharp contacts with the
       matrix. In this pseudotachylite sample, the matrix is
       structureless, and the
       inclusions show no deformation, preferred orientation, or other
       flow structures. Sample AV-81-53 (plane-polarized light).
       1 mm
       1 mm
       68 Traces of Catastrophe
       crocrystalline melt textures at SEM or microscopic scales
       (Fig. 5.6). This characteristic, i.e., a matrix of igneous melt,
       has been proposed (but not unanimously accepted) as a
       distinguishing
       feature of pseudotachylite breccias (Spray, 1995).
       In other samples, the matrix appears to consist of small
       fragments
       in a cataclastic texture, and distinguishing between
       the two types is a difficult process with important implications
       for both classification and origin (Reimold, 1995).
       Chemical studies of pseudotachylites (e.g., Dressler, 1984;
       Reimold, 1991) have shown that they correspond closely to
       Fig. 5.5. Pseudotachylite; extensive melting and flow.
       Pseudotachylite (“Levack Breccia”) from granitic gneisses in the
       North Range
       of the Sudbury structure (Canada). The pseudotachylite consists
       of a heterogeneous mixture of plastically deformed and possibly
       melted
       wallrock fragments (light-colored), mixed with discontinuous
       areas of more typical pseudotachylite material (dark) consisting
       of small
       rock and mineral fragments in a fine black matrix. Sample
       CSF-88-2A (plane-polarized light).
       Fig. 5.6. Pseudotachylite; igneous matrix with microlites. Black
       pseudotachylite developed in central granitic gneisses at
       Vredefort
       structure (South Africa), consisting of small, irregular,
       generally rounded rock and mineral fragments in a black, finely
       crystalline matrix.
       Matrix shows igneous flow-banding, expressed by alignment of
       small feldspar microlites typically 50–100 &#956;m long. The
       microlites are
       often concentrically aligned around larger inclusions. Sample
       AV81-52A (plane-polarized light).
       1 mm
       0.5 mm
       Shock-Metamorphosed Rocks (Impactites) in Impact Structures 69
       the adjacent host rocks, indicating that they have formed
       essentially in place by locally generated cataclastic milling
       and/or frictional melting processes.
       Controversy and debate over the characteristics, terminology,
       and origin of pseudotachylite has existed ever since
       the term was first used (Shand, 1916) and continues actively
       today (e.g., Spray, 1995; Reimold, 1995). Shand (1916,
       pp. 188–189) deliberately coined the word “pseudotachylite”
       to distinguish the Vredefort material from tachylite (basaltic
       glass) and also from highly crushed and melted materials
       formed tectonically along major faults (“flinty crush-rock,”
       ultramylonite, hyalomylonite, etc.). Unfortunately, Shand’s
       term has since been widely applied to the latter type of
       material, so that it now designates similar glassy breccias
       that are clearly tectonic in origin (Philpotts, 1964; Sibson,
       1975; Reimold, 1995). Such breccias form in entirely different
       environments and are the results of intense deformation
       (including frictional melting) of rocks along the linear
       trends of faults. They form in a compressional /shear regime,
       but they can resemble impact-produced pseudotachylite,
       including the presence of melted material in the matrix
       (Philpotts, 1964).
       Recently, some workers have suggested that impactproduced
       pseudotachylites are formed in the same way as
       tectonic ones, i.e., by frictional heating during the rapid
       movements of late-stage crater development and modification
       (e.g., Thompson and Spray, 1994; Spray, 1995, 1997; Spray
       and Thompson, 1995). In this view, impact-produced
       pseudotachylites have essentially the same frictional-melt
       origin as tectonic ones. One possible way to distinguish between
       them may be size. Bodies of tectonic pseudotachylite
       tend to be linear and less than a few meters wide (Sibson,
       1975; Spray, 1995). Impact-produced pseudotachylites, at
       least at Sudbury and Vredefort, form more irregular bodies,
       some of which may reach tens to hundreds of meters in size
       (Thompson and Spray, 1994; Spray and Thompson, 1995).
       Another problem, even within the study of impact-produced
       breccias, is that the term “pseudotachylite” has been
       used to designate different types of impact-produced breccias
       formed at different stages (and possibly by different
       mechanisms) during crater formation (Martini, 1991;
       Reimold, 1995; Dressler and Sharpton, 1997). One suggestion
       (Martini, 1991) is to use the term “type A pseudotachylite”
       to designate relatively rare, small, glassy veins,
       typically less than a centimeter wide, that contain fragments
       in a matrix of melted material, often accompanied by
       shockproduced
       high-pressure mineral polymorphs such as coesite
       and stishovite (Martini, 1991). Such veins are believed to
       form during the early, higher-pressure, compressive stages
       of shock-wave expansion. In contrast, the more abundant,
       widespread, and more intensely studied material (called “type
       B pseudotachylite”) is thought (Martini, 1991) to form later,
       during crater modification and central uplift formation,
       probably
       by friction generated by the rapid movement of large
       volumes of target rock below the crater.
       Pseudotachylite breccias (especially the more familiar “type
       B” variety) are distinctive and recognizable at Vredefort and
       Sudbury, but their wider use as unique indicators of impact
       is complicated by several factors. First, since they form below
       the original crater floor, they are found only in impact
       structures that have been deeply enough eroded to expose
       target rocks originally located beneath the crater, and
       pseudotachylites are usually restricted to the central-uplift
       regions of larger structures. Second, pseudotachylites resemble
       rocks formed by nonimpact processes, and the
       distinction is difficult unless definite preserved
       shockmetamorphic
       effects can be found. The current confusion in
       terminology and formation mechanisms, combined with the
       scarcity of distinctive shock effects in many impact-produced
       pseudotachylites, makes it difficult to use pseudotachylites
       by themselves as unique indicators of impact structures.
       Despite these problems, well-developed pseudotachylites
       may still be a useful field tool for identifying possible
       impact structures for more detailed study. Pseudotachylites
       can be widespread in impact structures, and their distinctive
       appearance can survive even high-grade metamorphism
       (Fig. 5.2). The striking irregular and anastomosing character
       of pseudotachylite bodies, their rounded inclusions (often
       altered at the rims), their development over large areas,
       and the frequent absence of a regular shape or of compressional
       effects typical of similar fault-related breccias make
       them a valuable field indicator of a possible impact structure,
       and their discovery should be followed up with an intensive
       search for more definite shock effects. In addition, melt-rich
       pseudotachylite breccias in established impact structures
       have proven valuable for determining the formation ages
       of the structures themselves (Spray et al., 1995; Kelley and
       Spray, 1997).
       5.4. CRATER INTERIOR: CRATER-FILL
       DEPOSITS (BRECCIAS AND
       MELT ROCKS)
       5.4.1. Formation Conditions
       During the modification stage, material excavated from
       various locations in the growing transient crater is deposited
       within the final crater to form crater-fill deposits of breccia
       and melt rock. These allogenic units consist of four main
       components: (1) material ejected ballistically on steep or
       near-vertical trajectories that impacts within the final crater;
       (2) large and small bodies of impact melt that do not travel
       beyond the rim of the final crater; (3) large and small
       fragments
       of unshocked target rock that collapse from the
       oversteepened walls and rim of the original transient crater;
       (4) ejecta originally deposited near the transient crater rim
       and caught up in the subsequent collapse.
       As a result of these processes, the final crater is partially
       filled with a complex mixture of rock fragments (shocked
       and unshocked) together with bodies of impact melt. These
       deposits consist mostly of crater-fill breccias, often
       accompanied
       by discrete units of impact melt rocks. In small, bowlshaped,
       simple craters, the various components tend to be
       mixed together, and the final deposit may fill the crater to
       70 Traces of Catastrophe
       about half its depth. [This crater-fill unit is also called the
       breccia lens because of its shape (Fig. 3.7).] In larger complex
       structures, particularly those formed in crystalline target
       rocks, the crater-fill rocks typically contain discrete units
       of breccias and impact melts that form a large annular deposit
       around the central uplift (Fig. 3.13).
       Subsequent to formation of the crater and the deposition
       of impact-produced crater-fill breccias, the structure may
       be filled, and the breccias buried, by younger crater-fill
       sediments
       deposited more slowly by the conventional processes
       of erosion, transport, and deposition. These sediments not
       only preserve the underlying impact-produced breccias, but,
       because of their circular outcrop pattern and often anomalous
       character, they may call attention to previously unsuspected
       impact structures. In this section, the discussion and
       the term “crater-fill deposits” are limited only to the
       impactproduced
       breccias that fill the crater during and immediately
       after formation and do not include any ordinary
       sediments that may also be present.
       Many of the individual fragments in the crater-fill deposits
       have been derived from within the zone of crater excavation
       (Fig. 3.4) and may be highly shocked. Much of the
       target rock within the excavation zone is subjected to
       relatively
       high shock pressures of about 5 GPa to >100 GPa.
       The lowest pressures in this range are sufficient to shatter
       and brecciate the target rocks extensively; at higher pressures,
       the rocks are deformed and melted as well. Shocked
       Fig. 5.7. Crater-fill breccias. Recent drill coring along the
       southern
       flank of the Chicxulub structure (Mexico), has recovered impact
       breccias and melt rocks only shallowly buried beneath the
       younger
       carbonate sediments. This mosaic shows the sequence of diverse
       crater-fill breccias retrieved from the UNAM-5 drill core
       located
       near the village of Santa Elena in southern Yucatán, ~112 km
       from
       the center of the basin. The core pieces are arranged so that
       each
       represents 10 m of core. The top of the impact sequence (top of
       picture) occurs at a depth of ~330 m below the surface and is
       characterized by a 30-m interval of highly vesicular and
       pulverized
       impact melt rock (M). The melt rock horizon is almost completely
       altered to clay but contains abundant clasts of the target rock
       assemblage. Below this horizon is a varicolored continuous unit
       of
       suevite breccia (SB). As is typical of suevites, this unit has a
       clastic
       matrix containing a substantial proportion of highly shocked and
       melted clasts derived from lithologies that were originally deep
       within the target assemblage. The upper 50 m of the UNAM-5
       suevite (SB1) is characterized by abundant, centimeter-scale
       clasts
       of vesicular melt rock, similar to that of the overlying melt
       horizon
       but less altered. The middle 50 m of the suevite (SB2) is
       dominated
       by larger clasts of shocked to partially melted silicate
       basement
       rock showing abundant evidence of shock deformation. The matrix
       of the lower section of suevite (SB3) is more melt-rich and
       contains
       a greater proportion of centimeter-scale silicate clasts. Total
       depth
       was reached at the UNAM-5 well while still in the suevite. Coin
       is
       ~3 cm in diameter. Photograph courtesy of V. L. Sharpton.
       SB3 SB2 SB1 M
       330 m
       Shock-Metamorphosed Rocks (Impactites) in Impact Structures 71
       rock fragments, derived from this zone and deposited in the
       crater-fill breccias, have provided the best evidence for the
       impact origin of numerous structures.
       The crater-filling process is both rapid and chaotic, and
       mixing of the different components is not complete. The
       crater-fill deposits therefore contain a variety of distinctive
       allogenic breccias and melt rocks (Fig. 5.7). The simple
       classification
       used below is based on (1) fragment lithologies
       (lithic vs. melt-fragment breccias; (2) nature of the matrix
       (clastic vs. melt-matrix). (For more detailed discussions and
       classifications, see, e.g., Stöffler et al., 1979; Taylor et
       al., 1991;
       Stöffler and Grieve, 1994, 1996.)
       5.4.2. Lithic Breccias (Allogenic)
       Melt-free breccias (lithic breccias) form a common and
       distinct lithology in both large and small impact structures
       (Figs. 3.7 and 3.13). In small impact structures, e.g., Brent
       (Canada) (Dence, 1968; Grieve and Cintala, 1981), lithic
       breccias
       may form units hundreds of meters thick that extend
       over much of the final crater. At the larger Ries Crater
       (Germany), a distinctive allogenic polymict lithic breccia
       [the Bunte (“colored”) Breccia] occurs beneath the overlying
       melt-bearing suevite breccias both inside and outside
       the crater (Hörz, 1982; Hörz et al., 1983), with a sharp contact
       between the two units. In some impact structures, especially
       those formed in carbonate target rocks, lithic breccias
       may be the only type of crater-fill material present (Roddy,
       1968; Reiff, 1977).
       Lithic breccias consist of rock and mineral fragments in a
       clastic matrix of finer-grained similar material (Fig. 5.8). The
       breccias are poorly sorted; fragment sizes generally range from
       <1 mm to tens of meters. Fragments are typically sharp to
       angular in appearance. Unlike the lithic breccias found in
       parautochthonous rocks, crater-fill lithic breccias are more
       apt to be polymict because their fragments have been derived
       from a wider region of the original target rocks. Because
       most of the material in lithic breccias is derived from
       less-shocked regions around the walls and rim of the transient
       crater, distinctive shock effects are only rarely observed
       in the fragments.
       Within the crater-fill deposits, lithic breccias are often
       associated, both horizontally and vertically, with units that
       contain a melt component as discrete fragments or as a matrix
       for lithic fragments. Breccias with a few percent or more
       of a melt component are regarded as melt-bearing breccias,
       but the transition between these breccia types appears
       continuous,
       and no formal boundary has been established. Such
       melt-bearing breccias typically form a smaller proportion of
       the crater fill, perhaps 10–25 vol%, and the amount of melt
       component they contain varies from a few percent to
       >90 vol% (e.g., Hörz, 1982; Masaitis, 1983; von Engelhardt,
       1990, 1997).
       Two basically different types of melt-bearing breccias can
       be distinguished. In melt-fragment breccias (suevites), the
       melt component occurs as large (centimeter-sized) discrete
       bodies; in melt-matrix breccias (impact melt breccias), the
       melt forms a matrix for rock and mineral fragments (Stöffler
       and Grieve, 1994, 1996).
       5.4.3. Melt-Fragment Breccias (Allogenic) (Suevites)
       Melt-fragment breccias (suevites, pronounced “SWAYvites”)
       are composed of discrete fragments of rocks and minerals,
       together with bodies of melt, in a clastic matrix of similar
       but finer-grained materials. Many of the rock and mineral
       Fig. 5.8. Crater-fill breccia; lithic breccia. Poorly sorted
       crater-fill lithic breccia composed of angular to sharp
       fragments of granitic
       rocks and constituent minerals (quartz, feldspar, etc.) in a
       finer clastic matrix. Drill core sample from the Brent Crater
       (Canada). Photograph
       courtesy of R. A. F. Grieve (cross-polarized light).
       0.1 mm
       72 Traces of Catastrophe
       Fig. 5.9. Crater-fill breccia; suevite. Large hand specimen,
       about 45 cm long, of typical fresh suevite from the Ries Crater
       (Germany)
       (Otting quarry). The specimen consists of irregular and
       contorted individual fragments of glass (dark), which show a
       roughly parallel
       elongation, and crystalline rock fragments (light) in a fine
       clastic matrix. The glass fragments, which range up to 5 cm in
       size, are
       composed of a mixture of rock and mineral fragments in
       heterogeneous, flow-banded glass. Photograph courtesy of D.
       Stöffler.
       Fig. 5.10. Crater-fill breccia; suevite. Suevite breccia from
       Nicholson Lake (Canada), containing glass fragments (dark) with
       rock and
       mineral clasts in a finer fragmental matrix. The glass fragments
       are heterogeneous mixtures of mineral clasts (light) in dark,
       flow-banded
       glass. Photograph courtesy of M. R. Dence (plane-polarized
       light).
       5 mm
       Shock-Metamorphosed Rocks (Impactites) in Impact Structures 73
       fragments are highly shocked, and these breccias often provide
       the most distinctive evidence for a meteorite impact
       origin of the structures in which they are found.
       The term suevite was originally applied to melt-fragment
       breccias from the type occurrence at the Ries Crater (Germany),
       a relatively young (15 Ma) and well-preserved structure
       24 km across, in which well-exposed suevites and other
       impactites have been extensively studied and drilled (for
       reviews,
       see von Engelhardt et al., 1969; von Engelhardt and
       Graup, 1984; von Engelhardt, 1990, 1997). Suevite breccias
       are found both inside the structure (crater suevite or fallback
       suevite) and as preserved ejecta deposits (ejecta or fallout
       suevite) as far as 40 km from the center of the Ries structure.
       Suevite breccias from the Ries Crater and other impact
       structures typically consist of large (centimeter-sized)
       and smaller glassy bodies (typically 5–15 vol%), together
       with rock and mineral clasts in a matrix of finer fragments
       (Figs. 5.9 and 5.10). Glass-rich suevites are also known, in
       which the glass fragments may make up >50 vol% of the
       rock (Masaitis, 1994). Individual rock and glass fragments
       typically range from a maximum size of 10–20 cm down to
       submillimeter dimensions.
       The glassy bodies in the fallout suevite beyond the Ries
       Crater rim typically show irregular to contorted shapes and
       textures (Hörz, 1965). These bodies are typically heterogeneous,
       consisting of a polymict mixture of rock and mineral
       clasts (frequently highly shocked or partially melted) in a
       matrix of glass that may be compositionally heterogeneous
       and often shows well-developed flow structure (Fig. 5.11).
       At the Ries Crater, the larger (5–20 cm) glassy fragments
       in the ejecta deposits outside the structure, called Fladen,
       show a grooved and lobate flow structure that is evidence of
       aerodynamic sculpturing during their flight through the
       atmosphere (Hörz, 1965). These bodies also show brittle
       fractures
       developed on landing, implying that they were solid
       when they struck the ground. In contrast, glass bodies in the
       crater suevite are smaller (normally <5 cm) and lack distinctive
       sculpturing, implying that they did not travel through
       the atmosphere for any significant length of time (Fig. 5.12)
       (von Engelhardt and Graup, 1984; von Engelhardt, 1990).
       Although the Ries suevites are the best-known and most
       intensely studied examples of this rock type, impressive
       suevite breccias have been recognized in many other impact
       structures. However, in many of these structures, erosion has
       largely removed the ejecta deposits outside the crater, and
       the suevites occur only as crater-fill units, where they are
       associated with, and often interbedded with, lithic breccias
       and impact-melt rocks. Examples include Brent (Canada)
       (Dence, 1965, 1968; Grieve, 1978); Rochechouart (France)
       (Kraut and French, 1971); Popigai (Russia) (Masaitis et al.,
       1980; Masaitis, 1994); Manson (Iowa) (Koeberl and Anderson,
       1996a; Koeberl et al., 1996b); Gardnos (Norway) (French
       et al., 1997); Slate Islands (Canada) (Dressler and Sharpton,
       1997); and Roter Kamm (Namibia) (Reimold et al., 1997a).
       The Onaping Formation, a complex and metamorphosed
       Fig. 5.11. Crater-fill breccia; suevite; glassy inclusion.
       Heterogeneous, fragment-rich glassy fragment (Fladen) in suevite
       breccia from
       Lake Mien (Sweden), showing complex, multiple layering with
       varying amounts of rock and mineral inclusions. The mineral
       inclusions
       are typically sharp to angular and do not show the phenocryst
       shapes that are typically observed in glassy volcanic rocks. The
       generally
       laminar flow-banding is emphasized by a sharp difference in
       clast content and by dark streaks that may represent decomposed
       and melted
       opaque minerals. Note that flow-banding in the clast-rich layers
       (e.g., top) is more highly contorted. Sample NBS-61-0487
       (planepolarized
       light).
       1 mm
       74 Traces of Catastrophe
       Fig. 5.12. Crater-fill breccia; suevite. Typical poorly sorted
       suevite
       breccia in a core sample from the Nördlingen deep drill hole
       (369.9 m depth), Ries Crater (Germany). The unit contains
       crystalline
       rock fragments (light-colored) and glassy fragments (Fladen)
       (dark) in a fine clastic matrix. Inclusion at upper left
       contains a
       rock fragment (core) surrounded by a rim of flow-banded glass.
       Specimen is 10 cm wide. Photograph courtesy of H. Newsom.
       crater-fill unit at the 1.85-Ga Sudbury (Canada) impact
       structure, contains the oldest suevite unit identified so far
       (Fig. 5.13) (French, 1968b; Muir and Peredery, 1984;
       Avermann, 1994).
       Because of their high melt content and the occurrence of
       individual glassy bodies, suevite breccias resemble conventional
       volcanic breccias, and the suevite from the Ries Crater
       was considered to be a volcanic tuff for nearly two
       centuries. However, suevites differ from volcanic breccias in
       several ways, both in hand specimen and microscopically.
       Fragments in suevites show no volcanic textures; such typical
       volcanic features as feldspar phenocrysts or corroded
       quartz phenocrysts are absent (Figs. 5.10, 5.11, 5.14, and
       5.15). Rock fragments in suevites are not deep-seated volcanic
       xenoliths but are derived entirely from the underlying
       shallow target rocks. Suevites often contain cored inclusions,
       composite fragments in which a rim of glass is wrapped
       around a fragment of basement rock, indicating that both
       rock and melt were ejected into the air at the same time
       (Figs. 5.16, 5.17, and 5.18). Most convincing is the presence
       of unique high-pressure shock-metamorphic effects
       (such as PDFs in quartz or the high-pressure minerals coesite
       and stishovite), in rock and mineral inclusions in the suevite.
       High-temperature melting effects, e.g., the formation of silica
       glass (lechatelierite) from quartz, may also be present in the
       glass fragments in suevite.
       Despite their widespread distribution, suevite breccias are
       not found in all meteorite impact structures. In some cases,
       their absence is probably due to erosion, which has removed
       these near-surface deposits from the structure. However, the
       nature of the target rocks also seems important in determining
       whether suevites are formed (Kieffer and Simonds, 1980;
       Grieve and Cintala, 1992). Suevites have so far been observed
       only in impact structures formed largely or entirely in
       crystalline
       silicate rocks, possibly because these rocks melt to
       produce cohererent and durable bodies of glass. No suevite
       deposits have yet been found in impact structures formed in
       carbonate rocks, in which decarbonation and volatile loss,
       rather than melting, would be important.
       5.4.4. Melt-Matrix Breccias (Impact-Melt Breccias)
       Suevites inside the crater are closely associated with a
       different
       type of melt-bearing breccia: melt-matrix breccias
       or impact-melt breccias. In these units, the melt occurs, not
       as individual fragments, but as a matrix that typically makes
       up 25–75 vol% of the rock and may range from glassy material
       to completely crystalline igneous rock. The fragments,
       which consist of target rocks and minerals, are frequently
       shocked or melted.
       Impact-melt breccias form distinct bodies of widely varying
       size, from small glassy inclusions in suevite breccias to
       distinct dike-like and sill-like units tens to hundreds of
       meters
       thick. As the melt component increases, impact-melt breccias
       grade into impact melt rocks (see Chapter 6), in which
       the melt component is dominant and the included fragments
       are minor or entirely absent. These rocks often have the
       appearance
       of conventional igneous rocks.
       5.5. CRATER RIM ZONE AND PROXIMAL
       EJECTA DEPOSITS
       The region near the rim of the transient crater is subjected
       to relatively low shock pressures (typically <1–2 GPa
       in smaller structures; Fig. 3.4) (Kieffer and Simonds, 1980).
       These pressures are high enough to fracture and brecciate
       target rocks but are too low to produce unique shock-deformation
       features in them. The dominant effects in this region
       are related to the excavation of the crater and the ejection
       of material from it. In simple craters, which are only slightly
       larger than the original transient crater, the rim is
       characterized
       by structural uplift (and even overturning) of the target
       rocks that occurs during development of the original transient
       crater (Fig. 3.3). Even though much of this original
       transient crater rim may collapse into the final crater during
       modification, significant uplift may be preserved, especially
       in smaller and younger craters (e.g., Shoemaker, 1963; Roddy
       et al., 1975; Roddy, 1978). Such rim uplift and overturnShock-
       Metamorphosed Rocks (Impactites) in Impact Structures 75
       Fig. 5.13. Crater-fill breccia; suevite, metamorphosed. Typical
       exposure of Onaping Formation “Black Member,” showing
       centimetersized
       fragments of rock fragments and contorted recrystallized glassy
       inclusions in a black fragmental matrix. Despite color
       differences,
       the unit has a strong resemblance to fresh suevite from the Ries
       Crater (Germany) (see Fig. 5.9). Exposure located at “Black
       Member”
       type locality at Onaping Falls (Highway 144, Dowling Township)
       in the northwestern part of the Sudbury structure (Canada).
       Diameter
       of coin near large glassy inclusion is about 2 cm. Photograph
       courtesy of J. Guy-Bray.
       Fig. 5.14. Crater-fill breccia; suevite, heterogeneous glasses.
       Complex heterogeneous glassy breccia from West Clearwater Lake
       (Canada), composed of distinct areas of light- and dark-colored
       mixed glasses, which show short-range turbulent flow and mixing.
       The glassy areas contain abundant small rock and mineral
       fragments. Photograph courtesy of M. R. Dence (plane-polarized
       light).
       0.1 mm
       76 Traces of Catastrophe
       Fig. 5.15. Crater-fill breccia; suevite, metamorphosed.
       Heterogeneous glassy breccia consisting of fragments of
       recrystallized glass,
       together with rock and mineral fragments, in a fine opaque
       carbon-bearing matrix. Despite greenschist-level metamorphism,
       the glassy
       fragments still preserve original melt textures such as flow
       banding and vesicles (now filled with chlorite; gray). Many of
       the fragments
       display sharp crosscutting fractures, indicating that they were
       cool and brittle when deposited. The rock and mineral clasts
       represent
       broken basement (target) rocks; no typical volcanic textures
       (phenocrysts, etc.) are observed. Discrete fragments as small as
       5 &#956;m across
       can be distinguished in the opaque matrix. Onaping Formation
       “Black Member,” from type locality at Onaping Falls (Highway
       144,
       Dowling Township), northwestern corner of Sudbury structure
       (Canada). Sample CSF-66-36-1 (plane-polarized light).
       Fig. 5.16. Crater-fill breccia; suevite, “cored” inclusion.
       Large flow-banded fragment (about 15 cm long) from a larger
       glassy inclusion
       in the suevite unit of the Ries Crater (Germany) (Bollstadt
       quarry). The specimen is a composite or “cored” inclusion
       containing a large
       block of shocked and fractured crystalline rock (light)
       surrounded by dark, flow-banded glass. Photograph courtesy of F.
       Hörz.
       0.5 mm
       Shock-Metamorphosed Rocks (Impactites) in Impact Structures 77
       Fig. 5.17. Crater-fill breccia; suevite, “cored” inclusion.
       Composite (cored) inclusion in Onaping Formation “Black Member”
       in
       northwestern corner of Sudbury structure (Canada). Inclusion
       consists of a core fragment of crystalline granitic rock
       (light-colored)
       surrounded by flow-banded glassy material, now recrystallized.
       Similar inclusions are observed in fresher suevite deposits,
       e.g., at the Ries
       Crater (Germany) (see Figs. 5.12 and 5.16). A separate angular
       granitic fragment appears at lower right. Coin at left of
       inclusion is about
       2 cm in diameter. Exposure located at “Black Member” type
       locality at Onaping Falls (Highway 144, Dowling Township).
       Photograph
       courtesy of J. Guy-Bray.
       Fig. 5.18. Crater-fill breccia; suevite, “cored” inclusion.
       Composite rock fragment in metamorphosed suevite unit. The
       fragment contains
       a core of fine-grained granitic basement rock surrounded by a
       rim of microcrystalline recrystallized glass. The fragment is
       associated
       with smaller individual clasts of glassy material and rock and
       mineral fragments in a black, opaque, carbon-bearing matrix.
       Onaping
       Formation “Black Member,” from type locality at Onaping Falls
       (Highway 144, Dowling Township), northwestern corner of Sudbury
       structure (Canada). Sample CSF-66-36-2 (cross-polarized light).
       0.1 mm
       78 Traces of Catastrophe
       ing are only rarely observed in volcanic explosion structures
       such as maars and diatremes, and the presence of such rim
       deformation provides a strong indication of an impact origin
       for a structure.
       In a newly formed crater the rim and the surrounding
       region are generally covered with allogenic ejecta ejected from
       the growing transient crater (Melosh, 1989; Chapter 6). Two
       kinds of ejecta deposits can be distinguished: those deposited
       near the crater (proximal ejecta) and those distant from
       the crater (distal ejecta).
       Most of the material ejected beyond the crater rim is deposited
       near the crater (Melosh, 1989, p. 90). In terms of
       crater radius (Rc, the distance from the center of the crater
       to the final rim), approximately half the ejecta is deposited
       within 2 Rc from the center (or 1 Rc from the rim) to form a
       continuous ejecta blanket that may be tens to hundreds of
       meters thick, depending on the size of the crater. At greater
       distances, the ejecta unit becomes thinner and increasingly
       discontinuous; most of the ejecta (>90%) is deposited within
       about 5 Rc. (This value may serve as an arbitrary boundary
       between proximal and distal ejecta.) Because many of the
       fragments in the ejecta deposits were originally close to the
       impact point, they are often distinctively shocked and melted.
       Ejecta blankets, where they are preserved, may therefore
       provide the best and most accessible evidence for an impact
       origin of the structure.
       Ejecta deposits around impact craters are not homogeneous,
       but are made up of distinct lithologic units derived
       from different regions of the transient crater and transported
       by different mechanisms to the site of deposition. Mixing
       during the ejection and deposition process is not complete,
       and the ejecta deposits that surround a crater contain the
       same diversity of rock types that are found as crater fill
       within
       the structure: lithic breccias, suevites, and impact melt rocks.
       In large impact structures, the ejecta deposits preserved
       outside
       the crater contain a recognizable sequence of different
       lithologies. The sequence at the Ries Crater (Germany) (see
       von Engelhardt, 1990, 1997, and references therein) contains
       a lower unit of polymict lithic melt-free breccia (Bunte
       Breccia)
       overlain by melt-bearing breccia (suevite). Some of the
       ejecta at the Ries also occurs as large (tens to hundreds of
       meters in size) limestone blocks ejected intact from the crater
       and skidded for many kilometers across the surrounding
       ground surface (von Engelhardt, 1990, pp. 264–265).
       In impact structures formed on land, the near-surface
       regions are quickly removed by erosion, and the distinctive
       rim uplift and ejecta deposits are observed only at relatively
       young structures such as the Barringer Meteor Crater (Arizona)
       (age 50 ka) (Shoemaker, 1963) and the Ries Crater
       (Germany) (age 15 Ma) (von Engelhardt, 1990). At older
       structures (e.g., Dence, 1965, 1968), distinctively shocked
       rocks tend to be preserved in only two areas: in the target
       rocks immediately beneath the crater floor, and in the breccia
       and melt deposits that fill the crater itself.
       5.6. DISTAL EJECTA
       Although most of the material (about 90 vol%) ejected
       from the crater is deposited relatively close (<5 Rc) to the
       crater (Melosh, 1989, p. 90), a significant amount (about
       10 vol%) may travel to even greater distances (>5 Rc) to form
       deposits of distal ejecta. Where an atmosphere is present, as
       in terrestrial impact events, a combination of disruption of
       the atmosphere by the impact fireball, ballistic ejection from
       the crater, and subsequent atmospheric transport can distribute
       the smaller ejecta particles (typically >1 mm) to regional
       or even global distances (Alvarez et al., 1995). The
       resulting deposits, usually less than a few centimeters thick,
       may contain distinctive evidence for impact: shocked rock
       and mineral fragments, distinctive chemical and isotopic
       signatures,
       and unusual glassy objects. It has thus become possible
       to recognize debris from a given impact structure over
       a large area of Earth, and even to establish the existence of a
       major impact event from a globally distributed ejecta layer
       before the structure itself could be located.
       Although few layers of distal ejecta have been identified,
       they have been critical to recognizing large impact structures
       and determining their age. Coarse ejecta (millimeterto
       centimeter-sized fragments) from the Acraman structure
       (Australia) (D = 90 km) has been recognized as a discrete
       layer several centimeters thick at distances of 300–400 km
       from the site (Gostin et al., 1986; Williams, 1986). Ejecta
       from the Manson structure (Iowa) (D = 36 km) has been
       recognized more than 250 km away (Izett et al., 1993). The
       most striking and best-known example of distal ejecta is the
       thin layer of material ejected from the Chicxulub structure
       (Mexico) and distributed worldwide to form the K/T boundary
       layer (Alvarez et al., 1980; papers in Sharpton and Ward,
       1990, and in Ryder et al., 1996). The occurrence in this layer
       of shocked quartz grains and small spherules of melted target
       rock, accompanied by an anomalously high content of
       the element iridium (derived from the projectile), provided
       conclusive evidence that a large meteorite impact had occurred
       at the end of the Cretaceous Period, even before the
       Chicxulub impact structure itself was identified. The layer
       also provided key geochemical and geochronological evidence
       to demonstrate that the Chicxulub structure was identical in
       age to the K/T boundary and that it was also the source for
       the global ejecta layer itself.
       Generally, ejecta found at greater distances from the crater
       displays a higher level of shock effects, and much distal
       ejecta consists of small fragments of melted target rock. One
       peculiar and much-studied variety of distal ejecta is tektites
       and microtektites, small (centimeter- to millimeter-sized)
       bodies of pure glass that have been ejected from a few impact
       structures and spread over areas (strewnfields) that may
       be thousands of kilometers in extent (see Chapter 6).
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